Substrates comprising malodor reduction compositions

ABSTRACT

The present invention relates to substrates comprising malodor reduction compositions and methods of making and using such substrates. Such malodor reduction compositions do not unduely interfere with the scent of the perfumed or unperfumed substrates comprising such malodor reduction compositions and the perfumed or unperfumed situs that is treated with such substrates.

FIELD OF THE INVENTION

The present invention relates to substrates comprising malodor reductioncompositions and methods of making and using such substrates.

BACKGROUND OF THE INVENTION

Unscented or scented products are desired by consumers as they may beconsidered more natural and discreet than scented products.Manufacturers of unscented or scented products for controlling malodorsrely on malodor reduction ingredients or other technologies (e.g.filters) to reduce malodors. However, effectively controlling malodors,for example, amine-based malodors (e.g. fish and urine), thiol andsulfide-based malodors (e.g. garlic and onion), C₂-C₁₂ carboxylic acidbased malodors (e.g. body and pet odor), indole based malodors (e.g.fecal and bad breath), short chain fatty aldehyde based malodors (e.g.grease) and geosmin based malodors (e.g. mold/mildew) may be difficult,and the time required for a product to noticeably reduce malodors maycreate consumer doubt as to the product's efficacy on malodors. Oftentimes, manufacturers incorporate scented perfumes to help mask thesedifficult malodors.

Unfortunately, malodor control technologies typically cover up themalodor with a stronger scent and thus interfere with the scent of theperfumed or unperfumed situs that is treated with the malodor controltechnology. Thus, limited nature of the current malodor controltechnologies is extremely constraining. Thus what is needed is a broaderpalette of malodor control technologies so the perfume community candeliver the desired level of character in a greater number ofsituations/applications. Surprisingly, Applicants recognized that inaddition to blocking a malodor's access to a sensory cell, in order toachieve the desired goal, a malodor control technology must leave suchsensor cell open to other molecules, for example scent molecules. As aresult, such malodor reduction compositions do not unduely interferewith the scent of the perfumed or unperfumed substrates comprising suchmalodor reduction compositions and the perfumed or unperfumed situs thatis treated with such substrates.

SUMMARY OF THE INVENTION

The present invention relates to substrates comprising malodor reductioncompositions and methods of making and using such substrates. Suchmalodor reduction compositions do not unduely interfere with the scentof the perfumed or unperfumed substrates comprising such malodorreduction compositions and the perfumed or unperfumed situs that istreated with such substrates.

DETAILED DESCRIPTION OF THE INVENTION

As used herein “MORV” is the calculated malodor reduction value for asubject material. A material's MORV indicates such material's ability todecrease or even eliminate the perception of one or more malodors. Forpurposes of the present application, a material's MORV is calculated inaccordance with method found in the test methods section of the presentapplication.

As used herein, the term “perfume” does not include malodor reductionmaterials. Thus, the perfume portion of a composition does not include,when determining the perfume's composition, any malodor reductionmaterials found in the composition as such malodor reduction materialsare described herein. In short, if a material has a malodor reductionvalue “MORV” that is within the range of the MORV recited in the subjectclaim, such material is a malodor reduction material for purposes ofsuch claim.

As used herein, “malodor” refers to compounds generally offensive orunpleasant to most people, such as the complex odors associated withbowel movements.

As used herein, “odor blocking” refers to the ability of a compound todull the human sense of smell.

As used herein, “odor masking” refers to the ability of a compound witha non-offensive or pleasant smell that is dosed such that it limits theability to sense a malodorous compound. Odor-masking may involve theselection of compounds which coordinate with an anticipated malodor tochange the perception of the overall scent provided by the combinationof odorous compounds.

As used herein, the terms “a” and “an” mean “at least one”.

As used herein, the terms “include”, “includes” and “including” aremeant to be non-limiting.

Unless otherwise noted, all component or composition levels are inreference to the active portion of that component or composition, andare exclusive of impurities, for example, residual solvents orby-products, which may be present in commercially available sources ofsuch components or compositions.

All percentages and ratios are calculated by weight unless otherwiseindicated. All percentages and ratios are calculated based on the totalcomposition unless otherwise indicated.

It should be understood that every maximum numerical limitation giventhroughout this specification includes every lower numerical limitation,as if such lower numerical limitations were expressly written herein.Every minimum numerical limitation given throughout this specificationwill include every higher numerical limitation, as if such highernumerical limitations were expressly written herein. Every numericalrange given throughout this specification will include every narrowernumerical range that falls within such broader numerical range, as ifsuch narrower numerical ranges were all expressly written herein.

Malodor Reduction Materials

A non-limiting set of suitable malodor reduction materials are providedin the tables below. For ease of use, each material in Tables 1-3 isassigned a numerical identifier which is found in the column for eachtable that is designated Number. Table 4 is a subset of Table 1, Table 5is a subset of Table 2 and Table 6 is a subset of Table 3 and there forTables 4, 5 and 6 each use the same numerical identifier as found,respectively, in Tables 1-3.

Codes

A=Vapor Pressure>0.1 torrB=Vapor Pressure is between 0.01 torr and 0.1 torr

C=Log P<3 D=Log P>3 E=Probability of Ingredient Color Instability=0%F=Probability of Ingredient Color Instability<71%

G=Odor Detection Threshold less than p.ol=8H=Odor Detection Threshold greater than p.ol=8I=Melamine formaldehyde PMC Headspace Response Ratio greater than orequal to 10J=Melamine formaldehyde PMC leakage less than or equal to 5%K=Log of liquid dish neat product liquid-air partition coefficientgreater than or equal to −7L=Log of liquid dish neat product liquid-air partition coefficientgreater than or equal to −5

TABLE 1 List of materials with at least one MORV from 1 to 5 Num- CASComment ber Material Name Number Code 1 2-ethylhexyl (Z)-3-(4- 5466-77-3DEFHJ methoxyphenyl)acrylate 2 2,4-dimethyl-2-(5,5,8,8-tetramethyl-131812-67-4 DFHJ 5,6,7,8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane 31,1-dimethoxynon-2-yne 13257-44-8 ACEFHJK 4 para-Cymen-8-ol 1197-01-9BCGIJK 7 3-methoxy-7,7-dimethyl-10- 216970-21-7 BDEFHJKmethylenebicyclo[4.3.1]decane 9 Methoxycyclododecane 2986-54-1 DEFHJK 101,1-dimethoxycyclododecane 950-33-4 DEFHJK 11 (Z)-tridec-2-enenitrile22629-49-8 DEFHJK 13 Oxybenzone 131-57-7 DEFGJ 14 Oxyoctaline formate65405-72-3 DFHJK 16 4-methyl-1-oxaspiro[5.5]undecan-4- 57094-40-3 CFGIJKol 17 7-methyl-2H-benzo[b][1,4]dioxepin- 28940-11-6 CGIK 3(4H)-one 181,8-dioxacycloheptadecan-9-one 1725-01-5 DGJ 214-(tert-pentyl)cyclohexan-1-one 16587-71-6 ADFGIJKL 22 o-Phenyl anisol86-26-0 DEFHJK 23 3a,5,6,7,8,8b-hexahydro- 823178-41-2 DEFHJK2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-1,3-dioxole 257-isopropyl-8,8-dimethyl-6,10- 62406-73-9 BDEFHIJK dioxaspiro[4.5]decane28 Octyl 2-furoate 39251-88-2 DEFHJK 29 Octyl acetate 112-14-1 BDEFHJKL30 octanal propylene glycol acetal 74094-61-4 BDEFHJKL 31 Octanal124-13-0 ACHIKL 32 Octanal dimethyl acetal 10022-28-3 ACEFGJKL 33Myrcene 123-35-3 ADEFGIKL 34 Myrcenol 543-39-5 BCEFGIJK 35 Myrcenylacetate 1118-39-4 ADEFGJK 36 Myristaldehyde 124-25-4 DFHJK 37Myristicine 607-91-0 CGJK 38 Myristyl nitrile 629-63-0 DEFHJK 392,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJKoctahydronaphthalen-1-ol 42 Ocimenol 5986-38-9 BCHIJK 43 Ocimenol28977-58-4 BCHIJK 47 Nopyl acetate 128-51-8 DEFHJK 48 Nootkatone4674-50-4 DHJK 49 Nonyl alcohol 143-08-8 BDEFGIJKL 50 Nonaldehyde124-19-6 ADHIKL 52 12-methyl-14-tetradec-9-enolide 223104-61-8 DFHJK 57N-ethyl-p-menthane-3-carboxamide 39711-79-0 DEFGIJK 611-(3-methylbenzofuran-2-yl)ethan-1- 23911-56-0 CEFHIK one 622-methoxynaphthalene 93-04-9 BDEFHK 63 Nerolidol 7212-44-4 DEFHJK 64Nerol 106-25-2 BCHIK 65 1-ethyl-3- 31996-78-8 ACEFHIJKLmethoxytricyclo[2.2.1.02,6]heptane 67 Methyl (E)-non-2-enoate 111-79-5ADEFHJKL 68 10-isopropyl-2,7-dimethyl-1- 89079-92-5 BDEFHIJKoxaspiro[4.5]deca-3,6-diene 69 2-(2-(4-methylcyclohex-3-en-1- 95962-14-4DHJK yl)propyl)cyclopentan-1-one 70 Myrtenal 564-94-3 ACFHIJKL 71(E)-4-(2,2,3,6- 54992-90-4 BDEFHIJK tetramethylcyclohexyl)but-3-en-2-one 74 Myraldyl acetate 53889-39-7 DHJK 75 Musk tibetine 145-39-1 DHIJ76 1,7-dioxacycloheptadecan-8-one 3391-83-1 DGJ 77 Musk ketone 81-14-1DHJ 78 Musk ambrette 83-66-9 DHIJ 79 3-methylcyclopentadecan-1-one541-91-3 DEFHJK 80 (E)-3-methylcyclopentadec-4-en-1- 82356-51-2 DHJK one82 3-methyl-4-phenylbutan-2-ol 56836-93-2 BCEFHIK 831-(4-isopropylcyclohexyl)ethan-1-ol 63767-86-2 BDEFHIJK 85 Milk Lactone72881-27-7 DEFHJK 91 Methyl octine carbonate 111-80-8 BDEFHKL 92 Methyloctyl acetaldehyde 19009-56-4 ADFHJKL 936,6-dimethoxy-2,5,5-trimethylhex-2- 67674-46-8 ACHIJKL ene 98 Methylphenylethyl carbinol 2344-70-9 BCEFHIK 100 Methyl stearate 112-61-8DEFHJ 101 Methyl nonyl acetaldehyde dimethyl 68141-17-3 BDEFHJK acetal102 Methyl nonyl ketone 112-12-9 BDFHJKL 103 Methyl nonyl acetaldehyde110-41-8 BDFHJK 104 Methyl myristate 124-10-7 DEFHJK 105 Methyllinoleate 112-63-0 DEFHJ 106 Methyl lavender ketone 67633-95-8 CFHJK 108Methyl isoeugenol 93-16-3 ACEFHK 109 Methyl hexadecanoate 112-39-0DEFHJK 110 Methyl eugenol 93-15-2 ACEFHK 112 Methyl epijasmonate1211-29-6 CHJK 113 Methyl dihydrojasmonate 24851-98-7 DFHJK 114 Methyldiphenyl ether 3586-14-9 DEFHJK 117 Methyl cinnamate 103-26-4 BCEFHK 119Methyl chavicol 140-67-0 ADEFHK 120 Methyl beta-naphthyl ketone 93-08-3CEFHK 122 Methyl 2-octynoate 111-12-6 ACEFHKL 123 Methylalpha-cyclogeranate 28043-10-9 ACHIJKL 126 Methoxycitronellal 3613-30-7ACFGIJK 128 Menthone 1,2-glycerol ketal 67785-70-0 CEFHJ (racemic) 130Octahydro-1H-4,7-methanoindene-1- 30772-79-3 BCFHIJKL carbaldehyde 1343-(3-(tert-butyl)phenyl)-2- 62518-65-4 BDHJK methylpropanal 135(E)-4-(4,8-dimethylnona-3,7-dien-1- 38462-23-6 DEFHJK yl)pyridine 137(E)-trideca-3,12-dienenitrile 134769-33-8 DEFHJK 1402,2-dimethyl-3-(m-tolyl)propan-1-ol 103694-68-4 CEFHIJK 1412,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJKtetrahydroindeno[1,2-d][1,3]dioxine 142 Maceal 67845-30-1 BDFHJK 1434-(4-hydroxy-4- 31906-04-4 CHJ methylpentyl)cyclohex-3-ene-1-carbaldehyde 145 1-Limonene 5989-54-8 ADEFGIJKL 146(Z)-3-hexen-1-yl-2-cyclopenten-1- 53253-09-1 BDHK one 148 Linalyloctanoate 10024-64-3 DEFHJ 149 Linalyl isobutyrate 78-35-3 BDHJK 152Linalyl benzoate 126-64-7 DFHJ 153 Linalyl anthranilate 7149-26-0 DFHJ155 Linalool oxide (furanoid) 60047-17-8 BCHIJK 156 linalool oxide1365-19-1 CGIJK 158 (2Z,6E)-3,7-dimethylnona-2,6- 61792-11-8 BDEFHJKdienenitrile 159 3-(4-methylcyclohex-3-en-1- 6784-13-0 ACFHIJKyl)butanal 161 (2,5-dimethyl-1,3-dihydroinden-2- 285977-85-7 CEFHJKyl)methanol 162 3-(4-(tert-butyl)phenyl)-2- 80-54-6 BDHJK methylpropanal167 (E)-1-(1-methoxypropoxy)hex-3-ene 97358-54-8 ACEFGJKL 168 Leafacetal 88683-94-7 ACEFGJKL 170 1-Carveol 2102-58-1 BCHIJK 174 Laurylalcohol 112-53-8 DEFGJK 175 Lauryl acetate 112-66-3 DEFHJK 176 Lauricacid 143-07-7 DEFHJ 177 Lactojasmone 7011-83-8 BDEFHIJKL 178Lauraldehyde 112-54-9 BDFHJK 179 3,6-dimethylhexahydrobenzofuran-92015-65-1 BCEFHIJKL 2(3H)-one 182 4-(1-ethoxyvinyl)-3,3,5,5- 36306-87-3BDFHIJK tetramethylcyclohexan-1-one 183 Khusimol 16223-63-5 CEFHJK 1845-(sec-butyl)-2-(2,4- 117933-89-8 DEFHJ dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane 185 (1-methyl-2-((1,2,2- 198404-98-7 DEFHJKtrimethylbicyclo[3.1.0]hexan-3- yl)methyl)cyclopropyl)methanol 1862-propylheptanenitrile 208041-98-9 ADEFHIJKL 187(E)-6-(pent-3-en-1-yl)tetrahydro-2H- 32764-98-0 BCFHIKL pyran-2-one 1892-hexylcyclopentan-1-one 13074-65-2 BDFHJKL 1902-methyl-4-phenyl-1,3-dioxolane 33941-99-0 BCEFGIK 1922,6,9,10-tetramethyl-1- 71078-31-4 BDEFHIJK oxaspiro(4.5)deca-3,6-diene193 Isopulegol 89-79-2 BCEFHIJKL 195 Isopropyl palmitate 142-91-6 DEFHJ196 Isopropyl myristate 110-27-0 DEFHJK 197 Isopropyl dodecanoate10233-13-3 DEFHJK 199 Isopimpinellin 482-27-9 CFGJ 206Iso3-methylcyclopentadecan-1-one 3100-36-5 DEFGJK 208 Isomenthone491-07-6 ADEFGIJKL 209 Isojasmone 95-41-0 BDFHJKL 210 Isomenthone36977-92-1 ADEFGIJKL 211 Isohexenyl cyclohexenyl 37677-14-8 DFHJKcarboxaldehyde 212 Isoeugenyl benzyl ether 120-11-6 DFHJ 2151-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2 DHJK1,2,3,4,5,6,7,8-octahydronaphthalen- 2-yl)ethan-1-one 218 Isocyclocitral1335-66-6 ACFHIJKL 221 Isobutyl quinoline 65442-31-1 DEFHJK 227Isobornylcyclohexanol 68877-29-2 DEFHJK 228 Isobornyl propionate2756-56-1 BDEFHIJK 229 Isobornyl isobutyrate 85586-67-0 BDEFHIJK 230Isobornyl cyclohexanol 66072-32-0 DEFHJK 231 Isobornyl acetate 125-12-2ADEFHIJKL 233 Isobergamate 68683-20-5 DEFHJK 234 Isoamyl undecylenate12262-03-2 DEFHJK 238 Isoamyl laurate 6309-51-9 DEFHJK 242Isoambrettolide 28645-51-4 DGJ 243 Irisnitrile 29127-83-1 ADEFHKL 244Indolene 68527-79-7 DEFHJ 246 Indol/Hydroxycitronellal Schiff base67801-36-9 DEFHJ 247 4,4a,5,9b-tetrahydroindeno[1,2- 18096-62-3 BCEFGJKdl[1,3]dioxine 249 Hydroxy-citronellol 107-74-4 CEFGIJK 2522-cyclododecylpropan-1-ol 118562-73-5 DEFHJK 253 Hydrocitronitrile54089-83-7 CEFHJK 254 Hydrocinnamyl alcohol 122-97-4 BCEFHIK 256Hydratropaldehyde dimethyl acetal 90-87-9 ACEFHJK 2595-ethyl-4-hydroxy-2-methylfuran- 27538-09-6 CFGIK 3(2H)-one 2602,3-dihydro-3,3-dimethyl-1H-indene- 173445-44-8 DHJK 5-propanal 2613-(3,3-dimethyl-2,3-dihydro-1H- 173445-65-3 DHJK inden-5-yl)propanal 263Hexyl octanoate 1117-55-1 DEFHJK 267 Hexyl hexanoate 6378-65-0 DEFHJKL269 Hexyl cinnamic aldehyde 101-86-0 DHJ 271 Hexyl benzoate 6789-88-4DEFHJK 274 Hexenyl tiglate 84060-80-0 BDEFHJK 276(E)-3,7-dimethylocta-2,6-dien-1-yl 3681-73-0 DEFHJ palmitate 277Hexadecanolide 109-29-5 DEFGJK 278 2-butyl-4,4,6-trimethyl-1,3-dioxane54546-26-8 ADEFHIJKL 280 Ethyl (1R,2R,3R,4R)-3- 116126-82-0 BDEFHIJKisopropylbicyclo[2.2.1]hept-5-ene-2- carboxylate 2813a,4,5,6,7,7a-hexahydro-1H-4,7- 5413-60-5 CEFGJK methanoinden-6-ylacetate 285 2-(1-(3,3- 141773-73-1 DEFHJ dimethylcyclohexyl)ethoxy)-2-methylpropyl propionate 286 Heliotropine diethyl acetal 40527-42-2 CEFGJ288 Helional 1205-17-0 CHJK 289 (E)-oxacyclohexadec-13-en-2-one111879-80-2 DGJK 290 Gyrane 24237-00-1 ADEFHIJKL 292 Guaiol 489-86-1DEFHJK 293 1-(2,6,6-trimethylcyclohex-2-en-1- 68611-23-4 DHJKyl)pentan-3-one 294 Ethyl 2-ethyl-6,6-dimethylcyclohex- 57934-97-1BDEFHIJK 2-ene-1-carboxylate 295 Germacrene B 15423-57-1 DEFHJK 296Germacrene D 23986-74-5 DEFHJK 300 Geranyl phenylacetate 102-22-7 DFHJ301 Geranyl phenyl acetate 71648-43-6 DFHJ 303 Geranyl linalool1113-21-9 DFHJ 307 Geranyl cyclopentanone 68133-79-9 DHJK 316gamma-Undecalactone (racemic) 104-67-6 DEFHJKL 317 gamma-Terpinylacetate 10235-63-9 BDHJK 318 gamma-Terpineol 586-81-2 BCGIJK 321gamma-Nonalactone 104-61-0 BCEFHIKL 322 gamma-Muurolene 30021-74-0DEFHJKL 323 gamma-(E)-6-(pent-3-en-1- 63095-33-0 BCEFHKLyl)tetrahydro-2H-pyran-2-one 324 gamma-Ionone 79-76-5 BDEFHIJK 325gamma-Himachalene 53111-25-4 BDEFHJKL 328 gamma-Gurjunene 22567-17-5DEFHJKL 329 gamma-Eudesmol 1209-71-8 DFHJK 330 gamma-Dodecalactone2305-05-7 DEFHJK 331 gamma-Damascone 35087-49-1 BDEFHIJK 332gamma-Decalactone 706-14-9 BDEFHIJKL 333 gamma-Cadinene 39029-41-9DEFHJKL 334 1-(3,3-dimethylcyclohexyl)pent-4- 56973-87-6 BDEFHJKen-1-one 335 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJKhexahydrocyclopenta[g]isochromene 336 Furfuryl octanoate 39252-03-4DEFHJK 338 Furfuryl hexanoate 39252-02-3 CEFHJK 339 Furfuryl heptanoate39481-28-2 CEFHJK 342 2-methyldecanenitrile 69300-15-8 BDEFHJKL 3438,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJKhexahydro-1H-4,7-methanoinden-6- yl propionate 344 Ethyl(3aR,4S,7R,7aR)-octahydro- 80657-64-3 DEFHIJK 3aH-4,7-methanoindene-3a-carboxylate 347 Diethyl cyclohexane-1,4- 72903-27-6 CEFHJK dicarboxylate349 (6-is opropyl-9-methyl-1,4- 63187-91-7 CEFHJdioxaspiro[4.5]decan-2-yl)methanol 350 2-isobutyl-4-methyltetrahydro-2H-63500-71-0 BCEFHIJK pyran-4-ol 352 Undec-10-enenitrile 53179-04-7BDEFHJK 353 (Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2 CEFGJKmethanochromen-2-one 356 3-(2-ethylphenyl)-2,2- 67634-15-5 BDHJKdimethylpropanal 358 (E)-4,8-dimethyldeca-4,9-dienal 71077-31-1 BDFHJK359 (E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK1,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3-methylbutan-2-ol 360 8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3 DEFHJKhexahydro-1H-4,7-methanoinden-6- yl acetate 361 3-(4-ethylphenyl)-2,2-134123-93-6 DEFHJK dimethylpropanenitrile 362 2-heptylcyclopentan-1-one137-03-1 DFHJKL 363 1-ethoxyethoxy Cyclododecane 389083-83-4 DEFHJK 3643-cyclohexene-1-carboxylic acid, 815580-59-7 ACHIJKL 2,6,6-trimethyl-,methyl ester 368 Farnesyl acetate 29548-30-9 DEFHJK 369 Farnesol4602-84-0 DEFHJK 370 Oxacyclohexadecan-2-one 106-02-5 DEFGJK 3711-cyclopentadec-4-en-1-one 14595-54-1 DEFGJK 3721-cyclopentadec-4-en-1-one 35720-57-1 DEFGJK 373 2-methoxy-4-(4-128489-04-3 CGJ methylenetetrahydro-2H-pyran-2- yl)phenol 374 Eugenylacetate 93-28-7 CFHJK 375 Eugenol 97-53-0 CHIK 377Ethylmethylphenylglycidate 77-83-8 CFHJK 378 Ethylene brassylate105-95-3 DFGJ 381 Ethyl undecylenate 692-86-4 DEFHJK 385 Ethyl palmitate628-97-7 DEFHJ 386 Ethyl nonanoate 123-29-5 BDEFHJKL 388 Ethyl myristate124-06-1 DEFHJK 390 Ethyl linalool 10339-55-6 BCEFHJK 391 Ethyl laurate106-33-2 DEFHJK 394 Ethyl hexyl ketone 925-78-0 ADFHIKL 397 Ethyldecanoate 110-38-3 BDEFHJK 398 Ethyl gamma-Safranate 35044-57-6 ADHIJK407 Ethyl 3-phenylglycidate 121-39-1 CGJK 4136-ethyl-2,10,10-trimethyl-1- 79893-63-3 BDEFHIJKoxaspiro[4.5]deca-3,6-diene 414 Elemol 639-99-6 DEFHJK 415(2-(1-ethoxyethoxy)ethyl)benzene 2556-10-7 BCEFHJK 416(E)-3-methyl-5-(2,2,3- 67801-20-1 DHJKtrimethylcyclopent-3-en-1-yl)pent-4- en-2-ol 417 d-xylose 58-86-6 CGIJ418 (E)-4-((3aS,7aS)-octahydro-5H-4,7- 30168-23-1 DFHJKmethanoinden-5-ylidene)butanal 421 Dodecanal dimethyl acetal 14620-52-1DEFHJK 424 d-Limonene 5989-27-5 ADEFGIJKL 425 Dipropylene Glycol25265-71-8 CEFGIK 426 Dispirone 83863-64-3 BDEFHJK 428 Diphenyloxide101-84-8 BDEFHK 429 Diphenylmethane 101-81-5 DEFGK 432 Dimethyl benzylcarbinyl butyrate 10094-34-5 DEFHJK 436 2,6-dimethyloct-7-en-4-one1879-00-1 ADEFHIJKL 441 Octahydro-1H-4,7-methanoinden-5- 64001-15-6DEFHJKL yl acetate 444 Dihydrocarveol acetate 20777-49-5 BDEFHIJK 445Dihydrocarveol 619-01-2 BCEFHIJKL 449 Dihydro Linalool 18479-51-1BCEFGIJKL 450 Dihydro Isojasmonate 37172-53-5 DHJK 453 Dibutyl sulfide544-40-1 ADEFHIKL 457 Dibenzyl 103-29-7 DEFGJK 459 delta-Undecalactone710-04-3 DEFHJKL 461 delta-Elemene 20307-84-0 BDEFHJK 462 delta-Guaiene3691-11-0 DEFHJKL 463 delta-Dodecalactone 713-95-1 DEFHJK 464delta-Decalactone 705-86-2 BDEFHIJKL 465 delta-Cadinene 483-76-1 DEFHJKL466 delta-damascone 57378-68-4 ADHIJK 467 delta-Amorphene 189165-79-5DEFHJKL 468 delta-3-Carene 13466-78-9 ADEFGIJKL 470 Decylenic alcohol13019-22-2 BDEFHJK 471 Decyl propionate 5454-19-3 DEFHJK 473 Decanaldiethyl acetal 34764-02-8 DEFHJK 474 Decahydro-beta-naphthol 825-51-4BCEFGIK 475 1-cyclohexylethyl (E)-but-2-enoate 68039-69-0 BDFHJK 4783-(4-isopropylphenyl)-2- 103-95-7 BDFHJK methylpropanal 479Cyclotetradecane 295-17-0 DEFGJKL 480 Cyclopentadecanone 502-72-7 DEFGJK482 Cyclohexyl salicylate 25485-88-5 DFGJ 4843a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK methanoinden-6-ylbutyrate 485 Cyclic ethylene dodecanedioate 54982-83-1 DFGJ 4868,8-dimethyl-1,2,3,4,5,6,7,8- 68991-97-9 DHJK octahydronaphthalene-2-carbaldehyde 487 3a,4,5,6,7,7a-hexahydro-1H-4,7- 67634-20-2 DEFHJKmethanoinden-5-yl isobutyrate 488 Curzerene 17910-09-7 DHJK 491 Cumicalcohol 536-60-7 CHIJK 493 Coumarone 1646-26-0 BCEFHIK 4972-(3-phenylpropyl)pyridine 2110-18-1 CEFHJK 498 Dodecanenitrile2437-25-4 DEFHJK 501 (E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ 502Citryl acetate 6819-19-8 DFHJK 503 Citrus Propanol 15760-18-6 CEFHIJK505 Citronitrile 93893-89-1 CEFHJK 519 Citral propylene glycol acetal10444-50-5 CEFHJK 520 Citral dimethyl acetal 7549-37-3 BCEFHJK 521Citral diethyl acetal 7492-66-2 BDEFHJK 524 cis-Ocimene 3338-55-4 ADGIKL527 cis-Limonene oxide 13837-75-7 ADEFGIJKL 529 Cis-iso-ambrettolide36508-31-3 DGJ 530 cis-6-nonenol 35854-86-5 BCEFHIKL 531 cis-carveol1197-06-4 BCHIJK 532 cis-4-Decen-1-al 21662-09-9 ADHKL 534cis-3-hexenyl-cis-3-hexenoate 61444-38-0 BDEFHJK 537 cis-3-Hexenylsalicylate 65405-77-8 DEFGJ 541 Cis-3-hexenyl Benzoate 25152-85-6 DEFHJK544 cis-3-Hexenyl 2-methylbutyrate 53398-85-9 ADEFHJKL 546 cis-3,cis-6-nonadienol 53046-97-2 ACEFHK 548 Cinnamyl propionate 103-56-0DEFHJK 550 Cinnamyl isobutyrate 103-59-3 DEFHJK 551 Cinnamyl formate104-65-4 BCEFHK 552 Cinnamyl cinnamate 122-69-0 DHJ 553 Cinnamyl acetate103-54-8 BCEFHK 555 Cinnamic alcohol 104-54-1 BCEFHIK 558 Cetyl alcohol36653-82-4 DEFHJ 559 (E)-1-(2,6,6-trimethylcyclohex-2-en- 79-78-7 DHJK1-yl)hepta-1,6-dien-3-one 560 2-methyl-4-(2,6,6-trimethylcyclohex-65405-84-7 DFHJK 1-en-1-yl)butanal 561 (3aR,5aR,9aR,9bR)-3a,6,6,9a-3738-00-9 DEFHJK tetramethyldodecahydronaphtho[2,1- b]furan 5621,6-dioxacycloheptadecan-7-one 6707-60-4 DGJ 5631-(6-(tert-butyl)-1,1-dimethyl-2,3- 13171-00-1 DEFHJKdihydro-1H-inden-4-yl)ethan-1-one 565 Cedryl methyl ether 19870-74-7ADEFHJK 566 Cedryl formate 39900-38-4 BDEFHJK 567 Cedryl acetate 77-54-3DEFHJK 568 (4Z,8Z)-1,5,9-trimethyl-13- 71735-79-0 DFHJKoxabicyclo[10.1.0]trideca-4,8-diene 569 Cedrol 77-53-2 DEFHJK 5705-methyl-1-(2,2,3- 139539-66-5 DEFHJK trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane 571 5-methyl-1-(2,2,3- 426218-78-2 DFHJtrimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 5721,1,2,3,3-pentamethyl-1,2,3,5,6,7- 33704-61-9 BDEFHIJKhexahydro-4H-inden-4-one 573 Caryophyllene alcohol acetate 32214-91-8DEFHJK 574 Caryolan-1-ol 472-97-9 DEFHJK 577 Carvyl acetate 97-42-7BDHIJK 578 Caprylnitrile 124-12-9 ACEFGIKL 580 Caprylic alcohol 111-87-5ACEFGIKL 581 Caprylic acid 124-07-2 BCEFHIK 582 Capric acid 334-48-5DEFHJK 584 Capraldehyde 112-31-2 ADHKL 586 3-(4-methoxyphenyl)-2-5462-06-6 BCHJK methylpropanal 587 Camphorquinone 10373-78-1 ACEFGIJK589 Camphene 79-92-5 ADEFGIJKL 591 Ethyl 2-methyl-4-oxo-6- 59151-19-8DHJ pentylcyclohex-2-ene-1-carboxylate 592 Butylated hydroxytoluene128-37-0 DEFGIJK 594 Butyl stearate 123-95-5 DEFHJ 595 Butyl butyryllactate 7492-70-8 CEFGJK 599 Butyl 10-undecenoate 109-42-2 DEFHJK 6002-methyl-4-(2,2,3- 72089-08-8 DEFHJK trimethylcyclopent-3-en-1-yl)butan-1-ol 601 3-(4-(tert-butyl)phenyl)propanal 18127-01-0 BDHJK 603 Bornylisobutyrate 24717-86-0 BDEFHIJK 604 Bornyl acetate 76-49-3 ADEFHIJKL 6062-ethoxy-2,6,6-trimethyl-9- 68845-00-1 BDEFHJKmethylenebicyclo[3.3.1]nonane 607 (ethoxymethoxy)cyclododecane58567-11-6 DEFHJK 608 Bisabolene 495-62-5 DEFHJK 609 Bigarade oxide72429-08-4 ADEFHJKL 610 beta-Vetivone 18444-79-6 DHJK 611 beta-Terpinylacetate 10198-23-9 BDHJK 612 beta-Terpineol 138-87-4 BCGIJK 613beta-Sinensal 60066-88-8 DHJK 614 beta-Sesquiphellandrene 20307-83-9DEFHJK 615 beta-Selinene 17066-67-0 BDEFGJK 616 beta-Santalol 77-42-9DEFHJK 618 beta-Pinene 127-91-3 ADEFGIJKL 620 beta-Naphthyl ethyl ether93-18-5 BDEFHJK 621 beta-Patchoulline 514-51-2 BDEFGJKL 624beta-Himachalene Oxide 57819-73-5 BDFHJK 625 beta-Himachalene 1461-03-6DEFHJKL 626 beta-Guaiene 88-84-6 DEFHJKL 627 (2,2-dimethoxyethyl)benzene101-48-4 DHJK 628 beta-Farnesene 18794-84-8 DEFHJK 631 beta-Copaene18252-44-3 BDEFHJKL 632 beta-Cedrene 546-28-1 BDEFGJKL 633beta-Caryophyllene 87-44-5 DEFHJKL 635 beta-Bisabolol 15352-77-9 DFHJK636 Beta ionone epoxide 23267-57-4 BDEFHIJK 638 Bergaptene 484-20-8 CGJ639 Benzyl-tert-butanol 103-05-9 CEFGJK 644 Benzyl laurate 140-25-0DEFHJ 649 Benzyl dimethyl carbinol 100-86-7 BCEFGIK 650 Benzyl cinnamate103-41-3 DHJ 653 Benzyl benzoate 120-51-4 DHJ 655 Benzophenone 119-61-9DEFHK 658 7-isopentyl-2H- 362467-67-2 DHJbenzo[b][1,4]dioxepin-3(4H)-one 659 2′-isopropyl-1,7,7- 188199-50-0DEFHJK trimethylspiro[bicyclo[2.2.1]heptane- 2,4′-[1,3]dioxane] 6604-(4-methylpent-3-en-1-yl)cyclohex- 21690-43-7 DEFHJK3-ene-1-carbonitrile 661 Aurantiol 89-43-0 DEFHJ 663 Anisylphenylacetate 102-17-0 DFHJ 668 Methyl (E)-octa-4,7-dienoate 189440-77-5ACEFHKL 671 Amyl Cinnamate 3487-99-8 DEFHJK 673(3aR,5aS,9aS,9bR)-3a,6,6,9a- 6790-58-5 DEFHJKtetramethyldodecahydronaphtho[2,1- b]furan 674(4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6 DEFHJKhexamethyloctahydro-4H-4a,9- methanoazuleno[5,6-d][1,3]dioxole 6752,5,5-trimethyl-1,2,3,4,5,6,7,8- 71832-76-3 DEFHJKoctahydronaphthalen-2-ol 676 2,5,5-trimethyl-1,2,3,4,5,6,7,8- 41199-19-3DEFHJK octahydronaphthalen-2-ol 677 1-((2-(tert- 139504-68-0 DEFHJKbutyl)cyclohexyl)oxy)butan-2-ol 678 (3S,5aR,7aS,11aS,11bR)-3,8,8,11a-57345-19-4 DEFHJ tetramethyldodecahydro-5H-3,5a-epoxynaphtho[2,1-c]oxepine 679 2,2,6,6,7,8,8-heptamethyldecahydro-476332-65-7 ADEFHJK 2H-indeno[4,5-b]furan 6802,2,6,6,7,8,8-heptamethyldecahydro- 647828-16-8 ADEFHJK2H-indeno[4,5-b]furan 681 Amber acetate 37172-02-4 BDEFHJK 682Alpinofix ® 811436-82-5 DEFHJ 683 alpha-Thujone 546-80-5 ADEFGIJKL 684alpha-Vetivone 15764-04-2 DHJK 686 alpha-Terpinyl propionate 80-27-3BDEFHJK 691 alpha-Sinensal 17909-77-2 DHJK 692 alpha-Selinene 473-13-2BDEFHJK 693 alpha-Santalene 512-61-8 ADEFHJKL 694 alpha-Santalol115-71-9 DEFHJK 696 alpha-Patchoulene 560-32-7 ADEFHJKL 697alpha-neobutenone 56973-85-4 BDHJK 698 alpha-Muurolene 10208-80-7DEFHJKL 700 alpha-methyl ionone 127-42-4 BDHJK 702 alpha-Limonene138-86-3 ADEFGIJKL 704 alpha-bone 79-69-6 BDHJK 706 alpha-Humulene6753-98-6 DEFHJK 707 alpha-Himachalene 186538-22-7 BDEFHJK 708alpha-Gurjunene 489-40-7 BDEFHJKL 709 alpha-Guaiene 3691-12-1 DEFHJKL710 alpha-Farnesene 502-61-4 DEFHJK 711 alpha-Fenchene 471-84-1ADEFGIJKL 712 alpha-Eudesmol 473-16-5 DEFHJK 713 alpha-Curcumene4176-17-4 DEFHJK 714 alpha-Cubebene 17699-14-8 ADEFHJKL 715alpha-Cedrene epoxide 13567-39-0 ADEFHJK 716 alpha-Cadinol 481-34-5DEFHJK 717 alpha-Cadinene 24406-05-1 DEFHJKL 718 alpha-Bisabolol515-69-5 DFHJK 719 alpha-bisabolene 17627-44-0 DEFHJK 720alpha-Bergamotene 17699-05-7 BDEFHJKL 721 alpha-Amylcinnamyl alcohol101-85-9 DEFHJ 722 alpha-Amylcinnamyl acetate 7493-78-9 DEFHJ 723alpha-Amylcinnamaldehyde diethyl 60763-41-9 DEFHJ acetal 724alpha-Amylcinnamaldehyde 122-40-7 DHJK 725 alpha-Amorphene 23515-88-0DEFHJKL 726 alpha-Agarofuran 5956-12-7 BDEFHJK 7271-methyl-4-(4-methyl-3-penten-1- 52475-86-2 DFHJKyl)-3-Cyclohexene-1-carboxaldehyde 730 1-Phenyl-2-pentanol 705-73-7CEFHK 731 1-Phenyl-3-methyl-3-pentanol 10415-87-9 CEFHJK 7332,3,4-trimethoxy-benzaldehyde 2103-57-3 BCGI 7352,4,5-trimethoxy-benzaldehyde 4460-86-0 BCG 7362,4,6-trimethoxybenzaldehyde 830-79-5 BCGI 738 2,4-Nonadienal 6750-03-4ACHKL 741 2,6,10-Trimethylundecanal 105-88-4 BDFGJK 742 alpha,4-Dimethylbenzenepropanal 41496-43-9 ACHJK 746 Allyl cyclohexyl propionate2705-87-5 BDEFHJK 748 Allyl amyl glycolate 67634-00-8 BCEFGJK 750Allo-aromadendrene 25246-27-9 BDEFHJKL 752 Aldehyde C-11 143-14-6 ADHJK754 Methyl (E)-2-(((3,5- 94022-83-0 DEFHJ dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate 757 2,6,10-trimethylundec-9-enal 141-13-9BDFHJK 758 Acetoxymethyl-isolongifolene 59056-62-1 BDEFHJK (isomers) 763Acetate C9 143-13-5 BDEFHJKL 764 Acetarolle ® 744266-61-3 DFHJK 766Acetaldehyde phenylethyl propyl 7493-57-4 CEFHJK acetal 767 Acetaldehydedipropyl acetal 105-82-8 ACEFGIKL 768 Acetaldehyde benzyl 2-methoxyethyl7492-39-9 BCEFHJK acetal 769 (Z)-2-(4-methylbenzylidene)heptanal84697-09-6 DHJ 770 9-decenal 39770-05-3 ADHKL 771 8-Hexadecenolide123-69-3 DGJ 772 7-Methoxycoumarin 531-59-9 CHK 774 7-epi-alpha-Selinene123123-37-5 BDEFHJK 775 7-eip-alpha-Eudesmol 123123-38-6 DEFHJK 7767-Acetyl-1,1,3,4,4,6- 1506-02-1 DEFHJ hexamethyltetralin 7786-Isopropylquinoline 135-79-5 CEFHJK 781 6,6-dimethyl-2-norpinene-2-33885-51-7 BCFHJK propionaldehyde 782 6,10,14-trimethyl-2-Pentadecanone502-69-2 DEFHJK 786 5-Isopropenyl-2-methyl-2- 13679-86-2 ACGIJKLvinyltetrahydrofuran 788 5-Cyclohexadecenone 37609-25-9 DEFGJK 7914-Terpinenol 562-74-3 BCHIJK 792 4-Pentenophenone 3240-29-7 BCEFHIK 8004-Carvomenthenol 28219-82-1 BCHIJK 802 4,5,6,7-Tetrahydro-3,6- 494-90-6BCEFHIJKL dimethylbenzofuran 803 4-(p-Methoxyphenyl)-2-butanone 104-20-1BCEFHJK 804 3-Thujopsanone 25966-79-4 BDEFHJK 805 3-Propylidenephthalide17369-59-4 CEFHK 806 3-Nonylacrolein 20407-84-5 BDFHJK 8073-Methyl-5-phenyl-1-pentanal 55066-49-4 BDFHJK 814 3-Hexenyl isovalerate10032-11-8 ADEFHJKL 821 3,6-Dimethyl-3-octanyl acetate 60763-42-0ADEFHIJKL 824 3,4,5-trimethoxybenzaldehyde 86-81-7 BCGIK 826 3-(p-7775-00-0 BDFHJK Isopropylphenyl)propionaldehyde 827 2-Undecenenitrile22629-48-7 BDEFHJK 828 2-Undecenal 2463-77-6 ADHJK 8292-trans-6-trans-Nonadienal 17587-33-6 ACHKL 831 2-Phenylethyl butyrate103-52-6 DEFHJK 833 2-Phenyl-3-(2-furyl)prop-2-enal 57568-60-2 CHJ 8342-Phenoxyethanol 122-99-6 BCEFGIK 837 2-Nonen-1-al 2463-53-8 ADHKL 8392-Nonanol 628-99-9 BDEFGIKL 840 2-Nonanone 821-55-6 ADFHIKL 8492-Isobutyl quinoline 93-19-6 CEFHJK 850 2-Hexylidene cyclopentanone17373-89-6 DFHJKL 852 2-Heptyl tetrahydrofuran 2435-16-7 BDEFHJKL 8562-Decenal 3913-71-1 ADHKL 864 2,6-Nonadienal 26370-28-5 ACHKL 8652,6-Nonadien-1-ol 7786-44-9 ACEFHK 866 2,6-dimethyl-octanal 7779-07-9ADFGIJKL 868 1-Decanol 112-30-1 BDEFGJK 869 1-Hepten-1-ol, 1-acetate35468-97-4 ACEFHKL 870 10-Undecen-1-ol 112-43-6 DEFHJK 871 10-Undecenal112-45-8 ADHJK 872 10-epi-gamma-Eudesmol 15051-81-7 DFHJK 8731,8-Thiocineol 68391-28-6 ADEFHIJKL 876 1,3,5-undecatriene 16356-11-9ADEFHJKL 877 1,2-Dihydrolinalool 2270-57-7 BCEFGIJKL 8781,3,3-trimethyl-2-norbornanyl 13851-11-1 ADEFHIJKL acetate 8791,1,2,3,3-Pentamethylindan 1203-17-4 ADHIJKL 881(Z)-6,10-dimethylundeca-5,9-dien-2- 3239-37-0 DEFHJK yl acetate 884(Z)-3-Dodecenal 68141-15-1 BCFHJK 885 (S)-gamma-Undecalactone 74568-05-1DEFHJKL 886 (R)-gamma-Undecalactone 74568-06-2 DEFHJKL 890(E)-6,10-dimethylundeca-5,9-dien-2- 3239-35-8 DEFHJK yl acetate 892(2Z)-3-methyl-5-phenyl-2- 53243-59-7 DEFHJK Pentenenitrile 893(2S,5S,6S)-2,6,10,10-tetramethyl-1- 65620-50-0 DFHIJKoxaspiro[4_5]decan-6-ol 894 (2E)-3-methyl-5-phenyl-2- 53243-60-0 CEFHJKpentenenitrile 897 (+)-Dihydrocarveol 22567-21-1 BCEFHIJKL 905 Menthone89-80-5 ADEFGIJKL 908 (R,E)-2-methyl-4-(2,2,3- 185068-69-3 CHJKtrimethylcyclopent-3-en-1-yl)but-2- en-1-ol 912 2-(8-isopropyl-6-68901-32-6 DEFHJK methylbicyclo[2.2.2]oct-5-en-2-yl)- 1,3-dioxolane 913gamma-methyl ionone 7388-22-9 BDHIJK 914 3-(3-isopropylphenyl)butanal125109-85-5 BDHJK 916 3-(1-ethoxyethoxy)-3,7- 40910-49-4 BDEFHJKdimethylocta-1,6-diene 919 3a,4,5,6,7,7a-hexahydro-1H-4,7- 17511-60-3CEFHJK methanoinden-6-yl propionate 920 Bulnesol 22451-73-6 DEFHJK 922Benzyl phenylacetate 102-16-9 DHJ 923 Benzoin 119-53-9 CEFHJ 924(E)-1,2,4-trimethoxy-5-(prop-1-en-1- 2883-98-9 BCFGJK yl)benzene 925alpha,alpha,6,6-tetramethyl 33885-52-8 BDFHJKbicyclo[3.1.1]hept-2-ene-propanal 926 7-epi-sesquithujene 159407-35-9DEFHJKL 927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJK hexamethylindan 9283-Methylphenethyl alcohol 1875-89-4 BCEFHIK 929 3,6-Nonadien-1-ol76649-25-7 ACEFHK 930 2-Tridecenal 7774-82-5 BDFHJK 933 Patchoulialcohol 5986-55-0 DEFHIJK 937 p-Cresyl isobutyrate 103-93-5 BDHJK 939p-Cresyl n-hexanoate 68141-11-7 DEFHJK 941 5-hexyl-4-methyldihydrofuran-67663-01-8 BDEFHIJKL 2(3H)-one 942 Ethyl (2Z,4E)-deca-2,4-dienoate3025-30-7 BDEFHJK 943 Pelargene 68039-40-7 DEFHJK 9452-cyclohexylidene-2- 10461-98-0 DFHJK phenylacetonitrile 946Perillaldehyde 2111-75-3 ACHIJK 947 Perillyl acetate 15111-96-3 DFHJK948 Perillyl alcohol 536-59-4 CHIJK 950 (2-isopropoxyethyl)benzene68039-47-4 ACEFHJKL 951 Ethyl (2Z,4E)-deca-2,4-dienoate 313973-37-4BDEFHJK 953 (2-(cyclohexyloxy)ethyl)benzene 80858-47-5 DEFHJK 954Phenethyl 2-methylbutyrate 24817-51-4 DEFHJK 955 Phenethyl alcohol60-12-8 BCEFGIK 959 Phenethyl phenylacetate 102-20-5 DHJ 962 Phenoxanol55066-48-3 DEFHJK 965 Phenyl benzoate 93-99-2 DFHJK 967 Phenyl ethylbenzoate 94-47-3 DHJ 969 Phenylacetaldehyde ethyleneglycol 101-49-5BCEFGIK acetal 973 2-(6,6-dimethylbicyclo[3.1.1]hept-2- 30897-75-7ACFHIJKL en-2-yl)acetaldehyde 974 Pinocarveol 5947-36-4 BCEFGIJKL 976Piperonyl acetone 55418-52-5 CEFGJ 978 3a,4,5,6,7,7a-hexahydro-1H-4,7-68039-44-1 DEFHJK methanoinden-6-yl pivalate 980(4aR,8aS)-7-methyloctahydro-1,4- 41724-19-0 CEFGJKLmethanonaphthalen-6(2H)-one 982 p-Menth-3-en-1-ol 586-82-3 BCGIJK 985(E)-3,3-dimethyl-5-(2,2,3- 107898-54-4 DHJKtrimethylcyclopent-3-en-1-yl)pent-4- en-2-ol 9881-methyl-4-(4-methylpent-3-en-1- 52474-60-9 DFHJKyl)cyclohex-3-ene-1-carbaldehyde 993 Propylene glycol 57-55-6 ACEFGIKL998 p-Tolyl phenylacetate 101-94-0 DFHJ 1000 Ethyl 2,4,7-decatrienoate78417-28-4 BDEFHJK 1003 2-benzyl-4,4,6-trimethyl-1,3-dioxane 67633-94-7DEFHJK 1006 2,4-dimethyl-4- 82461-14-1 BDEFHJK phenyltetrahydrofuran1007 (2R,4a′R,8a′R)-3,7′-dimethyl- 41816-03-9 DEFHJK3′,4′,4a′,5′,8′,8a′-hexahydro-1′H- spiro[oxirane-2,2′-[1,4]methanonaphthalene] 1008 (Z)-6-ethylideneoctahydro-2H-5,8-93939-86-7 BCEFHJKL methanochromene 1009 2-((S)-1-((S)-3,3- 236391-76-7DFHJ dimethylcyclohexyl)ethoxy)-2- oxoethyl propionate 1010 Methyl2,2-dimethyl-6- 81752-87-6 ADHIJKL methylenecyclohexane-1-carboxylate1012 2-methyl-5-phenylpentan-1-ol 25634-93-9 DEFHJK 10164-methyl-2-phenyl-3,6-dihydro-2H- 60335-71-9 BCEFGJK pyran 1020 Sabinol471-16-9 BCEFHIJKL 1021 Safrole 94-59-7 BCEFHK 10222,2,7,9-tetramethylspiro(5.5)undec- 502847-01-0 DHIJK 8-en-1-one 10233-methyl-5-(2,2,3- 65113-99-7 DEFHJKtrimethylcyclopent-3-en-1-yl)pentan- 2-ol 1024 (Z)-2-ethyl-4-(2,2,3-28219-61-6 DEFHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1025(E)-2-methyl-4-(2,2,3- 28219-60-5 CHJKtrimethylcyclopent-3-en-1-yl)but-2- en-1-ol 10265-methoxyoctahydro-1H-4,7- 86803-90-9 CHJK methanoindene-2-carbaldehyde1027 5-methoxyoctahydro-1H-4,7- 193425-86-4 CHJKmethanoindene-2-carbaldehyde 1028 Sclareol 515-03-7 DEFHJ 1029 Sclareoloxide 5153-92-4 DEFHJK 1031 Selina-3,7(11)-diene 6813-21-4 DEFHJKL 10322-(1-(3,3- 477218-42-1 DEFHJ dimethylcyclohexyl)ethoxy)-2- methylpropylcyclopropanecarboxylate 1033 3-(4-isobutylphenyl)-2- 6658-48-6 DHJKmethylpropanal 1035 Spathulenol 6750-60-3 DEFHJK 1036 Spirambrene533925-08-5 BCEFHJK 1037 Spirodecane 6413-26-9 BCEFGIJKL 1038 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3 DGJK 1-one 10422-(4-methylthiaz ol-5-yl)ethan-1-ol 137-00-8 CGIKL 10432-(heptan-3-yl)-1,3-dioxolane 4359-47-1 ACEFHIJKL 1045 (Z)-dodec-4-enal21944-98-9 BDFHJK 1046 tau-Cadinol 5937-11-1 DEFHJK 1047 tau-Muurolol19912-62-0 DEFHJK 1053 Tetrahydrojasmone 13074-63-0 BDFHIJKL 10572,6,10,10-tetramethyl-1- 36431-72-8 BDFHIJKL oxaspiro[4.5]dec-6-ene 1059Thiomenthone 38462-22-5 BDEFHIJKL 1060 Thujopsene 470-40-6 BDEFGJKL 1062Thymol methyl ether 1076-56-8 ADHIJKL 10631-(2,2,6-trimethylcyclohexyl)hexan- 70788-30-6 DEFHJK 3-ol 1064trans,trans-2,4-Nonadienal 5910-87-2 ACHKL 1065 trans,trans-Farnesol106-28-5 DEFHJK 1066 trans-2,cis-6-Nonadienal 557-48-2 ACHKL 1067trans-2-Decenal 3913-81-3 ADHKL 1070 trans-2-Nonen-1-al 18829-56-6 ADHKL1072 trans-3, cis-6-nonadienol 56805-23-3 ACEFHK 1073 trans-4-Decen-1-al65405-70-1 ADHKL 1075 trans-ambrettolide 51155-12-5 DGJ 1077trans-beta-ocimene 13877-91-3 ADGIKL 1078 trans-beta-Ocimene 3779-61-1ADGIKL 1082 trans-Geraniol 106-24-1 BCHIK 1083 trans-Hedione 2570-03-8DFHJK 1085 7-(1,1-Dimethylethyl)-2H-1,5- 195251-91-3 CEFHJbenzodioxepin-3(4H)-one 1089 Tricyclone 68433-81-8 DEFHJK 1090 Tridecylalcohol 112-70-9 DEFGJK 1091 Triethyl citrate 77-93-0 CEFGJ 1093 Methyl24(1-hydroxy-3- 144761-91-1 DFHJ phenylbutyl)amino)benzoate 10951-((2E,5Z,9Z)-2,6,10- 28371-99-5 DHJKtrimethylcyclododeca-2,5,9-trien-1- yl)ethan-1-one 1097Decahydro-2,6,6,7,8,8-hexamethyl- 338735-71-0 BDEFHJK2h-indeno(4,5-b)furan 1099 13-methyl oxacyclopentadec-10-en- 365411-50-3DEFHJK 2-one 1102 Undecanal 112-44-7 BDHJK 1104(E)-4-methyldec-3-en-5-ol 81782-77-6 BDEFHIJK 1105 Valencene 4630-07-3BDEFHJK 1107 Valerianol 20489-45-6 DEFHJK 1111 Vanillin isobutyrate20665-85-4 CHJ 1113 Vaniwhite ® 5533-03-9 CGIK 1116(Z)-2-methyl-4-(2,6,6- 68555-62-4 BDFHJKtrimethylcyclohex-2-en-1-yl)but-2- enal 1117 Methyl 2,4-dihydroxy-3,6-4707-47-5 CGIJ dimethylbenzoate 1120 1-methoxy-3a,4,5,6,7,7a-hexahydro-27135-90-6 ACEFHJKL 1H-4,7-methanoindene 1121 Methyl (Z)-2-((3-(4-(tert-91-51-0 DFHJ butyl)phenyl)-2- methylpropylidene)amino)benzoate 1125(Z)-hex-3-en-1-yl isobutyrate 41519-23-7 ADEFHJKL 1126 Vertacetal5182-36-5 BCFHJK 1129 1-((3R,3aR,7R,8aS)-3,6,8,8- 32388-55-9 DHJKtetramethyl-2,3,4,7,8,8a-hexahydro- 1H-3a,7-methanoazulen-5-yl)ethan-1-one 1131 Methyl (Z)-2-(((2,4- 68738-99-8 DEFHJdimethylcyclohex-3-en-1- yl)methylene)amino)benzoate 1135 Vetiverol89-88-3 CEFHIJK 1136 Vetivert Acetate 117-98-6 DEFHJK 1137Decahydro-3H-spiro[furan-2,5′- 68480-11-5 DEFGJKL [4,7]methanoindene]1138 (2Z,6E)-nona-2,6-dienenitrile 67019-89-0 ACEFHKL 1139(Z)-cyclooct-4-en-1-yl methyl 87731-18-8 BCHJKL carbonate 1140(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3 DEFHJKtetramethyldecahydro-1H- cyclopropa[e]azulen-4-ol 11423,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJtetrahydronaphthalene-2-carbonitrile 1143 (1S,2S,3S,5R)-2,6,6-133636-82-5 DEFHJK trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexan]-2′-en-4′-one 1144 1′,1′,5′,5′-tetramethylhexahydro-154171-76-3 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene] 1145 1′,1′,5′,5′-tetramethylhexahydro-154171-77-4 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene] K 1146 4-(4-hydroxy-3- 122-48-5 CEFGJmethoxyphenyl)butan-2-one 1147 (1R,8aR)-4-isopropyl-1,6-dimethyl-41929-05-9 DEFHJKL 1,2,3,7,8,8a-hexahydronaphthalene 11484,5-epoxy-4,11,11-trimethyl-8- 1139-30-6 DEFHJKmethylenebicyclo(7.2.0)undecane 1149 1,3,4,6,7,8alpha-hexahydro-1,1,5,5-23787-90-8 DEFHIJK tetramethyl-2H-2,4alpha- methanophtalen-8(5H)-one

TABLE 2 List of materials with at least one MORV greater than 5 to 10CAS Comment Number Material Name Number Code 22,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4 DFHJ5,6,7,8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane 233a,5,6,7,8,8b-hexahydro- 823178-41-2 DEFHJK2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-1,3-dioxole 1412,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJKtetrahydroindeno[1,2-d][1,3]dioxine 185 (1-methyl-2-((1,2,2- 198404-98-7DEFHJK trimethylbicyclo[3.1.0]hexan-3- yl)methyl)cyclopropyl)methanol227 Isobornylcyclohexanol 68877-29-2 DEFHJK 230 Isobornyl cyclohexanol66072-32-0 DEFHJK 246 Indol/Hydroxycitronellal Schiff base 67801-36-9DEFHJ 248 Hydroxymethyl isolongifolene 59056-64-3 DEFHJK 3438,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJKhexahydro-1H-4,7-methanoinden-6- yl propionate 359(E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK1,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3-methylbutan-2-ol 565 Cedryl methyl ether 19870-74-7 BDEFHJK 631beta-Copaene 18252-44-3 BDEFHJKL 659 2′-isopropyl-1,7,7- 869292-93-3BDEFHJK trimethylspiro[bicyclo[2.2.1]heptane- 2,4′-[1,3[dioxane] 674(4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6 DEFHJKhexamethyloctahydro-4H-4a,9- methanoazuleno[5,6-d][1,3]dioxole 678(3S,5aR,7aS,11aS,11bR)-3,8,8,11a- 57345-19-4 DEFHJtetramethyldodecahydro-5H-3,5a- epoxynaphtho[2,1-c]oxepine 6792,2,6,6,7,8,8-heptamethyldecahydro- 476332-65-7 DEFHJK2H-indeno[4,5-b]furan 715 alpha-Cedrene epoxide 13567-39-0 BDEFHJK 758Acetoxymethyl-isolongifolene 59056-62-1 DEFHJK (isomers) 1028 Sclareol515-03-7 DEFHJ 1097 Decahydro-2,6,6,7,8,8-hexamethyl- 338735-71-0 DEFHJK2h-indeno(4,5-b)furan

TABLE 3 List of materials with at least one MORV from 0.5 to less than 1CAS Comment Number Material Name Number Code 12 1-ethoxy-4-(tert-181258-89-9 ADEFHJK pentyl)cyclohexane 19 (3Z)-1-(2-buten-1-yloxy)-3-888744-18-1 ADEFHJKL hexene 20 4-(2-methoxypropan-2-yl)-1- 14576-08-0ADHIJKL methylcyclohex-1-ene 24 O-Methyl linalool 60763-44-2 ADHIJKL 26o-Methoxycinnamaldehyde 1504-74-1 ACHK 27 Octanal, 3,7-dimethyl-25795-46-4 ADGIJKL 53 3,3-Dimethyl-5(2,2,3- 329925-33-9 CEFHJTrimethyl-3-Cyclopenten- 1yl)-4-Penten-2-ol 54 n-Hexyl salicylate6259-76-3 DEFHJ 55 n-Hexyl 2-butenoate 19089-92-0 ADEFHJKL 59 NerylFormate 2142-94-1 BCEFHJK 72 Methyl-beta-ionone 127-43-5 DHJK 73Myroxide 28977-57-3 ADGIJKL 81 (E)-3,7-dimethylocta-4,6- 18479-54-4BCEFGIJK dien-3-ol 84 (Z)-hex-3-en-1-yl 188570-78-7 BCEFHIKLcyclopropanecarboxylate 96 Methyl phenyl carbinyl 120-45-6 BCHJKpropionate 97 Methyl phenylacetate 101-41-7 ACEFHIKL 107 2-methyl-6-91069-37-3 BCEFGIKL oxaspiro[4.5]decan-7-one 111 Methyl geraniate2349-14-6 BCHJKL 115 2-ethoxy-4- 5595-79-9 CFGK (methoxymethyl)phenol116 Methyl 40203-73-4 ACEFHIKL cyclopentylideneacetate 125Methoxymelonal 62439-41-2 ACGIJK 133 ((1s,4s)-4- 13828-37-0 BDEFHIJKisopropylcyclohexyl) methanol 147 Linalyl propionate 144-39-8 BDFHJK 150Linalyl formate 115-99-1 ACFHJK 151 Linalyl butyrate 78-36-4 BDEFHJK 154Linalyl acetate 115-95-7 BDHJK 157 Linalool 78-70-6 BCEFGIJK 163(Z)-hex-3-en-1-yl methyl 67633-96-9 ACEFGKL carbonate 166 Lepidine491-35-0 BCEFHIKL 169 L-Carvone 6485-40-1 ACGIJKL 181 Khusinil75490-39-0 DHJK 191 Isoraldeine 1335-46-2 BDHIJK 194Isopropylvinylcarbinol 4798-45-2 ACGIKL 198 Isopropyl 2-methylbutyrate66576-71-4 ACEFGIJKL 201 Isopentyrate 80118-06-5 ADEFGIJKL 204 Isononylacetate 40379-24-6 BDEFHJKL 205 Isononanol 27458-94-2 BDEFGIKL 213Isoeugenyl acetate 93-29-8 CFHJK 214 Isoeugenol 97-54-1 CEFHIK 232Isoborneol 124-76-5 ACEFHIJKL 237 Isoamyl octanoate 2035-99-6 DEFHJK 239Isoamyl isobutyrate 2050-01-3 ACEFGIJKL 255 Hydrocinnamic acid 501-52-0CEFHIK 258 Hydratopic alcohol 1123-85-9 BCEFHIK 264 Hexyl propanoate2445-76-3 ADEFHIKL 270 Hexyl butyrate 2639-63-6 BDEFHJKL 273 Hexyl2-methylbutanoate 10032-15-2 BDEFHJKL 275 Hexyl 2-furoate 39251-86-0DEFHJK 282 Heptyl alcohol 111-70-6 ACEFGIKL 283 Heptyl acetate 112-06-1ADEFHKL 284 Heptaldehyde 111-71-7 ACHIKL 287 Heliotropin 120-57-0 BCGIK302 Geranyl nitrile 5146-66-7 BCEFHKL 306 Geranyl formate 105-86-2BCEFHJK 308 Geranyl caprylate 51532-26-4 DEFHJ 310 Geranyl benzoate94-48-4 DFHJ 312 Geranial 141-27-5 ACHIKL 314 N,2-dimethyl-N- 84434-18-4BCEFHJK phenylbutanamide 319 gamma-Terpinene 99-85-4 ADEFGIJKL 3462-(sec-butyl)cyclohexan-1- 14765-30-1 ADFHIKL one 3543-(2-ethylphenyl)-2,2- 67634-14-4 BDHJK dimethylpropanal 3552-(tert-butyl)cyclohexyl 67801-64-3 BDFHJK ethyl carbonate 3652-(tert-butyl)cyclohexyl 81925-81-7 ACFHIKL ethyl carbonate 366 Fenchylalcohol 1632-73-1 ACGIJKL 376 Eucalyptol 470-82-6 ADEFGIJKL 379 Ethylvanillin acetate 72207-94-4 CHJ 387 Ethyl octanoate 106-32-1 BDEFHJKL400 Ethyl cinnamate 103-36-6 BCEFHK 412 Ethyl 2- 2511-00-4 BDFHIJKL(cyclohexyl)propionate 419 d-p-8(9)-Menthen-2-one 5524-05-0 ACGIJKL 4204-methyl-2-phenyltetra- 94201-73-7 BDEFHJK hydro-2H-pyran 437Dihydromyrcenol 18479-58-8 ADEFGIJK 438 Dihydrojasmone 1128-08-1BCFHIJKL 439 Dihydroisophorone 873-94-9 ACEFGIJKL 440 Dihydroeugenol2785-87-7 CEFHIJK 442 Dihydrocoumarin 119-84-6 BCGIKL 443 Dihydrocarvone7764-50-3 ACGIJKL 447 Dihydro-alpha-terpinyl 80-25-1 BDEFHIJKL acetate448 Dihydro-alpha-ionone 31499-72-6 BDHIJK 454 Dibenzyl ether 103-50-4DEFHJK 455 Dibutyl o-phthalate 84-74-2 DEFHJ 4692-pentylcyclopentan-1-one 4819-67-4 BDFHIKL 472 Decyl anthranilate18189-07-6 DEFHJ 477 Methyl (1s,4s)-1,4- 23059-38-3 ADEFHIJKLdimethylcyclohexane-1- carboxylate 481 Cyclohexylethyl acetate21722-83-8 BDEFHJKL 492 Creosol 93-51-6 BCHIK 495 Cosmene 460-01-5ADEFGIKL 496 4-cyclohexyl-2-methyl- 83926-73-2 BDEFGIJK butan-2-ol 5042-benzyl-2-methylbut-3- 97384-48-0 BDHJK enenitrile 509 Citronellylnitrile 51566-62-2 BCEFGIKL 510 Citronellyl phenylacetate 139-70-8 DFHJ512 Citronellyl formate 105-85-1 BCEFGJKL 515 Citronellyl benzoate10482-77-6 DFHJ 517 Citronellol 106-22-9 BCHIJKL 518 Citronellal106-23-0 ACHIJKL 522 Citral 5392-40-5 ACHIKL 525 cis-Pinane 6876-13-7ADEFGIJKL 526 (Z)-3-methyl-2-(pent-2-en- 488-10-8 BCHIJKL1-yl)cyclopent-2-en-1-one 528 cis-iso-Eugenol 5912-86-7 CEFHIK 535cis-3-Hexenyl valerate 35852-46-1 BDEFHJKL 536 cis-3-Hexenyl tiglate67883-79-8 BDEFHJK 538 cis-3-Hexenyl propionate 33467-74-2 ACEFHIKL 540cis-3-Hexenyl butyrate 16491-36-4 ADEFHJKL 542 cis-3-Hexen-1-ol 928-96-1ACEFHIKL 547 cis-2-Hexenol 928-94-9 ACEFHIKL 549 Cinnamyl nitrile4360-47-8 ACEFGIK 554 Cinnamic aldehyde 104-55-2 ACHIK 556 Cinnamylnitrile 1885-38-7 ACEFGIK 557 Chloroxylenol 88-04-0 BCHIJK 575 Carvacrol499-75-2 DHIJK 576 Carvone 99-49-0 ACGIJKL 579 Carbitol 111-90-0 BCEFGIK583 Caproyl alcohol 111-27-3 ACEFGIKL 585 2-(2,2,3-trimethylcyclo-15373-31-6 ACGIJKL pent-3-en-1-yl)acetonitrile 588 Camphor 76-22-2ACEFGIJKL 602 (E)-2-methyl-4-(2,6,6- 3155-71-3 DHJKtrimethylcyclohex-1-en-1- yl)but-2-enal 605 Borneol 507-70-0 ACEFHIJKL617 beta-Pinene epoxide 6931-54-0 ACEFGIJKL 619 beta-Phellandrene555-10-2 ADEFGIJKL 640 Benzylacetone 2550-26-7 ACEFGIK 641 Benzylsalicylate 118-58-1 DFGJ 645 Benzyl isovalerate 103-38-8 BDEFHJK 647Benzyl isobutyrate 103-28-6 BCHJK 651 Benzyl butyrate 103-37-7 BCEFHJK652 Benzyl alcohol 100-51-6 ACEFGIKL 662 1-(3,3- 25225-08-5 ADEFHIJKLdimethylcyclohexyl)ethyl formate 664 Anisyl acetate 104-21-2 BCEFGK 665Anisyl formate 122-91-8 BCEFGK 667 Anethole 104-46-1 ACEFHK 672 Amylbenzoate 2049-96-9 DEFHJK 687 alpha-Terpinyl acetate 80-26-2 BDHJK 699alpha-methyl- 10528-67-3 BDEFHIK cyclohexanepropanol 701 alpha-methyl101-39-3 ACHIK cinnamaldehyde 703 alpha-Isomethylionone 127-51-5 BDHIJK740 2,5-Dimethyl-4-methoxy- 4077-47-8 ACEFGIJKL 3(2H)-furanone 743 Allylphenoxyacetate 7493-74-5 BCGK 744 Allyl Phenethyl ether 14289-65-7ACEFHK 745 Allyl heptanoate 142-19-8 ADEFHJKL 755 N-ethyl-N-(m-179911-08-1 CEFHJK tolyl)propionamide 760 3-hydroxybutan-2-one 513-86-0ACEFGIKL 761 Acetoanisole 100-06-1 BCEFHIK 777 6-Methylquinoline 91-62-3BCEFHIKL 779 6,8-Diethyl-2-nonanol 70214-77-6 BDEFGIJKL 7845-Methyl-3-heptanone 541-85-5 ACFGIKL 789 4-Vinylphenol 2628-17-3 BCHIK796 4-hydroxy-3-methoxy- 458-36-6 CH cinnamaldehyde 797 4-Ethylguaiacol2785-89-9 CEFHIK 799 4-Damascol 4927-36-0 BDFHJK 8083-methyl-4-phenylpyrazole 13788-84-6 CEFHK 810 3-Methyl-1,2- 765-70-8ACEFGIKL cyclopentanedione 811 3-Methoxy-5-methylphenol 3209-13-0 BCHIK812 3-Methoxy-3-Methyl 56539-66-3 ACGIKL Butanol 817 3-Hexenol 544-12-7ACEFHIKL 819 3,7-dimethyl-2-methylene- 22418-66-2 ADFHIJK 6-octenal 8203,7-dimethyl-1-octanol 106-21-8 BDEFGIJKL 832 2-Phenylethyl acetate103-45-7 BCEFHK 835 2-Phenethyl propionate 122-70-3 BCEFHJK 8362-Pentylcyclopentan-1-ol 84560-00-9 DEFHIKL 838 2-nonanone propylene165191-91-3 BDEFHJK glycol acetal 845 2-Methoxy-3-(1- 24168-70-5 BCEFGIKmethylpropyl)pyrazine 846 2-isopropyl-N,2,3- 51115-67-4 ACEFGIJKtrimethylbutyramide 847 2-Isopropyl-5-methyl-2- 35158-25-9 ADFGIJKLhexenal 848 2-Isopropyl-4-methyl- 15679-13-7 ACHIJKL thiazole 8512-Hexen-1-ol 2305-21-7 ACEFHIKL 858 2-Butoxyethanol 111-76-2 ACEFGIKL875 1,4-Cineole 470-67-7 ADGIJKL 880 1-(2,6,6-Trimethyl-2- 43052-87-5BDHIJK cyclohexen-1-yl)-2-buten- 1-one 882 (Z)-3-hepten-1-yl acetate1576-78-9 ACEFHKL 883 (S)-(1R,5R)-4,6,6- 1196-01-6 ACEFGIJKLtrimethylbicyclo[3.1.1] hept-3-en-2-one 888 (R)-(-)-Linalool 126-91-0BCEFGIJK 889 (1)-Citronellal 5949-05-3 ACHIJKL 891 (d)-Citronellal2385-77-5 ACHIJKL 899 (+)-Citronellol 1117-61-9 BCHIJKL 900(-)-Citronellol 7540-51-4 BCHIJKL 901 (+)-alpha-Pinene 7785-70-8ADEFGIJKL 902 (+)-Carvone 2244-16-8 ACGIJKL 903 (-)-alpha-Pinene7785-26-4 ADEFGIJKL 904 Methyl 2-methylbutyrate 868-57-5 ACEFGIKL 909Hexyl tiglate 16930-96-4 BDEFHJKL 918 Allyl 2- 68901-15-5 CHJK(cyclohexyloxy)acetate 921 1,5- 75147-23-8 CFHIJK dimethylbicyclo[3.2.1]octan-8-one oxime 931 alpha-acetoxystyrene 2206-94-2 ACEFHIK 940p-Cymene 99-87-6 ADGIJKL 956 Phenethyl formate 104-62-1 ACEFHK 958Phenethyl isobutyrate 103-48-0 DHJK 960 Phenethyl tiglate 55719-85-2DHJK 971 Phenylethyl methacrylate 3683-12-3 DHJK 977 P- 4395-92-0 BDFHKIsopropylphenyl- acetaldehyde 981 1,2-dimethyl-3-(prop-1-en- 72402-00-7BCEFGIJKL 2-yl)cyclopentan-1-ol 983 p-Methoxyphenylacetone 122-84-9BCEFHK 986 (2Z,5Z)-5,6,7-trimethylocta- 358331-95-0 ADHIJKL2,5-dien-4-one 987 p-Propyl anisole 104-45-0 ADEFHKL 994 p-t-butylphenyl 109347-45-7 BDHJK acetaldehyde 995 p-tert-Amyl cyclohexanol5349-51-9 BDEFHIJK 1001 Racemic alpha-Pinene 80-56-8 ADEFGIJKL 10024-(4-hydroxyphenyl)butan- 5471-51-2 CEFGIK 2-one 1004 Rhodinol 141-25-3BCHIJKL 1005 Ethyl (2,3,6- 93981-50-1 BDEFHJKL trimethylcyclohexyl)carbonate 1011 1-(3,3- 25225-10-9 ADHIJKL dimethylcyclohexyl)ethylacetate 1017 S)-(+)-Linalool 126-90-9 BCEFGIJK 1018 Sabinene 3387-41-5ADEFGIJKL 1019 Sabinene hydrate 546-79-2 ADEFGIJKL 1030 Propyl(S)-2-(tert- 319002-92-1 BDEFHJK pentyloxy)propanoate 1039 Spirolide699-61-6 BCGIKL 1040 (Z)-5-methylheptan-3-one 22457-23-4 BCEFGIJKL oxime1041 1-phenylethyl acetate 93-92-5 ACEFHIK 1051 Tetrahydrogeranial5988-91-0 ADGIJKL 1052 Tetrahydroionol 4361-23-3 BDEFHIJK 1054Tetrahydrolinalool 78-69-3 BDEFGIJKL 1055 Tetrahydrolinalyl acetate20780-48-7 ADEFHJKL 1058 Ethyl (1R,6S)-2,2,6- 22471-55-2 ADEFHIJKLtrimethylcyclohexane-1- carboxylate 1061 Thymol 89-83-8 BDHIJK 1069trans-2-Hexenol 928-95-0 ACEFHIKL 1071 trans-2-tert- 5448-22-6 ACGIJKLButylcyclohexanol 1074 trans-alpha-Damascone 24720-09-0 BDHIJK 1076trans-Anethole 4180-23-8 ACEFHK 1079 trans-Cinnamic acid 140-10-3 CEFHK1081 trans-Dihydrocarvone 5948-04-9 ACGIJKL 1084 trans-Isoeugenol5932-68-3 CEFHIK 1088 Trichloromethyl phenyl 90-17-5 BDEFGJ carbinylacetate 1098 2-mercapto-2-methyl- 258823-39-1 ACEFHIJKL pentan-1-ol 1110Vanillin acetate 881-68-5 CH 1112 Vanitrope 94-86-0 CEFHK 11152,2,5-trimethyl-5- 65443-14-3 BDFGIJKL pentylcyclopentan-1-one 1118Veratraldehyde 120-14-9 BCGIK 1119 (1R,5R)-4,6,6- 18309-32-5 ACEFGIJKLtrimethylbicyclo[3.1.1] hept-3-en-2-one 1122 Verdol 13491-79-7 ACGIJKL1127 4-(tert-butyl)cyclohexyl 10411-92-4 BDEFHJK acetate 11284-(tert-butyl)cyclohexyl 32210-23-4 BDEFHJK acetate 1133 Vethymine7193-87-5 CEFGK 1134 4-methyl-4-phenylpentan- 68083-58-9 BDFHJK2-ylacetate 1141 (Z)-1-((2- 292605-05-1 ADEFHKLmethylallyl)oxy)hex-3-ene

TABLE 4 List of materials with ALL MORVs from 1 to 5 Number MaterialName CAS Number Comment Code 7 3-methoxy-7,7-dimethyl-10- 216970-21-7BDEFHJK methylenebicyclo[4.3.1]decane 14 Oxyoctaline formate 65405-72-3DFHJK 39 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJKoctahydronaphthalen-1-ol 48 Nootkatone 4674-50-4 DHJK 183 Khusimol16223-63-5 CEFHJK 199 Isopimpinellin 482-27-9 CFGJ 206Iso3-methylcyclopentadecan-1-one 3100-36-5 DEFGJK 212 Isoeugenyl benzylether 120-11-6 DFHJ 215 1-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2 DHJK1,2,3,4,5,6,7,8-octahydronaphthalen- 2-yl)ethan-1-one 229 Isobornylisobutyrate 85586-67-0 BDEFHIJK 260 2,3-dihydro-3,3-dimethyl-1H-indene-173445-44-8 DHJK 5-propanal 261 3-(3,3-dimethyl-2,3-dihydro-1H-173445-65-3 DHJK inden-5-yl)propanal 281 3a,4,5,6,7,7a-hexahydro-1H-4,7-5413-60-5 CEFGJK methanoinden-6-yl acetate 329 gamma-Eudesmol 1209-71-8DFHJK 335 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJKhexahydrocyclopenta[g]isochromene 353 (Z)-6-ethylideneoctahydro-2H-5,8-69486-14-2 CEFGJK methanochromen-2-one 360 8,8-dimethyl-3a,4,5,6,7,7a-171102-41-3 DEFHJK hexahydro-1H-4,7-methanoinden-6- yl acetate 441Octahydro-1H-4,7-methanoinden-5- 64001-15-6 DEFHJKL yl acetate 4843a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK methanoinden-6-ylbutyrate 487 3a,4,5,6,7,7a-hexahydro-1H-4,7- 67634-20-2 DEFHJKmethanoinden-5-yl isobutyrate 488 Curzerene 17910-09-7 DHJK 501(E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ 566 Cedryl formate39900-38-4 BDEFHJK 567 Cedryl acetate 77-54-3 DEFHJK 569 Cedrol 77-53-2DEFHJK 570 5-methyl-1-(2,2,3- 139539-66-5 DEFHJKtrimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 573Caryophyllene alcohol acetate 32214-91-8 DEFHJK 574 Caryolan-1-ol472-97-9 DEFHJK 603 Bornyl isobutyrate 24717-86-0 BDEFHIJK 616beta-Santalol 77-42-9 DEFHJK 621 beta-Patchoulline 514-51-2 BDEFGJKL 624beta-Himachalene Oxide 57819-73-5 BDFHJK 627 (2,2-dimethoxyethyl)benzene101-48-4 DHJK 632 beta-Cedrene 546-28-1 BDEFGJKL 663 Anisylphenylacetate 102-17-0 DFHJ 680 2,2,6,6,7,8,8-heptamethyldecahydro-647828-16-8 ADEFHJK 2H-indeno[4,5-b]furan 684 alpha-Vetivone 15764-04-2DHJK 694 alpha-Santalol 115-71-9 DEFHJK 696 alpha-Patchoulene 560-32-7ADEFHJKL 708 alpha-Gurjunene 489-40-7 BDEFHJKL 712 alpha-Eudesmol473-16-5 DEFHJK 714 alpha-Cubebene 17699-14-8 ADEFHJKL 726alpha-Agarofuran 5956-12-7 BDEFHJK 750 Allo-aromadendrene 25246-27-9BDEFHJKL 764 Acetarolle 744266-61-3 DFHJK 775 7-eip-alpha-Eudesmol123123-38-6 DEFHJK 776 7-Acetyl-1,1,3,4,4,6- 1506-02-1 DEFHJhexamethyltetralin 788 5-Cyclohexadecenone 37609-25-9 DEFGJK 8043-Thujopsanone 25966-79-4 BDEFHJK 872 10-epi-gamma-Eudesmol 15051-81-7DFHJK 919 3a,4,5,6,7,7a-hexahydro-1H-4,7- 17511-60-3 CEFHJKmethanoinden-6-yl propionate 927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJKhexamethylindan 933 Patchouli alcohol 5986-55-0 DEFHIJK 9783a,4,5,6,7,7a-hexahydro-1H-4,7- 68039-44-1 DEFHJK methanoinden-6-ylpivalate 1007 (2R,4a′R,8a′R)-3,7′-dimethyl- 41816-03-9 DEFHJK3′,4′,4a′,5′,8′,8a′-hexahydro-1′H- spiro[oxirane-2,2′-[1,4]methanonaphthalene] 1022 2,2,7,9-tetramethylspiro(5.5)undec-502847-01-0 DHIJK 8-en-1-one 1024 (Z)-2-ethyl-4-(2,2,3- 28219-61-6DEFHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 10275-methoxyoctahydro-1H-4,7- 193425-86-4 CHJK methanoindene-2-carbaldehyde1029 Sclareol oxide 5153-92-4 DEFHJK 1035 Spathulenol 6750-60-3 DEFHJK1038 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3 DGJK 1-one 1060Thujopsene 470-40-6 BDEFGJKL 1089 Tricyclone 68433-81-8 DEFHJK 1107Valerianol 20489-45-6 DEFHJK 1129 1-((3R,3aR,7R,8aS)-3,6,8,8- 32388-55-9DHJK tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan- 1-one 1131 Methyl (Z)-2-(((2,4-68738-99-8 DEFHJ dimethylcyclohex-3-en-1- yl)methylene)amino)benzoate1136 Vetivert Acetate 117-98-6 DEFHJK 1137Decahydro-3H-spiro[furan-2,5′- 68480-11-5 DEFGJKL [4,7]methanoindene]1140 (laR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3 DEFHJKtetramethyldecahydro-1H- cyclopropa[e]azulen-4-ol 11423,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJtetrahydronaphthalene-2-carbonitrile 1143 (1S,2S,3S,5R)-2,6,6-133636-82-5 DEFHJK trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexan]-2′-en-4′-one 1144 1′,1′,5′,5′-tetramethylhexahydro-154171-76-3 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene] 1145 1′,1′,5′,5′-tetramethylhexahydro-154171-77-4 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene] K 1148 4,5-epoxy-4,11,11-trimethyl-8-1139-30-6 DEFHJK methylenebicyclo(7.2.0)undecane 11491,3,4,6,7,8alpha-hexahydro-1,1,5,5- 23787-90-8 DEFHIJKtetramethyl-2H-2,4alpha- methanophtalen-8(5H)-one

TABLE 5 List of materials with ALL MORVs greater than 5 to 10 NumberMaterial Name CAS Number Comment Code 248 Hydroxymethyl 59056-64-3BDEFHJK isolongifolene

TABLE 6 List of materials with ALL MORVs from 0.5 to less than 1 NumberMaterial Name CAS Number Comment Code 472 Decyl anthranilate 18189-07-6DEFHJ 526 (Z)-3-methyl-2- (pent- 488-10-8 BCHIJKL 2-en-1-yl)cyclopent-2-en-1-one

The materials in Tables 1-6 can be supplied by one or more of thefollowing:

Firmenich Inc. of Plainsboro N.J. USA; International Flavor andFragrance Inc. New York, N.Y. USA; Takasago Corp. Teterboro, N.J. USA;Symrise Inc. Teterboro, N.J. USA; Sigma-Aldrich/SAFC Inc. Carlsbad,Calif. USA; and Bedoukian Research Inc. Danbury, Conn. USA.

Actual MORV values for each material listed in Tables 1-6 above are asfollows:

Material MORV value for MORV Value MORV Value MORV value for No.Equation a.) for Equation b.) for Equation c.) Equation d.) 10.548223914 0.876283261 1.22018588 −0.41901144 2 1.520311929 3.4934504462.70657265 5.11342862 3 2.267801995 −0.81712657 0.43218875 1.595983683 4−0.591063369 −0.48283571 0.16199804 1.210497701 7 1.4374446362.131822996 3.81633465 1.318339345 9 2.151445882 −0.46189495 0.560904691.206360803 10 2.5733592 −0.58780849 1.39751471 1.258361951 113.052627325 1.008519135 −0.30475953 0.076323462 12 0.683776599−0.01157903 0.82853231 0.326169402 13 1.549643217 1.809183231 0.708645312.22799611 14 2.82111224 2.339505033 1.240818 2.502429355 16 −0.31551128−0.06816599 −0.04371934 2.76742389 17 −1.334904153 −0.5773313 1.756447981.898455724 18 −1.34154226 −2.63596666 0.06885109 1.001431671 190.15532384 0.09866097 0.64214585 −0.33330779 20 0.640261783 0.6932132680.54637273 −0.97556029 21 0.936895364 −0.01521118 1.1697513 −0.6351080922 1.158981042 1.115900089 −0.25859776 1.318200884 23 3.7023610741.399942641 5.23954766 7.089933671 24 0.773874141 0.146848137−1.05705847 −0.36193173 25 −1.016103969 −1.18967936 0.780646252.944710012 25 −1.016103969 −1.18967936 0.78064625 2.944710012 260.615085491 −0.00096877 −0.35697252 −0.18121401 27 0.70261974−0.22197386 0.19710806 −2.37196477 28 1.366472597 −0.42546942−0.59394241 −0.01417395 29 1.096043453 −1.02972898 −1.42167356−0.63817943 30 1.143415203 −0.85945441 −0.41416913 2.499807942 311.138642907 −0.19595476 −0.54547769 −0.98828898 32 1.914414495−0.64487788 0.63212987 1.166699371 33 0.314847366 1.848003955 −1.3905032−0.62848261 34 −0.113542761 0.981530917 0.32824239 1.126524277 350.472382903 1.494882467 −0.07201236 −0.64589543 36 3.1585137951.084094934 −0.00328981 −0.17786385 37 −1.055631982 2.2401729640.92596118 2.105391988 38 3.158513795 0.592820874 −0.493262410.212867212 39 1.083800659 2.069727985 2.48170879 3.205630609 42−0.103134861 0.267726008 −0.65350189 1.125952363 43 0.3239616281.469295081 −0.52991193 0.797908251 47 1.703678841 1.3487370952.00634162 −0.16505407 48 2.370955056 2.783472865 2.68240273 1.22186440549 1.670680003 −0.41866107 −0.9173849 1.181929544 50 1.6706800030.076369374 −0.49915943 −0.85392575 52 0.464485039 0.0575128691.31230219 −0.11170276 53 0.626671823 −0.46954947 −0.333837360.277079201 54 0.666149043 0.009549925 −0.36226343 0.197224432 550.723473579 −1.50916383 −0.3848989 −0.71458778 57 0.3812732271.192994109 1.65593321 −1.65739236 59 0.561360663 −0.17793966−1.63250554 −0.7564969 61 0.146473611 −0.01535544 −0.163396581.738656146 62 1.20162032 −0.3576095 −0.10695443 1.322155191 631.084291915 2.258720158 −1.01245416 1.688283974 64 0.7447706650.155243763 −1.8029919 1.023503542 65 0.972835178 2.797151284 1.534535790.857051645 67 2.069410561 0.021831924 0.37855159 −0.67235457 680.527636614 0.590831983 1.02843762 2.208655795 69 2.1339656912.088998449 2.05751412 −0.9433713 70 0.327378959 0.996844599 1.23648533−1.25138371 71 1.40093669 0.778222691 0.70401172 −0.24075444 720.617697349 −0.29503359 0.52404847 0.816184656 73 0.6177924730.888976061 −0.45289639 0.615659244 74 1.437359024 1.5482921470.10314807 −0.48982286 75 −1.970885622 3.398008325 4.08025266−0.89948156 76 −1.32746934 −2.65365233 0.10272816 1.001614125 77−2.541686116 3.295534192 3.75284227 0.404837808 78 −2.110794 2.1098747463.13350902 −0.3880285 79 1.641162056 −0.28533994 1.53676145 0.65269602380 1.594400214 0.283682865 2.23140233 1.111682021 81 0.176566806−2.0786518 −2.13986952 0.981126964 82 0.980373758 −0.28813159 0.194045011.252564677 83 0.941833098 0.317310013 1.17606727 0.72992237 840.774237336 −0.27140727 0.72461427 −1.56415746 85 2.0929769650.810644229 0.82999192 −0.62861806 91 2.061595915 −0.79930338−0.18285395 −0.66898499 92 2.068748434 −0.24299896 0.07214682−1.11758276 93 −0.08984279 −1.06025959 −0.05068694 1.560050105 960.927758203 −0.44129515 0.89190422 0.744284978 97 0.658667572−0.68771072 0.46051026 −0.53120883 98 0.853222693 −0.2037738 −0.214144411.119784962 100 1.654535066 0.995056228 2.35139085 0.543654824 1012.173663649 −0.11491477 1.48285148 1.698527571 102 2.066679492−0.16785146 −0.84780149 0.12159477 103 2.335152618 −0.028665850.16993375 −0.98254522 104 2.760588276 0.459513599 1.353102410.000336976 105 1.654535066 3.654489674 3.13033965 0.544225478 1061.750588169 −0.55853348 0.50257773 1.630011313 107 0.8967898630.73615897 0.53011623 −0.54697747 108 0.532375207 0.826537134 1.210403120.690230716 109 2.407655187 0.742651426 1.80322099 0.271832856 1100.54830833 2.916795026 1.40126098 0.690230716 111 0.939597126 −0.3750368−1.23479972 −0.89366351 112 1.398518854 1.265740274 4.19618377−0.12762692 113 1.415726941 0.086297006 3.43559555 −0.12964168 115−1.557729423 −0.44113526 0.86330536 0.590708892 116 0.193562268−1.58091165 0.83247813 −0.70978039 117 1.353510875 −0.59062398−0.31776345 −0.3050158 119 0.830052725 2.28725579 0.38409695 0.219336109120 1.261997955 −0.22622961 −1.04772194 2.028504137 122 1.505653628−1.14748206 −0.19760084 −0.81373045 123 −0.658721962 −0.212998781.01439841 −0.76731016 125 0.749676998 −1.0761601 0.99563924 −1.15409002126 0.931054384 −0.35067079 1.06050832 −1.62171794 128 −1.344832644−0.09451199 1.19145467 1.621274257 130 1.153249538 1.6050707082.38047907 −0.93842293 133 0.840066046 0.2323025 0.19054023 −0.26588341134 0.522267541 0.824106618 1.83479545 0.364403434 135 2.1428178872.142411243 −0.93830995 0.696522652 137 3.052627325 3.6062701660.50445208 0.076323462 140 −0.153437637 0.246303216 0.765657581.800968868 141 2.067620311 1.424830396 2.33536931 7.644025075 1420.98353103 1.950251373 2.50851828 −0.24499521 143 1.7369697250.991537809 2.5691601 1.227191656 145 −0.211768579 1.46336231−0.93580247 −1.48749449 146 1.912710035 0.926306508 1.812533330.494121361 147 0.675736703 0.99202385 −0.66034472 −0.66302669 1480.757176542 1.83006252 0.16210659 0.243674851 149 0.4387723711.091438092 −0.1560319 −0.61711642 150 0.84399938 0.675302022−1.69771411 −0.73841711 151 0.633570539 0.988413715 −0.54991825−0.43550324 152 0.911582356 1.974700218 −0.92267786 0.628660087 1530.319053885 2.531735341 −0.39139184 0.734629224 154 0.7148145120.690769753 −2.06588692 −0.73356628 155 −0.161798388 0.032135767−0.13802086 1.734928461 156 −0.571799976 −1.32834264 −1.653460171.856689553 157 0.131224024 0.21510779 −1.70996346 0.964902175 1581.201616145 −0.21158932 −0.8501176 −0.33330779 159 0.8112899081.606645397 0.25352447 −1.83775117 159 0.811289908 1.6066453970.25352447 −1.83775117 161 0.475184006 1.99305646 1.90910177 3.288337059162 0.833030517 0.487189028 1.76798642 0.104378164 163 0.58993703−0.46431772 0.74883588 −0.81090824 166 −0.121286831 −0.84664528−0.32625341 0.778055656 167 0.846400186 −0.25922232 0.692487741.183696217 168 −0.310930833 −0.81048493 0.08527131 1.61831109 169−0.2346025 0.890438419 −0.13206526 −0.83961838 170 −0.1692236951.172917966 −0.11306441 0.099121666 174 2.863652137 0.236674094−0.69038707 1.610215283 175 1.789769228 −0.31740428 −0.89529921−0.09686469 176 2.625947334 0.083548191 0.30634559 −0.35925728 1771.674319352 −0.22179044 0.42093738 −0.23683577 178 2.8636521370.727069168 −0.26724686 −0.44888613 179 0.070511885 0.3658528641.35327505 −0.03748038 181 0.976254543 0.691638796 0.51371978−0.02503945 182 −1.842503751 −0.12688474 2.56277877 0.111744488 1833.195758563 3.886545621 4.29482769 3.829845293 184 0.333889534−0.67236766 2.21605977 4.254612125 185 5.61162203 1.40458529 2.862313431.035135749 186 1.068190511 −0.65969343 −0.63104765 −1.36962992 1871.396358739 0.249705611 0.81449499 −0.15353102 189 1.544466636−0.33742685 0.8096674 −0.44483677 190 −0.210918777 −1.040860630.02614862 3.362615492 191 0.715897301 0.666316436 −0.417195380.400723176 192 0.65612864 1.231196814 0.75462061 1.514581532 193−0.394884432 1.129269425 −0.3157071 −0.61478944 194 −2.111794245−0.71010521 0.53077207 0.59302222 195 1.18880856 0.704463775 1.993127771.419709023 196 1.885714606 0.436434665 1.44657532 1.145809063 1972.174580668 0.133070149 0.99814905 0.871658496 198 −0.533922573−2.16213117 0.5812107 −0.92280453 199 1.493919434 1.45125612 1.951413714.403441058 201 −0.005520296 −0.83362523 0.65480762 −0.38894276 2040.732981164 −0.97494758 −0.91192246 −1.00034323 205 0.991838899−0.60053505 −0.49983634 0.674468753 206 2.147983695 1.2913519581.64553247 1.626455601 208 −0.386224123 −0.24799559 1.19406353−1.61243489 209 1.447075297 0.122626462 1.08021156 0.473154634 210−0.386224123 −0.24799559 1.19406353 −1.61243489 211 2.1861184671.873949371 0.64852028 −0.59205851 212 1.367811201 1.689658923 1.80173762.525531645 213 0.925016223 0.875610609 0.31462609 0.847028648 214−0.239873321 1.808823425 −0.36105512 −0.07650286 215 2.2642750881.360001278 3.25759951 2.147928282 218 −0.509585598 −0.934286431.63030386 −0.79436377 221 1.876297063 0.026873469 0.454427581.538486988 227 5.317676982 2.824566654 1.73360625 3.103310061 2283.323728685 1.554268023 1.8883835 0.957527434 229 3.2189501751.464118271 2.47512497 1.214429025 230 5.242356467 3.4822067153.50441556 1.614847073 230 5.242356467 3.482206715 3.504415561.614847073 231 2.710087358 1.517756148 0.35088855 0.603171932 2312.710087358 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974 0.130904221 1.882440008 1.85101055 0.112524893 976−0.236681385 −0.09745533 0.1779313 2.08923366 977 0.9044026120.936956925 0.87731788 0.102346515 978 2.201759817 2.123549573 3.78816072.358768953 980 1.784266982 1.845281076 3.42873622 −0.31098233 981−0.225023329 0.087962898 −0.29053012 0.514272787 982 −0.231175318−0.0159671 1.27391892 1.090487158 983 0.889215441 0.24321159 0.068776290.816247177 985 1.864634345 0.133647536 1.29803755 1.951226654 9860.511450274 −2.33512445 −0.56246315 −0.42184152 987 0.8472608130.368638185 0.4114346 0.219336109 988 1.596170102 1.592158381 0.300523570.283467897 993 −3.549941097 −2.6847861 −0.17502622 1.41034664 9940.445802042 0.899738574 0.61059602 0.323194673 995 0.9494987240.357111159 0.28371155 −0.14156488 998 2.197271885 1.5788718260.90563334 1.056619658 998 2.197271885 1.578871826 0.905633341.056619658 1000 1.456120673 0.626173572 0.07683183 −0.43324035 1001−0.440378333 0.918089245 0.03050609 −1.62235977 1002 0.8199290660.459101825 −0.09227583 0.324342063 1003 1.64412453 −0.093433990.70197344 3.710273595 1004 0.796928207 0.459954079 −0.885386160.152000937 1005 0.044923203 −0.19994963 0.60082875 0.258347835 1006−0.320452673 −0.33232662 −0.52315783 1.406273663 1007 4.0402911333.474551355 3.57146797 3.565985043 1008 0.764519082 0.9176351022.88258762 2.319622474 1009 −0.071112206 0.539362906 2.980487320.580423329 1010 −0.689737481 0.547928768 1.98805626 −0.76653376 10110.343668917 0.931501008 −0.05483722 0.395369857 1012 1.9267131310.124849138 −0.09654906 1.126499382 1016 0.124247716 0.1931027120.39003599 1.737670628 1017 0.131224136 0.21510779 −1.709963460.964902175 1018 0.499624069 0.962843507 0.77617619 −1.15296947 10190.813491983 0.322635656 0.02800396 0.599500927 1020 0.7154681141.015469049 1.45994989 0.352548581 1021 −1.176339404 1.539767848−0.14427147 1.389902738 1022 1.364966718 1.690570939 2.059141942.364375484 1023 2.154641091 0.800066339 0.85365652 0.965810338 10242.302280068 1.252164308 1.73414439 1.549538352 1025 1.8783315151.287303121 0.11530502 1.132065786 1026 2.97722987 2.0964419653.87172868 0.550274831 1027 2.474381478 1.950326182 3.818618671.366897355 1028 1.778414353 3.114931059 4.47690731 6.054314034 10293.672910795 2.760483725 3.26915034 3.042677588 1030 −0.604959715−2.13584086 0.8687855 0.024144016 1031 2.012732245 2.2938571610.54405555 1.261882121 1032 −1.086688867 0.953083194 2.921770540.876865185 1033 1.617520676 1.008017006 2.21183536 −0.1288484 10352.506372295 3.419954592 4.58206882 4.134341651 1036 −0.675805062−0.15357004 0.94597719 3.966016669 1037 −0.275092569 −0.67687665−0.52763797 1.489972106 1038 2.753559643 3.81185814 2.713447342.243351472 1039 0.65087433 0.026885305 −0.0153558 0.011870127 10400.141526548 −1.65455278 0.50170705 −1.90794 1041 0.458680435 −0.69730218−0.48806249 0.586073092 1042 −0.513264812 −0.22001961 0.363395191.03208599 1043 −1.497887014 −1.76116109 −0.76634926 1.137002742 10452.863652137 1.96790869 0.43661485 −0.44756897 1046 0.9811942481.73892162 2.21166953 2.738129365 1047 0.981194248 1.73892162 2.211669532.738129365 1051 0.70261974 −0.22197386 0.19710806 −2.37196477 10520.662126832 0.741436531 0.61672724 0.289359903 1053 0.87463644−0.19717783 1.2664131 −0.4187507 1054 0.284558077 −1.46754925−0.03124571 0.587227244 1055 0.885837831 −0.91907796 −0.45817355−1.1936897 1057 0.790964847 1.387925398 −0.18370692 1.302393792 1058−1.052897931 −0.85226912 0.90324527 −1.09684959 1059 −0.871565421−0.17856476 1.51267137 −1.52734367 1060 3.311161199 3.0747839212.10199297 1.822541682 1061 −0.655128061 0.497032417 0.92381279−0.56348341 1062 −0.443129049 0.96200606 1.51641349 −0.22974864 10631.385675542 0.738759296 1.1677069 0.501211562 1064 1.670680003−0.20756775 −0.73755051 −0.84924056 1065 1.43532227 1.656262941−1.09448841 1.674272267 1066 1.670680003 1.284791101 0.14864516−0.84985664 1067 2.237616041 0.345329863 −0.60597063 −0.71581056 1069−0.24632881 −0.23975349 −0.01449288 0.574861147 1070 1.6706800030.070165381 −0.64700996 −0.85055617 1071 −1.02687397 −0.362442730.13010074 0.535909448 1072 1.670680003 1.94609957 0.19633838 1.148257641073 2.237616041 1.438074134 0.31117554 −0.71786492 1074 −0.1926329110.142411101 0.79310676 0.125548041 1075 0.909356011 0.3685978871.03689838 1.001198751 1076 0.812238101 0.195908668 0.215646640.219336109 1077 0.325255266 1.131242708 −2.79377204 −0.62848261 10780.325255266 1.131242708 −2.79377204 −0.62848261 1079 0.85330799−0.6855194 −0.90046979 −0.46415796 1081 −0.131519393 0.7318360140.81604919 −1.29993979 1082 0.744770665 0.155243763 −1.80299191.023503542 1083 1.415726941 0.086297223 3.43559555 −0.12964168 10840.161304111 0.66712144 0.58401752 0.373809692 1085 −0.72863532−0.2873027 2.21251376 3.003873022 1088 −1.1773616 −0.23258175 0.405291950.994988969 1089 2.769817302 1.661618789 3.97585272 1.059236597 10903.052627325 0.420821685 −0.57080756 1.751222205 1091 -3.379896722−3.71174986 2.53586709 0.644702886 1093 0.72304265 1.6670114762.53982093 2.7903213 1095 0.744219765 1.372184572 0.15852396 1.1260534421097 4.407270402 2.670641491 5.02636153 5.361271976 1098 −1.85804837−2.59071226 −0.46522239 0.655734646 1099 0.745797788 −0.205473784.27836342 4.646390386 1102 2.068748434 −0.24299896 0.07214682−1.11758276 1104 1.018876287 0.025163067 −0.1106021 0.838914654 11052.387326861 3.865456674 2.2251199 0.728667998 1107 2.3525820592.595496601 3.20492728 2.844590737 1110 0.302703712 0.599942142−0.25637571 −0.03195517 1111 0.750930333 0.656784751 1.683264130.329846578 1112 −0.205527848 0.287622624 −0.00340777 0.59203719 11150.999825037 0.662221152 0.43571192 0.342558518 1116 0.8733812631.544324176 0.13703728 −0.38172701 1117 −0.682983903 1.7982043022.42110319 −0.39173951 1118 0.069769623 0.496895599 0.67857133−0.14954441 1119 −0.671908804 −0.65984824 0.5238174 −0.85314111 11200.953790113 1.106552668 3.00006904 1.585038764 1121 −1.1846309732.476138312 4.80971952 2.450646806 1122 −1.02687397 −0.362442730.13010074 0.535909448 1125 0.387315524 −0.36101406 1.14153708−0.75303953 1126 1.021783831 −0.0070257 −0.14327539 3.954381426 11270.990592079 0.305612583 0.14155512 −0.29526854 1128 0.9905920790.305612583 0.14155512 −0.29526854 1129 3.18966648 3.2843629874.49398568 3.950809104 1131 1.650621055 1.545704806 2.375350811.259373143 1133 −1.519747805 −0.60804324 0.02746106 0.590708892 11340.815942067 −0.16126019 −0.54117238 0.613093526 1135 0.6269733851.998305877 2.61706075 1.570404253 1136 2.812199484 1.3531981462.05618426 1.869204406 1137 2.208307057 1.387136198 3.215213742.069795393 1138 1.670680003 1.316442078 0.14822999 −0.46985154 11391.408517438 0.890457374 1.24524408 0.685687797 1140 2.7658609522.525539595 4.12464228 3.833744077 1141 −0.484394663 0.677713073−0.22783646 −0.37267608 1142 2.54335679 4.298105601 3.362342382.684404542 1143 4.204367611 3.062126931 3.4234313 2.072899554 11442.479165229 3.226545885 4.65897152 4.952127235 1145 2.4791589213.226545885 4.65897152 4.952127235 1146 0.774334025 1.0758007741.06893156 1.011113116 1147 0.844648531 1.21935371 2.591385950.805938034 1148 2.906236436 1.550674121 3.56959167 2.832126896 11492.837627443 3.707154326 4.53384262 2.625871865

Articles and Methods

An article comprising

-   -   a) a substrate, preferably a flexible substrate, more preferably        a flexible substrate that is a sheet; preferably said substrate        comprises a fabric softening active, preferably said fabric        softening active coats all or a portion of said substrate;    -   b) a sum total from about 0.00025% to about 1%, preferably from        about 0.0025% to about 0.1%, more preferably from about 0.005%        to about 0.075%, most preferably from about 0.01% to about 0.05%        of 1 or more malodor reduction materials, preferably 1 to about        20 malodor reduction materials, more preferably 1 to about 15        malodor reduction materials, most preferably 1 to about 10        malodor reduction materials, each of said malodor reduction        materials having a MORV of at least 0.5, preferably from 0.5 to        10, more preferably from 1 to 10, most preferably from 1 to 5,        and preferably each of said malodor reduction materials having a        Universal MORV, said sum total of malodor reduction materials        having a Blocker Index of less than 3, more preferable less than        about 2.5 even more preferably less than about 2 and still more        preferably less than about 1 and most preferably 0 and/or a        Blocker Index average of 3 to about 0.001        is disclosed.

In one aspect of said article, said malodor reduction materials have aFragrance Fidelity Index of from about less than 3, more preferable lessthan about 2.5 even more preferably less than about 2 and still morepreferably less than about 1 and most preferably 0 or a FragranceFidelity Index average of 3 to about 0.001.

In one aspect of said article, said article comprises a perfume, saidarticle having a weight ratio of parts of malodor reduction compositionto parts of perfume of from about 1:20,000 to about 3000:1, preferablyfrom about 1:10,000 to about 1,000:1, more preferably 5,000:1 to about500:1 and most preferably from about 1:15 to about 1:1.

In one aspect of said article, said article comprises one or moremalodor reduction materials having a log P greater than 3, preferablygreater than 3 but less than 8, preferably said one or more malodorreduction materials are selected from the group consisting of Table 1materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30;31; 32; 33; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68;69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102;103; 104; 105; 109; 114; 119; 120; 122; 123; 128; 134; 135; 137; 140;142; 145; 148; 149; 152; 153; 158; 159; 161; 162; 174; 175; 176; 177;178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209;210; 211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242;243; 244; 246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277;280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316;317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338;339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364;368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398;413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453;457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478;479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519;520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552; 558; 559;560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573; 574;577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 601; 603; 604; 606;607; 608; 609; 610; 611; 613; 614; 615; 616; 618; 620; 621; 624; 625;626; 628; 631; 632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671;673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693;694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712;713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725; 726;727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771;774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821;826; 827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869;870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892;893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927;930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959;965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009;1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035;1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070;1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102;1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137;1138; 1140; 1142; 1143; 1144; 1145; 1147; 1148; 1149; Table 2 materials2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659; 674; 678; 679;715; 758; 1028; 1097; Table 3 materials 1; 9; 12; 13; 19; 20; 21; 24;25; 27; 32; 38; 54; 55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105;109; 111; 114; 119; 133; 134; 135; 137; 140; 142; 147; 148; 150; 151;152; 153; 154; 157; 159; 162; 178; 181; 189; 191; 192; 195; 197; 204;211; 228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273; 275;277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 302; 306; 308; 310;312; 319; 322; 325; 331; 333; 334; 336; 338; 339; 344; 346; 354; 355;356; 358; 361; 362; 363; 370; 371; 372; 378; 381; 385; 387; 388; 390;412; 413; 418; 420; 428; 429; 432; 437; 438; 444; 447; 448; 454; 455;457; 461; 465; 467; 472; 477; 478; 479; 480; 481; 482; 495; 496; 497;502; 503; 504; 509; 510; 512; 515; 517; 518; 522; 525; 529; 535; 536;537; 540; 541; 544; 550; 557; 558; 559; 560; 561; 568; 571; 572; 575;589; 592; 594; 599; 600; 602; 604; 609; 619; 620; 625; 626; 633; 641;644; 645; 650; 653; 662; 667; 672; 673; 675; 676; 681; 686; 687; 693;697; 698; 700; 703; 704; 706; 707; 716; 717; 718; 722; 725; 744; 745;746; 757; 769; 771; 779; 782; 799; 806; 819; 820; 827; 828; 836; 838;839; 847; 850; 875; 878; 879; 880; 881; 888; 889; 890; 891; 893; 899;900; 901; 903; 909; 912; 914; 920; 922; 930; 939; 940; 941; 945; 947;948; 953; 954; 958; 959; 960; 965; 967; 971; 986; 987; 994; 995; 998;1000; 1001; 1003; 1005; 1008; 1009; 1010; 1011; 1017; 1018; 1023; 1031;1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057; 1058; 1061; 1062;1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095; 1099; 1102; 1104; 1105;1115; 1116; 1120; 1127; 1128; 1134; 1135; 1141; 1147; 1148, 1149, andmixtures thereof; preferably said malodor reduction materials areselected from the group consisting of Table 1 materials 1; 2; 3; 7; 9;10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 33; 35; 36; 38;39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77;78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114;119; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152;153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184; 185;186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221;227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253;260; 261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292;293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325;328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344; 349;352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372;378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421;424; 426; 428; 429; 432; 441; 444; 449; 453; 457; 459; 461; 462; 463;465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482; 484; 486;487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532;534; 537; 541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565;566; 567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589;591; 592; 594; 599; 600; 601; 603; 604; 606; 607; 608; 609; 610; 611;613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633;635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677;678; 679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700;702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717;718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750;752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778; 781;782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828; 831; 837;839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876;877; 878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912;913; 914; 916; 919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942;943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985;988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023;1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047;1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078;1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116;1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143;1144; 1145; 1147; 1148; 1149; Table 2 materials 2; 23; 185; 227; 230;246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097and mixtures thereof; more preferably said malodor reduction materialsare selected from the group consisting of Table 4 materials 7; 14; 39;48; 183; 206; 212; 215; 229; 260; 261; 329; 335; 360; 441; 484; 487;488; 501; 566; 567; 569; 570; 573; 574; 603; 616; 621; 624; 632; 663;680; 684; 694; 696; 708; 712; 714; 726; 750; 775; 776; 788; 804; 872;919; 927; 933; 978; 1007; 1022; 1024; 1029; 1035; 1038; 1060; 1089;1107; 1129; 1131; 1136; 1137; 1140; 1142; 1143; 1144; 1145; 1148, 1149Table 5 material 248 and mixtures thereof, most preferably said materialis selected from the group consisting of Table 4 materials 261; 680;788; 1129, 1148, 1149 and mixtures thereof. All of the aforementionedmaterials have a log P that is equal to or greater than 3, thus theydeposit through the wash especially well. The more preferred and mostpreferred of the aforementioned material are particularly preferred asthey are effective at counteracting all of the key malodors.

In one aspect of said article, said malodor reduction materials are notselected from the group consisting of Table 1-3 malodor reductionmaterials 302; 288; 50; 157; 1017; 888; 64; 1054; 832; 375; 390; 745;504; 505; 140; 1012; 498; 362; 103; 356; 1074; 908; 1127; 475; 918; 687;611; 317; 9; 141; 550; 602; 913; 1005; 521; 10; 215; 370; 335; 378;1121; 360; 565; 1136; 1129; 655; 369; 1065; 914; 757; 601; 478; 889;891; 358; 973; 162; 554; 522; 312; 125; 26; 418; 92; 586; 1026; 218; 31;828; 871; 829; 1066; 287; 269; 769; 701; 1118; 70; 946; 142; 109; 108 ormixtures thereof.

In one aspect of said article, said article having a weight ratio offabric softener active to dry substrate ranging from about 10:1 to about0.5:1, preferably from about 5:1 to about 1:1, preferably said fabricsoftener active is selected from the group consisting of a quaternaryammonium compound, a silicone polymer, a polysaccharide, a clay, anamine, a fatty ester, a dispersible polyolefin, a polymer latex andmixtures thereof.

In one aspect of said article, said article comprises a quaternaryammonium compound selected from the group consisting ofbis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester,1,2-di(acyloxy)-3-trimethylammoniopropane chloride, N,N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride,N,N-bis(tallowoyl-oxy-ethyl) N,N-dimethyl ammonium chloride,N,N-bis(stearoyl-oxy-ethyl)N-(2 hydroxyethyl)N-methyl ammoniummethylsulfate, 1, 2 di(stearoyl-oxy) 3 trimethyl ammoniumpropanechloride, dicanoladimethylammonium chloride,di(hard)tallowdimethylammonium chloride dicanoladimethylammoniummethylsulfate, 1-methyl-1-stearoylamidoethyl-2-stearoylimidazoliniummethylsulfate, 1-tallowylamidoethyl-2-tallowylimidazoline, DipalmethylHydroxyethylammoinum Methosulfate and mixtures thereof.

In one aspect of said article, said article comprises a fabric softeningactive having an Iodine Value of between 0-140, preferably 5-100, morepreferably 10-80, even more preferably, 15-70, most preferably 18-25.

In one aspect of said article, said article comprises an adjunctingredient selected from the group consisting of surfactants, builders,chelating agents, dye transfer inhibiting agents, dispersants, enzymes,and enzyme stabilizers, catalytic materials, bleach activators, hydrogenperoxide, sources of hydrogen peroxide, preformed peracids, polymericdispersing agents, clay soil removal/anti-redeposition agents,brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfumedelivery systems, structure elasticizing agents, carriers, structurants,hydrotropes, processing aids, solvents, pigments and mixtures thereof.

A method of controlling malodors comprising: contacting a situscomprising a malodor or that will develop a malodor with an one or moreof the articles Applicants' disclose herein, is disclosed.

In one aspect of said method, said situs comprises a fabric and saidcontacting step comprises contacting said fabric with a sufficientamount of Applicants' article containing Malodor reducing composition toprovide said fabric with a level of malodor reduction material at least0.0025 mg of malodor reduction material/kg of fabric, preferably fromabout 0.00025 mg of malodor reduction material/kg of fabric to about 25mg of malodor reduction material/kg of fabric, more preferably fromabout 0.025 mg of malodor reduction material/kg of fabric to about 20 mgof malodor reduction material/kg of fabric, most preferably from about0.25 of malodor reduction material/kg of fabric to about 10 mg ofmalodor reduction material/kg of fabric of said sum of malodor reductionmaterials.

Softener Actives

The article of the present invention can comprise at least one fabricconditioning compound. Typical levels of said fabric conditioningcompounds within the conditioning compositions are from 1% to 99% byweight of the compositions. However, compositions of the presentinvention can also contain from about 1% to about 80%, preferably fromabout 20% to about 70%, more preferably from about 25% to about 60% offabric conditioning component.

The fabric conditioning compound, or compounds, can be selected fromcationic, nonionic, amphoteric and/or anionic fabric conditioningcompounds. Cationic and/or nonionic conditioning compounds are preferredas they provide effective fabric softening and/or anti-static benefitsand/or care benefits when applied to fabrics in the dryer. Thesecompounds also aid in the delivery of odor/freshening ingredients andbenefits when transferred to fabrics in the dryer.

Cationic Fabric Conditioning Compounds

The typical cationic fabric conditioning compounds include thequaternary-ammonium fabric conditioning actives, the most commonly usedhaving been di(long alkyl chain)dimethylammonium (C1-C4 alkyl) sulfateor chloride, preferably the methyl sulfate. Quaternary ammonium fabricconditioning compounds include the following:

DTDMAMS

-   dipalmityldimethylammonium methyl sulfate-   distearyldimethylammonium methyl sulfate;-   dioleyldimethylammonium methyl sulfate;-   di(tallowoyl)dimethylammonium methyl sulfate (DTDMAMS);-   di(hydrogenated tallowoyl)dimethylammonium methyl sulfate;-   di(C₁₂₋₁₆ alkyl)dimethylammonium methyl sulfate;

MTDMAMS

-   palmoyltrimethylammonium methyl sulfate-   stearoyltrimethylammonium methyl sulfate-   oleoyltrimethylammonium methyl sulfate-   tallowoyltrimethylammonium methyl sulfate-   (hydrogenated tallowoyl)trimethylammonium methyl sulfate;-   (C₁₂₋₁₆ alkyl)trimethylammonium methyl sulfate

OTHERS NonBiodegradable

-   di(hydrogenated tallowoyl)dimethylammonium chloride (DTDMAC);-   stearylbenzyldimethylammonium methyl sulfate;-   ditallowalkylimidazolinium methyl sulfate;

The currently preferred compounds are more environmentally-friendlymaterials, being rapidly biodegradable quaternary ammonium compoundsthat are alternatives to the traditionally used di(long alkylchain)dimethylammonium methyl sulfate. Such quaternary ammoniumcompounds can contain long chain alk(en)yl groups interrupted byfunctional groups such as carboxy groups.

A preferred fabric conditioning compound is an ester quaternary ammoniumcompound (EQA), their ester amine precursors, and mixtures thereof. By“amine precursors thereof” is meant the secondary or tertiary aminescorresponding to the above quaternary ammonium compounds.

The preferred compounds can be considered to be diester quaternaryammonium salts (DEQA). At least about 25% of the DEQA is in the diesterform, and from 0% to about 40%, preferably less than about 30%, morepreferably less than about 20%, can be EQA monoester (As used herein,when the diester is specified, it will include the monoester that isnormally present. For the optimal antistatic benefit the percentage ofmonoester should be as low as possible, preferably less than about 2.5%.The level of monoester present can be controlled in the manufacturing ofthe EQA.

EQA compounds prepared with fully saturated acyl groups are excellentsofteners. However, it has now been discovered that compounds preparedwith at least partially unsaturated acyl groups have advantages (i.e.,antistatic benefits) and are highly acceptable for consumer productswhen certain conditions are met. Variables that must be adjusted toobtain the benefits of using unsaturated acyl groups include the IodineValue of the fatty acids, the odor of fatty acid starting material,and/or the EQA. Any reference to Iodine Value values hereinafter refersto Iodine Value of fatty acyl groups and not to the resulting EQAcompound.

Some highly desirable, readily available sources of fatty acids such astallow, possess odors that remain with the compound EQA despite thechemical and mechanical processing steps which convert the raw tallow tofinished EQA. Such sources must be deodorized, e.g., by absorption,distillation (including stripping such as steam stripping), etc., as iswell known in the art. In addition, care must be taken to minimizecontact of the resulting fatty acyl groups to oxygen and/or bacteria byadding antioxidants, antibacterial agents, etc.

Generally, hydrogenation of fatty acids to reduce polyunsaturation andto lower Iodine Value to insure good color and odor stability leads to ahigh degree of trans configuration in the molecule. Therefore, diestercompounds derived from fatty acyl groups having low Iodine Value valuescan be made by mixing fully hydrogenated fatty acid with touchhydrogenated fatty acid at a ratio which provides an Iodine Value offrom about 3 to about 60. The polyunsaturation content of the touchhardened fatty acid should be less than about 5%, preferably less thanabout 1%. During touch hardening the cis/trans isomer weight ratios arecontrolled by methods known in the art such as by optimal mixing, usingspecific catalysts, providing high availability, etc. It has also beenfound that for good chemical stability of the diester quaternarycompound in molten storage, water levels in the raw material must beminimized to preferably less than about 8% and more preferably less thanabout 5%. Storage temperatures should be kept as low as possible andstill maintain a fluid material, ideally in the range of from about45.degree. C. to about 70.degree. C. The optimum storage temperature forstability and fluidity depends on the specific Iodine Value of the fattyacid used to make the diester quaternary and the level/type of solventselected. Also, exposure to oxygen should be minimized to keep theunsaturated groups from oxidizing. It can therefore be important tostore the material under a reduced oxygen atmosphere such as a nitrogenblanket. It is important to provide good molten storage stability toprovide a commercially feasible raw material that will not degradenoticeably in the normal transportation/storage/handling of the materialin manufacturing operations.

A specific example of a EQA compound suitable for use in the fabricsoftening compositions herein is: 1,2-bis(tallowyl oxy)-3-trimethylammoniopropane methylsulfate (DTTMAPMS).

Other examples of suitable EQA compounds are obtained by, e.g.,replacing “tallowyl” in the above compounds with, for example, cocoyl,lauryl, oleyl, stearyl, palmityl, or the like; replacing “methyl” in theabove compounds with ethyl, propyl, isopropyl, butyl, isobutyl, t-butyl,or the hydroxy substituted analogs of these radicals; and/or replacing“methylsulfate” in the above compounds with chloride, ethylsulfate,bromide, formate, sulfate, lactate, nitrate, and the like, butmethylsulfate is preferred. Another example of a suitable EQA compoundis: N-2-hydroxyethyl ammonium methylsulfate. A preferred compound isN-methyl, N,N-di-(2-oleyloxyethyl)N-2-hydroxyethyl ammoniummethylsulfate.

Another example of a suitable compound is methyl bis(oleyl amidoethyl)2-hydroxyethyl ammonium methyl sulfate.

The compounds herein can be prepared by standard esterification andquaternization reactions, using readily available starting materials.General methods for preparation are disclosed in U.S. Pat. No.4,137,180, which is incorporated herein by reference.

Specific examples of EQA compounds include:

-   di(tallowoyloxyethyl)dimethylammonium methyl sulfate;-   (tallowoyl)hydroxyethyldimethylammonium methyl sulfate;-   di(tallowoylhydroxyethyl)methylammonium methyl sulfate;-   tallowoyl(dihydroxyethyl)methylammonium methyl sulfate;-   tri(tallowoylhydroxyethyl)ammonium methyl sulfate-   (2-tallowylamidoethyl)-2-tallowylimidazolinium methyl sulfate; and-   N-(tallowoyloxyethyl)-N-(tallowyl)-N,N-dimethyl-ammonium methyl    sulfate;-   methyl bis(oleyl amidoethyl) 2-hydroxyethyl ammonium methyl sulfate;-   1,2-bis(tallowoyloxyethyl)-3,3,3-trimethyl ammoniopropane    methylsulfate (DTTMAPMS); and mixtures of any of the above    materials.

Particularly preferred is N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium methyl sulfate, where the tallow chains are fully hydrogenatedor partially unsaturated.

Other examples of suitable compounds can be obtained by, e.g., replacing“tallowoyl” in the above compounds with, for example, cocoyl, lauroyl,oleoyl, stearoyl, palmitoyl, or the like, the fatty acyl chains beingeither fully saturated, or preferably at least partly unsaturated; Thefatty acyl chains may be mixed from natural or purified sources orblended from one or more sources; replacing “methyl” in the abovecompounds with ethyl, propyl, isopropyl, butyl, isobutyl, t-butyl, orthe hydroxy substituted analogs of these radicals; and/or replacing“methylsulfate” in the above compounds with chloride, ethyl sulfate,bromide, formate, sulfate, lactate, nitrate, and the like, butmethylsulfate is preferred.

The level of unsaturation of the acyl chain mixture can be measured bythe Iodine Value (IV) of the corresponding fatty acid, which in thepresent case should preferably be in the range of from 5 to 100.

Tertiary Amines and Salts Thereof

Another fabric conditioning active useful in the articles of the presentinvention is a carboxylic acid salt of a tertiary amine and/or esteramine said materials have a thermal softening point of from about35.degree. C. to about 100.degree. C.

This component can provide superior odor and/or improved fabricsoftening performance, compared to similar articles which utilizeprimary amine or ammonium compounds as the sole fabric conditioningagent. Particularly preferred tertiary amines for static controlperformance are those containing unsaturation; e.g., oleyldimethylamineand/or soft tallowdimethylamine. Examples of preferred tertiary aminesas starting material for the reaction between the amine and carboxylicacid to form the tertiary amine salts are: lauryldimethylamine,myristyldimethylamine, stearyldimethylamine, tallowdimethylamine,coconutdimethylamine, dilaurylmethyl amine, distearylmethyl amine,ditallowmethylamine, oleyldimethylamine, dioleylmethylamine,lauryldi(3-hydroxypropyl)amine, stearyldi(2-hydroxyethyl)amine,trilaurylamine, laurylethylmethylamine, and

Examples of specific carboxylic acids as a starting material are: formicacid, acetic acid, lauric acid, myristic acid, palmitic acid, stearicacid, oleic acid, oxalic acid, adipic acid, 12-hydroxy stearic acid,benzoic acid, 4-hydroxy benzoic acid, 3-chloro benzoic acid, 4-nitrobenzoic acid, 4-ethyl benzoic acid, 4-(2-chloroethyl)benzoic acid,phenylacetic acid, (4-chlorophenyl)acetic acid, (4-hydroxyphenyl)aceticacid, and phthalic acid. Preferred carboxylic acids are stearic, oleic,lauric, myristic, palmitic, and mixtures thereof. The amine salt can beformed by a simple addition reaction, well known in the art anddisclosed in U.S. Pat. No. 4,237,155, Kardouche, issued Dec. 2, 1980,which is incorporated herein by reference. Excessive levels of freeamines may result in odor problems, and generally free amines providepoorer softening performance than the amine salts. The amine and theacid, respectively, used to form the amine salt will often be of mixedchain lengths rather than single chain lengths, since these materialsare normally derived from natural fats and oils, or synthetic processedwhich produce a mixture of chain lengths. Also, it is often desirable toutilize mixtures of different chain lengths in order to modify thephysical or performance characteristics of the softening composition.Specific preferred amine salts for use in the present invention areoleyldimethylamine stearate, stearyldimethylamine stearate,stearyldimethylamine myristate, stearyldimethylamine oleate,stearyldimethylamine palmitate, distearylmethylamine palmitate,distearylmethylamine laurate, and mixtures thereof. A particularlypreferred mixture is oleyldimethylamine stearate anddistearylmethylamine myristate, in a ratio of 1:10 to 10:1, preferablyabout 1:1.

Nonionic Softening Actives

A softening active that can also be employed in the present invention isa nonionic fabric softener material. Typically, such nonionic fabricsoftener materials have an HLB of from about 2 to about 9, and moretypically from about 3 to about 7. In general, the materials selectedshould be relatively crystalline and higher melting, (e.g., >25.degree.C.). The level of optional nonionic softener in the solid composition istypically from about 0.1% to about 50%, preferably from about 5% toabout 30%. Preferred nonionic softeners are fatty acid partial esters ofpolyhydric alcohols, or anhydrides thereof, wherein the alcohol oranhydride contains from about 2 to about 18 and preferably from about 2to about 8 carbon atoms, and each fatty acid moiety contains from about8 to about 30 and preferably from about 12 to about 20 carbon atoms.Typically, such softeners contain from about one to about 3 andpreferably about 2 fatty acid groups per molecule. The polyhydricalcohol portion of the ester can be ethylene glycol, glycerol, poly(e.g., di-, tri-, tetra, penta-, and/or hexa-) glycerol, xylitol,sucrose, erythritol, pentaerythritol, sorbitol or sorbitan. The fattyacid portion of the ester is normally derived from fatty acids havingfrom about 8 to about 30 and preferably from about 12 to about 22 carbonatoms. Typical examples of said fatty acids being lauric acid, myristicacid, palmitic acid, stearic acid, oleic acid, and behenic acid. Highlypreferred optional nonionic softening agents for use in the presentinvention are C₁₀-C₂₆ acyl sorbitan esters and polyglycerolmonostearate. Sorbitan esters are esterified dehydration products ofsorbitol. The preferred sorbitan ester comprises a member selected fromthe group consisting of C₁₀-C₂₆ acyl sorbitan monoesters and C₁₀-C₂₆acyl sorbitan diesters and ethoxylates of said esters wherein one ormore of the unesterified hydroxyl groups in said esters contain fromabout 1 to about 6 oxyethylene units, and mixtures thereof. For thepurpose of the present invention, sorbitan esters containingunsaturation (e.g., sorbitan monooleate) can be utilized. Sorbitol,which is typically prepared by the catalytic hydrogenation of glucose,can be dehydrated in well known fashion to form mixtures of 1,4- and1,5-sorbitol anhydrides and small amounts of isosorbides.

The preferred sorbitan softening agents of the type employed herein canbe prepared by esterifying the “sorbitan” mixture with a fatty acylgroup in standard fashion, e.g., by reaction with a fatty acid halide,fatty acid ester, and/or fatty acid. The esterification reaction canoccur at any of the available hydroxyl groups, and various mono-, di-,etc., esters can be prepared. In fact, mixtures of mono-, di-, tri-,etc., esters almost always result from such reactions, and thestoichiometric ratios of the reactants can be simply adjusted to favorthe desired reaction product. Certain derivatives of the preferredsorbitan esters herein, especially the “lower” ethoxylates thereof(i.e., mono-, di-, and tri-esters wherein one or more of theunesterified —OH groups contain one to about twenty oxyethylene moieties(Tweens®) are also useful in the composition of the present invention.Therefore, the term “sorbitan ester” is intended to include suchderivatives. For the purposes of the present invention, it is preferredthat a significant amount of di- and tri-sorbitan esters are present inthe ester mixture. Ester mixtures having from about 20-50% mono-ester,about 25-50% di-ester and about 10-35% of tri- and tetra-esters arepreferred. Material which is sold commercially as sorbitan mono-ester(e.g., monostearate) typically contains significant amounts of di- andtri-esters. A typical analysis of commercial sorbitan monostearateindicates that it comprises about 27% mono-, about 32% di- and about 30%tri- and tetra-esters and is therefore a preferred material. Mixtures ofsorbitan stearate and sorbitan palmitate having stearate/palmitateweight ratios varying between 10:1 and 1:10, and 1,5-sorbitan esters arealso useful. In addition, both the 1,4- and 1,5-sorbitan esters areuseful herein.

Other useful alkyl sorbitan esters for use in the softening compositionsherein include sorbitan monolaurate, sorbitan monomyristate, sorbitanmonopalmitate, sorbitan monobehenate, sorbitan monooleate, sorbitandilaurate, sorbitan dimyristate, sorbitan dipalmitate, sorbitandistearate, sorbitan dibehenate, sorbitan dioleate, and mixturesthereof, and mixed tallowalkyl sorbitan mono- and di-esters. Suchmixtures are readily prepared by reacting the foregoinghydroxy-substituted sorbitans, particularly the 1,4- and 1,5-sorbitans,with the corresponding acid, ester, or acid chloride in a simpleesterification reaction. It is to be recognized, of course, thatcommercial materials prepared in this manner will comprise mixturesusually containing minor proportions of uncyclized sorbitol, fattyacids, polymers, isosorbide structures, and the like. In the presentinvention, it is preferred that such impurities are present at as low alevel as practical. The preferred sorbitan esters employed herein cancontain up to about 15% by weight of esters of the C₂₀-C₂₆, and higher,fatty acids, as well as minor amounts of C₈, and lower, fatty esters.Glycerol and polyglycerol esters, especially glycerol, diglycerol,triglycerol, and polyglycerol mono- and/or di-esters, preferably mono-,are also preferred herein (e.g., polyglycerol monostearate with a tradename of Radiasurf 7248). Glycerol esters can be prepared from naturallyoccurring triglycerides by normal extraction, purification and/orinteresterification processes or by esterification processes of the typeset forth hereinbefore for sorbitan esters. Partial esters of glycerincan also be ethoxylated to form usable derivatives that are includedwithin the term “glycerol esters.” Useful glycerol and polyglycerolesters include mono-esters with stearic, oleic, palmitic, lauric,isostearic, myristic, and/or behenic acids and the diesters of stearic,oleic, palmitic, lauric, isostearic, behenic, and/or myristic acids. Itis understood that the typical mono-ester contains some di- andtri-ester, etc. The “glycerol esters” also include the polyglycerol,e.g., diglycerol through octaglycerol esters. The polyglycerol polyolsare formed by condensing glycerin or epichlorohydrin together to linkthe glycerol moieties via ether linkages. The mono- and/or diesters ofthe polyglycerol polyols are preferred, the fatty acyl groups typicallybeing those described hereinbefore for the sorbitan and glycerol esters.

Alkanolamides

Alkanolamide are also suitable.

Fatty Acids

The fabric conditioning active in the articles of the present inventionmay further comprise one or more fatty acids. Typically, the fatty acidis present to improve the processability of the composition, and isadmixed with any material, or materials, that are difficult to process,especially as a result of having a high viscosity. The fatty acidprovides improved viscosity and/or processability, without harmingsoftening or antistatic performance of the fabric conditioningcomposition. Preferred fatty acids are those containing a long chain,unsubstituted alkenyl group of from about 8 to about 30 carbon atoms,more preferably from about 11 to about 18 carbon atoms. Examples ofspecific carboxylic acids are: oleic acid, linoleic acid, and mixturesthereof. Although unsaturated fatty acids are preferred, the unsaturatedfatty acids can be used in combination with saturated fatty acids likestearic, palmitic, and/or lauric acids. Preferred carboxylic acids areoleic, linoleic, tallow fatty acids, and mixtures thereof. Another typeof preferred softener is high molecular weight fatty acid containing atleast 20 carbon atoms. These fatty acids can be used in combination withthe quaternary softener actives or as part of the fatty acid tertiaryamine salts, or mixtures of free fatty acids and fatty acid tertiaryamine salts. These fatty acids normally have higher melting ranges, thuscan be used to elevate the melting range of the total softenercomposition if necessary. Non-limiting examples of high molecular weightfatty acids useful in the present invention are arachidic acid (C₂₀,eicosanoic acid), docosanoic acid (C₂₂, behenic acid), tetracosanoicacid (C₂₄, lignoceric acid), triacontanoic acid (C₃₀, melissic acid),and mixtures thereof. Behenic acid, arachidic acid, and mixtures thereofare preferred. Behenic acid is most preferred.

Preferably, the fatty acid is added to the quaternization reactionmixture used to form the biodegradable quaternary ammonium compounds ofFormulas II, III, and/or IV as described hereinbefore to lower theviscosity of the reaction mixture to less than about 1500 cps,preferably less than about 1000 cps, more preferably less than about 800cps. The solvent level of added fatty acid is from about 5% to about30%, preferably from about 10% to about 25%, more preferably from about10% to about 20%. The unsaturated fatty acid can be added before thestart of the quaternization reaction or, preferably, during thequaternization reaction when it is needed to reduce the viscosity whichincreases with increased level of quaternization. Preferably theaddition occurs when at least about 60% of the product is quaternized.This allows for a low viscosity for processing while minimizing sidereactions that can occur when the quaternizing agent reacts with thefatty acid. The resulting quaternized biodegradable fabric softeningactives can be used without removal of the unsaturated fatty acid, and,in fact, are more useful since the mixture is more fluid and more easilyhandled.

Coating Mix

In one embodiment, the coat mix comprises a low level of water. Addingtoo much water to a coat mix may cause the coat mix to solidify or gel.This will cause problems in the manufacturing process as the phasechanged coat mix may clog pipes or no longer have desirable flowcharacteristics for processing. In one embodiment, the coat mixcomprises less than about 10%, alternatively less than about 9%, or 8%,or 7%, or 6%, or 5%, or 4%, or 3%, or 2%, or 1%, or 0.5%, or about 0.1%of water by weight of the coat mix. Alternatively the coat mix maycomprise at least about 0.001% water, by weight of the coat mix.Alternatively the coat mix is free or substantially free of water.

Additional Suitable Fabric Softening Actives

The fluid fabric enhancer compositions disclosed herein comprise afabric softening active (“FSA”). Suitable fabric softening actives,include, but are not limited to, materials selected from the groupconsisting of quaternary ammonium compounds, amines, fatty esters,sucrose esters, silicones, dispersible polyolefins, clays,polysaccharides, fatty acids, softening oils, polymer latexes andmixtures thereof.

Non-limiting examples of water insoluble fabric care benefit agentsinclude dispersible polyethylene and polymer latexes. These agents canbe in the form of emulsions, latexes, dispersions, suspensions, and thelike. In one aspect, they are in the form of an emulsion or a latex.Dispersible polyethylenes and polymer latexes can have a wide range ofparticle size diameters (χ₅₀) including but not limited to from about 1nm to about 100 μm; alternatively from about 10 nm to about 10 μm. Assuch, the particle sizes of dispersible polyethylenes and polymerlatexes are generally, but without limitation, smaller than silicones orother fatty oils.

Generally, any surfactant suitable for making polymer emulsions oremulsion polymerizations of polymer latexes can be used to make thewater insoluble fabric care benefit agents of the present invention.Suitable surfactants consist of emulsifiers for polymer emulsions andlatexes, dispersing agents for polymer dispersions and suspension agentsfor polymer suspensions. Suitable surfactants include anionic, cationic,and nonionic surfactants, or combinations thereof. In one aspect, suchsurfactants are nonionic and/or anionic surfactants. In one aspect, theratio of surfactant to polymer in the water insoluble fabric carebenefit agent is about 1:100 to about 1:2; alternatively from about 1:50to about 1:5, respectively. Suitable water insoluble fabric care benefitagents include but are not limited to the examples described below.

Quats—Suitable quats include but are not limited to, materials selectedfrom the group consisting of ester quats, amide quats, imidazolinequats, alkyl quats, amidoester quats and mixtures thereof. Suitableester quats include but are not limited to, materials selected from thegroup consisting of monoester quats, diester quats, triester quats andmixtures thereof. In one aspect, a suitable ester quat isbis-(2-hydroxypropyl)-dimethylammonium methylsulfate fatty acid esterhaving a molar ratio of fatty acid moieties to amine moieties of from1.85 to 1.99, an average chain length of the fatty acid moieties of from16 to 18 carbon atoms and an iodine value of the fatty acid moieties,calculated for the free fatty acid, which has an Iodine Value of between0-140, preferably 5-100, more preferably 10-80, even more preferably15-70, even more preferably 18-55, most preferably 18-25. When a softtallow quaternary ammonium compound softener is used, most preferablyrange is 25-60. In one aspect, the cis-trans-ratio of double bonds ofunsaturated fatty acid moieties of the bis (2hydroxypropyl)-dimethylammonium methylsulfate fatty acid ester is from55:45 to 75:25, respectively. Suitable amide quats include but are notlimited to, materials selected from the group consisting of monoamidequats, diamide quats and mixtures thereof. Suitable alkyl quats includebut are not limited to, materials selected from the group consisting ofmono alkyl quats, dialkyl quats, trialkyl quats, tetraalkyl quats andmixtures thereof.

Amines—Suitable amines include but are not limited to, materialsselected from the group consisting of amidoesteramines, amidoamines,imidazoline amines, alkyl amines, amidoester amines and mixturesthereof. Suitable ester amines include but are not limited to, materialsselected from the group consisting of monoester amines, diester amines,triester amines and mixtures thereof. Suitable amido quats include butare not limited to, materials selected from the group consisting ofmonoamido amines, diamido amines and mixtures thereof. Suitable alkylamines include but are not limited to, materials selected from the groupconsisting of mono alkylamines, dialkyl amines quats, trialkyl amines,and mixtures thereof.

In one embodiment, the fabric softening active is a quaternary ammoniumcompound suitable for softening fabric in a rinse step. In oneembodiment, the fabric softening active is formed from a reactionproduct of a fatty acid and an aminoalcohol obtaining mixtures of mono-,di-, and in one embodiment, tri-ester compounds. In another embodiment,the fabric softening active comprises one or more softener quaternaryammonium compounds such, but not limited to, as a monoalkyquaternaryammonium compound, dialkylquaternary ammonium compound, a diamidoquaternary compound, a diester quaternary ammonium compound, or acombination thereof.

In one aspect, the fabric softening active comprises a diesterquaternary ammonium or protonated diester ammonium (hereinafter “DQA”)compound composition. In certain embodiments of the present invention,the DQA compound compositions also encompass diamido fabric softeningactives and fabric softening actives with mixed amido and ester linkagesas well as the aforementioned diester linkages, all herein referred toas DQA.

In one aspect, said fabric softening active may comprise, as theprincipal active, compounds of the following formula:

{R_(4-m)—N⁺—[X—Y—R¹]_(m)}X⁻  (1)

wherein each R comprises either hydrogen, a short chain C₁-C₆, in oneaspect a C₁-C₃ alkyl or hydroxyalkyl group, for example methyl, ethyl,propyl, hydroxyethyl, and the like, poly(C₂₋₃ alkoxy), polyethoxy,benzyl, or mixtures thereof; each X is independently (CH₂)n,CH₂—CH(CH₃)— or CH—(CH₃)—CH₂—; each Y may comprise —O—(O)C—, —C(O)—O—,—NR—C(O)—, or —C(O)—NR—; each m is 2 or 3; each n is from 1 to about 4,in one aspect 2; the sum of carbons in each R¹, plus one when Y is—O—(O)C— or —NR—C(O)—, may be C₁₂-C₂₂, or C₁₄-C₂₀, with each R¹ being ahydrocarbyl, or substituted hydrocarbyl group; and X⁻ may comprise anysoftener-compatible anion. In one aspect, the softener-compatible anionmay comprise chloride, bromide, methylsulfate, ethylsulfate, sulfate,and nitrate. In another aspect, the softener-compatible anion maycomprise chloride or methyl sulfate.

In another aspect, the fabric softening active may comprise the generalformula:

[R₃N+CH₂CH(YR¹)(CH₂YR¹)]X⁻

wherein each Y, R, R¹, and X⁻ have the same meanings as before. Suchcompounds include those having the formula:

[CH₃]₃N⁽⁺⁾[CH₂CH(CH₂O(O)CR¹)O(O)CR¹]Cl⁽⁻⁾  (2)

wherein each R may comprise a methyl or ethyl group. In one aspect, eachR¹ may comprise a C₁₅ to C₁₉ group. As used herein, when the diester isspecified, it can include the monoester that is present.

These types of agents and general methods of making them are disclosedin U.S. Pat. No. 4,137,180. An example of a suitable DEQA (2) is the“propyl” ester quaternary ammonium fabric softener active comprising theformula 1,2-di(acyloxy)-3-trimethylammoniopropane chloride.

A third type of useful fabric softening active has the formula:

[R_(4-m)—N⁺—R¹ _(m)]X⁻  (3)

wherein each R, R¹, m and X⁻ have the same meanings as before.

In a further aspect, the fabric softening active may comprise theformula:

wherein each R, R¹, and A⁻ have the definitions given above; R² maycomprise a C₁₋₆ alkylene group, in one aspect an ethylene group; and Gmay comprise an oxygen atom or an —NR— group;

In a yet further aspect, the fabric softening active may comprise theformula:

wherein R¹, R² and G are defined as above.

In a further aspect, the fabric softening active may comprisecondensation reaction products of fatty acids with dialkylenetriaminesin, e.g., a molecular ratio of about 2:1, said reaction productscontaining compounds of the formula:

R¹—C(O)—NH—R²—NH—R³—NH—C(O)—R¹  (6)

wherein R¹, R² are defined as above, and R³ may comprise a C₁₋₆ alkylenegroup, in one aspect, an ethylene group and wherein the reactionproducts may optionally be quaternized by the additional of analkylating agent such as dimethyl sulfate. Such quaternized reactionproducts are described in additional detail in U.S. Pat. No. 5,296,622.

In a yet further aspect, the fabric softening active may comprise theformula:

[R¹—C(O)—NR—R²—N(R)₂—R³—NR—C(O)—R¹]⁺A⁻  (7)

wherein R, R¹, R², R³ and A⁻ are defined as above;

In a yet further aspect, the fabric softening active may comprisereaction products of fatty acid with hydroxyalkylalkylenediamines in amolecular ratio of about 2:1, said reaction products containingcompounds of the formula:

R¹—C(O)—NH—R²—N(R³OH)—C(O)—R¹  (8)

wherein R¹, R² and R³ are defined as above;

In a yet further aspect, the fabric softening active may comprise theformula:

wherein R, R¹, R², and A⁻ are defined as above.

In yet a further aspect, the fabric softening active may comprise theformula:

wherein;

-   -   X₁ is a C₂₋₃ alkyl group, in one aspect, an ethyl group;    -   X₂ and X₃ are independently C₁₋₆ linear or branched alkyl or        alkenyl groups, in one aspect, methyl, ethyl or isopropyl        groups;    -   R₁ and R₂ are independently C₈₋₂₂ linear or branched alkyl or        alkenyl groups;    -   characterized in that;    -   A and B are independently selected from the group comprising        —O—(C═O)—, —(C═O)—O—, or mixtures thereof, in one aspect,        —O—(C═O)—

Non-limiting examples of fabric softening actives comprising formula (1)are N,N-bis(stearoyl-oxy-ethyl)-N,N-dimethylammonium chloride,N,N-bis(tallowoyl-oxy-ethyl)-N,N-dimethylammonium chloride,N,N-bis(stearoyl-oxy-ethyl)-N-(2 hydroxyethyl)-N-methylammoniummethylsulfate.

Non-limiting examples of fabric softening actives comprising formula (2)is 1,2-di-(stearoyl-oxy)-3-trimethyl ammoniumpropane chloride.

Non-limiting examples of fabric softening actives comprising formula (3)include dialkylenedimethylammonium salts such asdicanoladimethylammonium chloride, di(hard)tallowdimethylammoniumchloride, dicanoladimethylammonium methylsulfate, and mixtures thereof.An example of commercially available dialkylenedimethylammonium saltsusable in the present invention is dioleyldimethylammonium chlorideavailable from Witco Corporation under the trade name Adogen® 472 anddihardtallow dimethylammonium chloride available from Akzo Nobel Arquad2HT75.

A non-limiting example of fabric softening actives comprising formula(4) is 1-methyl-1-stearoylamidoethyl-2-stearoylimidazoliniummethylsulfate wherein R¹ is an acyclic aliphatic C₁₅-C₁₇ hydrocarbongroup, R² is an ethylene group, G is a NH group, R⁵ is a methyl groupand A⁻ is a methyl sulfate anion, available commercially from the WitcoCorporation under the trade name Varisoft®.

A non-limiting example of fabric softening actives comprising formula(5) is 1-tallowylamidoethyl-2-tallowylimidazoline wherein R¹ is anacyclic aliphatic C₁₅-C₁₇ hydrocarbon group, R² is an ethylene group,and G is a NH group.

A non-limiting example of a fabric softening active comprising formula(6) is the reaction products of fatty acids with diethylenetriamine in amolecular ratio of about 2:1, said reaction product mixture containingN,N″-dialkyldiethylenetriamine with the formula:

R¹—C(O)—NH—CH₂CH₂—NH—CH₂CH₂—NH—C(O)—R¹

wherein R¹ is an alkyl group of a commercially available fatty acidderived from a vegetable or animal source, such as Emersol® 223LL orEmersol® 7021, available from Henkel Corporation, and R² and R³ aredivalent ethylene groups.

In one aspect, said fatty acid may be obtained, in whole or in part,from a renewable source, via extraction from plant material,fermentation from plant material, and/or obtained via geneticallymodified organisms such as algae or yeast.

A non-limiting example of Compound (7) is a di-fatty amidoamine basedsoftener having the formula:

[R¹—C(O)—NH—CH₂CH₂—N(CH₃)(CH₂CH₂OH)—CH₂CH₂—NH—C(O)—R¹]⁺CH₃SO₄—

wherein R¹ is an alkyl group. An example of such compound is thatcommercially available from the Witco Corporation e.g. under the tradename Varisoft® 222LT.

An example of a fabric softening active comprising formula (8) is thereaction products of fatty acids with N-2-hydroxyethylethylenediamine ina molecular ratio of about 2:1, said reaction product mixture containinga compound of the formula:

R¹—C(O)—NH—CH₂CH₂—N(CH₂CH₂OH)—C(O)—R¹

wherein R¹—C(O) is an alkyl group of a commercially available fatty acidderived from a vegetable or animal source, such as Emersol® 223LL orEmersol® 7021, available from Henkel Corporation.

An example of a fabric softening active comprising formula (9) is thediquaternary compound having the formula:

wherein R¹ is derived from fatty acid. Such compound is available fromWitco Company.

A non-limiting example of a fabric softening active comprising formula(10) is a dialkyl imidazoline diester compound, where the compound isthe reaction product of N-(2-hydroxyethyl)-1,2-ethylenediamine orN-(2-hydroxyisopropyl)-1,2-ethylenediamine with glycolic acid,esterified with fatty acid, where the fatty acid is (hydrogenated)tallow fatty acid, palm fatty acid, hydrogenated palm fatty acid, oleicacid, rapeseed fatty acid, hydrogenated rapeseed fatty acid or a mixtureof the above.

It will be understood that combinations of softener actives disclosedabove are suitable for use in this invention.

Anion A

In the cationic nitrogenous salts herein, the anion A⁻, which comprisesany softener compatible anion, provides electrical neutrality. Mostoften, the anion used to provide electrical neutrality in these salts isfrom a strong acid, especially a halide, such as chloride, bromide, oriodide. However, other anions can be used, such as methylsulfate,ethylsulfate, acetate, formate, sulfate, carbonate, fatty acid anionsand the like. In one aspect, the anion A may comprise chloride ormethylsulfate. The anion, in some aspects, may carry a double charge. Inthis aspect, A⁻ represents half a group.

In one embodiment, the fabric softening agent is chosen from at leastone of the following: ditallowoyloxyethyl dimethyl ammonium chloride,dihydrogenated-tallowoyloxyethyl dimethyl ammonium chloride, ditallowdimethyl ammonium chloride, dihydrogenatedtallow dimethyl ammoniumchloride, ditallowoyloxyethyl methylhydroxyethylammonium methyl sulfate,dihydrogenated-tallowoyloxyethyl methyl hydroxyethylammonium chloride,or combinations thereof.

Polyssacharides

One aspect of the invention provides a fabric enhancer compositioncomprising a cationic starch as a fabric softening active. In oneembodiment, the fabric care compositions of the present inventiongenerally comprise cationic starch at a level of from about 0.1% toabout 7%, alternatively from about 0.1% to about 5%, alternatively fromabout 0.3% to about 3%, and alternatively from about 0.5% to about 2.0%,by weight of the composition. Suitable cationic starches for use in thepresent compositions are commercially-available from Cerestar under thetrade name C*BOND® and from National Starch and Chemical Company underthe trade name CATO® 2A.

Sucrose Esters

Nonionic fabric care benefit agents can comprise sucrose esters, and aretypically derived from sucrose and fatty acids. Sucrose ester iscomposed of a sucrose moiety having one or more of its hydroxyl groupsesterified.

Sucrose is a disaccharide having the following formula:

Alternatively, the sucrose molecule can be represented by the formula:M(OH)₈, wherein M is the disaccharide backbone and there are total of 8hydroxyl groups in the molecule.

Thus, sucrose esters can be represented by the following formula:

M(OH)_(8-x)(OC(O)R¹)_(x)

wherein x is the number of hydroxyl groups that are esterified, whereas(8−x) is the hydroxyl groups that remain unchanged; x is an integerselected from 1 to 8, alternatively from 2 to 8, alternatively from 3 to8, or from 4 to 8; and R¹ moieties are independently selected fromC₁-C₂₂ alkyl or C₁-C₃₀ alkoxy, linear or branched, cyclic or acyclic,saturated or unsaturated, substituted or unsubstituted.

In one embodiment, the R¹ moieties comprise linear alkyl or alkoxymoieties having independently selected and varying chain length. Forexample, R¹ may comprise a mixture of linear alkyl or alkoxy moietieswherein greater than about 20% of the linear chains are C₁₈,alternatively greater than about 50% of the linear chains are C₁₈,alternatively greater than about 80% of the linear chains are C₁₈.

In another embodiment, the R¹ moieties comprise a mixture of saturateand unsaturated alkyl or alkoxy moieties; the degree of unsaturation canbe measured by “Iodine Value” (hereinafter referred as “IV”, as measuredby the standard AOCS method). The IV of the sucrose esters suitable foruse herein ranges from about 1 to about 150, or from about 2 to about100, or from about 5 to about 85. The R¹ moieties may be hydrogenated toreduce the degree of unsaturation. In the case where a higher IV ispreferred, such as from about 40 to about 95, then oleic acid and fattyacids derived from soybean oil and canola oil are the startingmaterials.

In a further embodiment, the unsaturated R¹ moieties may comprise amixture of “cis” and “trans” forms about the unsaturated sites. The“cis”/“trans” ratios may range from about 1:1 to about 50:1, or fromabout 2:1 to about 40:1, or from about 3:1 to about 30:1, or from about4:1 to about 20:1.

Dispersible Polyolefins

Generally, all dispersible polyolefins that provide fabric care benefitscan be used as water insoluble fabric care benefit agents in the presentinvention. The polyolefins can be in the format of waxes, emulsions,dispersions or suspensions. Non-limiting examples are discussed below.

In one embodiment, the polyolefin is chosen from a polyethylene,polypropylene, or a combination thereof. The polyolefin may be at leastpartially modified to contain various functional groups, such ascarboxyl, alkylamide, sulfonic acid or amide groups. In anotherembodiment, the polyolefin is at least partially carboxyl modified or,in other words, oxidized.

For ease of formulation, the dispersible polyolefin may be introduced asa suspension or an emulsion of polyolefin dispersed by use of anemulsifying agent. The polyolefin suspension or emulsion may comprisefrom about 1% to about 60%, alternatively from about 10% to about 55%,alternatively from about 20% to about 50% by weight of polyolefin. Thepolyolefin may have a wax dropping point (see ASTM D3954-94, volume15.04—“Standard Test Method for Dropping Point of Waxes”) from about 20°to about 170° C., alternatively from about 50° to about 140° C. Suitablepolyethylene waxes are available commercially from suppliers includingbut not limited to Honeywell (A-C polyethylene), Clariant (Velustrol®emulsion), and BASF (LUWAX®).

When an emulsion is employed with the dispersible polyolefin, theemulsifier may be any suitable emulsification agent. Non-limitingexamples include an anionic, cationic, nonionic surfactant, or acombination thereof. However, almost any suitable surfactant orsuspending agent may be employed as the emulsification agent. Thedispersible polyolefin is dispersed by use of an emulsification agent ina ratio to polyolefin wax of about 1:100 to about 1:2, alternativelyfrom about 1:50 to about 1:5, respectively.

Polymer Latexes

Polymer latex is made by an emulsion polymerization which includes oneor more monomers, one or more emulsifiers, an initiator, and othercomponents familiar to those of ordinary skill in the art. Generally,all polymer latexes that provide fabric care benefits can be used aswater insoluble fabric care benefit agents of the present invention.Additional non-limiting examples include the monomers used in producingpolymer latexes such as: (1) 100% or pure butylacrylate; (2)butylacrylate and butadiene mixtures with at least 20% (weight monomerratio) of butylacrylate; (3) butylacrylate and less than 20% (weightmonomer ratio) of other monomers excluding butadiene; (4) alkylacrylatewith an alkyl carbon chain at or greater than C₆; (5) alkylacrylate withan alkyl carbon chain at or greater than C₆ and less than 50% (weightmonomer ratio) of other monomers; (6) a third monomer (less than 20%weight monomer ratio) added into an aforementioned monomer systems; and(7) combinations thereof.

Polymer latexes that are suitable fabric care benefit agents in thepresent invention may include those having a glass transitiontemperature of from about −120° C. to about 120° C., alternatively fromabout −80° C. to about 60° C. Suitable emulsifiers include anionic,cationic, nonionic and amphoteric surfactants. Suitable initiatorsinclude initiators that are suitable for emulsion polymerization ofpolymer latexes. The particle size diameter (χ₅₀) of the polymer latexescan be from about 1 nm to about 10 μm, alternatively from about 10 nm toabout 1 μm, or even from about 10 nm to about 20 nm.

Fatty Acid

One aspect of the invention provides a fabric softening compositioncomprising a fatty acid, such as a free fatty acid. The term “fattyacid” is used herein in the broadest sense to include unprotonated orprotonated forms of a fatty acid; and includes fatty acid that is boundor unbound to another chemical moiety as well as the variouscombinations of these species of fatty acid. One skilled in the art willreadily appreciate that the pH of an aqueous composition will dictate,in part, whether a fatty acid is protonated or unprotonated. In anotherembodiment, the fatty acid is in its unprotonated, or salt form,together with a counter ion, such as, but not limited to, calcium,magnesium, sodium, potassium and the like. The term “free fatty acid”means a fatty acid that is not bound to another chemical moiety(covalently or otherwise) to another chemical moiety.

In one embodiment, the fatty acid may include those containing fromabout 12 to about 25, from about 13 to about 22, or even from about 16to about 20, total carbon atoms, with the fatty moiety containing fromabout 10 to about 22, from about 12 to about 18, or even from about 14(mid-cut) to about 18 carbon atoms.

The fatty acids of the present invention may be derived from (1) ananimal fat, and/or a partially hydrogenated animal fat, such as beeftallow, lard, etc.; (2) a vegetable oil, and/or a partially hydrogenatedvegetable oil such as canola oil, safflower oil, peanut oil, sunfloweroil, sesame seed oil, rapeseed oil, cottonseed oil, corn oil, soybeanoil, tall oil, rice bran oil, palm oil, palm kernel oil, coconut oil,other tropical palm oils, linseed oil, tung oil, etc.; (3) processedand/or bodied oils, such as linseed oil or tung oil via thermal,pressure, alkali-isomerization and catalytic treatments; (4) a mixturethereof, to yield saturated (e.g. stearic acid), unsaturated (e.g. oleicacid), polyunsaturated (linoleic acid), branched (e.g. isostearic acid)or cyclic (e.g. saturated or unsaturated α-disubstituted cyclopentyl orcyclohexyl derivatives of polyunsaturated acids) fatty acids.

Mixtures of fatty acids from different fat sources can be used.

In one aspect, at least a majority of the fatty acid that is present inthe fabric softening composition of the present invention isunsaturated, e.g., from about 40% to 100%, from about 55% to about 99%,or even from about 60% to about 98%, by weight of the total weight ofthe fatty acid present in the composition, although fully saturated andpartially saturated fatty acids can be used. As such, the total level ofpolyunsaturated fatty acids (TPU) of the total fatty acid of theinventive composition may be from about 0% to about 75% by weight of thetotal weight of the fatty acid present in the composition.

The cis/trans ratio for the unsaturated fatty acids may be important,with the cis/trans ratio (of the C18:1 material) being from at leastabout 1:1, at least about 3:1, from about 4:1 or even from about 9:1 orhigher.

Branched fatty acids such as isostearic acid are also suitable sincethey may be more stable with respect to oxidation and the resultingdegradation of color and odor quality.

The Iodine Value or “IV” measures the degree of unsaturation in thefatty acid. In one embodiment of the invention, the fatty acid has an IVfrom about 10 to about 140, from about 15 to about 100 or even fromabout 15 to about 60.

Another class of fatty ester fabric care actives is softening oils,which include but are not limited to, vegetable oils (such as soybean,sunflower, and canola), hydrocarbon based oils (natural and syntheticpetroleum lubricants, in one aspect polyolefins, isoparaffins, andcyclic paraffins), triolein, fatty esters, fatty alcohols, fatty amines,fatty amides, and fatty ester amines. Oils can be combined with fattyacid softening agents, clays, and silicones.

Clays

In one embodiment of the invention, the fabric care composition maycomprise a clay as a fabric care active. In one embodiment clay can be asoftener or co-softeners with another softening active, for example,silicone. Suitable clays include those materials classified geologicallysmectites.

Silicone

In one embodiment, the fabric softening composition comprises asilicone. Suitable levels of silicone may comprise from about 0.1% toabout 70%, alternatively from about 0.3% to about 40%, alternativelyfrom about 0.5% to about 30%, alternatively from about 1% to about 20%by weight of the composition. Useful silicones can be any siliconecomprising compound. In one embodiment, the silicone polymer is selectedfrom the group consisting of cyclic silicones, polydimethylsiloxanes,aminosilicones, cationic silicones, silicone polyethers, siliconeresins, silicone urethanes, and mixtures thereof. In one embodiment, thesilicone is a polydialkylsilicone, alternatively a polydimethyl silicone(polydimethyl siloxane or “PDMS”), or a derivative thereof. In anotherembodiment, the silicone is chosen from an aminofunctional silicone,amino-polyether silicone, alkyloxylated silicone, cationic silicone,ethoxylated silicone, propoxylated silicone, ethoxylated/propoxylatedsilicone, quaternary silicone, or combinations thereof.

In another embodiment, the silicone may be chosen from a random orblocky organosilicone polymer having the following formula:

[R₁R₂R₃SiO_(1/2)]_((j+2))[(R₄Si(X—Z)O_(2/2)]_(k)[R₄R₄SiO_(2/2)]_(m)[R₄SiO_(3/2)]_(j)

wherein:

-   -   j is an integer from 0 to about 98; in one aspect j is an        integer from 0 to about 48; in one aspect, j is 0;    -   k is an integer from 0 to about 200, in one aspect k is an        integer from 0 to about 50; when k=0, at least one of R₁, R₂ or        R₃ is —X—Z;    -   m is an integer from 4 to about 5,000; in one aspect m is an        integer from about 10 to about 4,000; in another aspect m is an        integer from about 50 to about 2,000;        -   R₁, R₂ and R₃ are each independently selected from the group            consisting of H, OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl,            C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl,            C₆-C₃₂ alkylaryl, C₆-C₃₂ substituted alkylaryl, C₁-C₃₂            alkoxy, C₁-C₃₂ substituted alkoxy and X—Z;        -   each R₄ is independently selected from the group consisting            of H, OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ or            C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂            alkylaryl, C₆-C₃₂ substituted alkylaryl, C₁-C₃₂ alkoxy and            C₁-C₃₂ substituted alkoxy;        -   each X in said alkyl siloxane polymer comprises a            substituted or unsubstituted divalent alkylene radical            comprising 2-12 carbon atoms, in one aspect each divalent            alkylene radical is independently selected from the group            consisting of —(CH₂)_(s)— wherein s is an integer from about            2 to about 8, from about 2 to about 4; in one aspect, each X            in said alkyl siloxane polymer comprises a substituted            divalent alkylene radical selected from the group consisting            of: —CH₂—CH(OH)—CH₂—; —CH₂—CH₂—CH(OH)—; and

-   -   each Z is selected independently from the group consisting of

-   -    with the proviso that when Z is a quat, Q cannot be an amide,        imine, or urea moiety and if Q is an amide, imine, or urea        moiety, then any additional Q bonded to the same nitrogen as        said amide, imine, or urea moiety must be H or a C₁-C₆ alkyl, in        one aspect, said additional Q is H; for Z A^(n−) is a suitable        charge balancing anion. In one aspect A^(n−) is selected from        the group consisting of Cl⁻, Br⁻, I⁻, methylsulfate, toluene        sulfonate, carboxylate and phosphate; and at least one Q in said        organosilicone is independently selected from        —CH₂—CH(OH)—CH₂—R₅;

-   -   each additional Q in said organosilicone is independently        selected from the group comprising of H, C₁-C₃₂ alkyl, C₁-C₃₂        substituted alkyl, C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂        substituted aryl, C₆-C₃₂ alkylaryl, C₆-C₃₂ substituted        alkylaryl, —CH₂—CH(OH)—CH₂—R₅;

-   -   wherein each R₅ is independently selected from the group        consisting of H, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂        or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂        alkylaryl, C₆-C₃₂ substituted alkylaryl, —(CHR₆—CHR₆—O—)_(w)-L        and a siloxyl residue;        -   each R₆ is independently selected from H, C₁-C₁₈ alkyl        -   each L is independently selected from —C(O)—R₇ or        -   R₇;        -   w is an integer from 0 to about 500, in one aspect w is an            integer from about 1 to about 200; in one aspect w is an            integer from about 1 to about 50;        -   each R₇ is selected independently from the group consisting            of H; C₁-C₃₂ alkyl; C₁-C₃₂ substituted alkyl, C₅-C₃₂ or            C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂            alkylaryl; C₆-C₃₂ substituted alkylaryl and a siloxyl            residue;        -   each T is independently selected from H, and

-   -    and        -   wherein each v in said organosilicone is an integer from 1            to about 10, in one aspect, v is an integer from 1 to about            5 and the sum of all v indices in each Q in the said            organosilicone is an integer from 1 to about 30 or from 1 to            about 20 or even from 1 to about 10.

In another embodiment, the silicone may be chosen from a random orblocky organosilicone polymer having the following formula:

[R₁R₂R₃SiO_(1/2)]_((j+2))[(R₄Si(X—Z)O_(2/2)]_(k)[R₄R₄SiO_(2/2)]_(m)[R₄SiO_(3/2)]_(j)

-   -   wherein        -   j is an integer from 0 to about 98; in one aspect j is an            integer from 0 to about 48; in one aspect, j is 0;        -   k is an integer from 0 to about 200; when k=0, at least one            of R₁, R₂ or R₃=—X—Z, in one aspect, k is an integer from 0            to about 50        -   m is an integer from 4 to about 5,000; in one aspect m is an            integer from about 10 to about 4,000; in another aspect m is            an integer from about 50 to about 2,000;            -   R₁, R₂ and R₃ are each independently selected from the                group consisting of H, OH, C₁-C₃₂ alkyl, C₁-C₃₂                substituted alkyl, C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or                C₆-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl, C₆-C₃₂                substituted alkylaryl, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted                alkoxy and X—Z;            -   each R₄ is independently selected from the group                consisting of H, OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted                alkyl, C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂                substituted aryl, C₆-C₃₂ alkylaryl, C₆-C₃₂ substituted                alkylaryl, C₁-C₃₂ alkoxy and C₁-C₃₂ substituted alkoxy;            -   each X comprises of a substituted or unsubstituted                divalent alkylene radical comprising 2-12 carbon atoms;                in one aspect each X is independently selected from the                group consisting of —(CH₂)_(s)—O—; —CH₂—CH(OH)—CH₂—O—;

-   -   wherein each s independently is an integer from about 2 to about        8, in one aspect s is an integer from about 2 to about 4;        -   At least one Z in the said organosiloxane is selected from            the group consisting of R₅;

-   -   —C(R₅)₂O—R₅; —C(R₅)₂S—R₅ and

-   -    provided that when X is

-   -    then Z=—OR₅ or

-   -   wherein A⁻ is a suitable charge balancing anion. In one aspect        A⁻ is selected from the group consisting of Cl⁻, Br⁻, I⁻,        methylsulfate, toluene sulfonate, carboxylate and phosphate and        each additional Z in said organosilicone is independently        selected from the group comprising of H, C₁-C₃₂ alkyl, C₁-C₃₂        substituted alkyl, C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂        substituted aryl, C₆-C₃₂ alkylaryl, C₆-C₃₂ substituted        alkylaryl, R₅,

-   -   —C(R₅)₂O—R₅; —C(R₅)₂S—R₅ and

-   -    provided that when X is

-   -    then Z=—OR₅ or

-   -   each R₅ is independently selected from the group consisting of        H; C₁-C₃₂ alkyl; C₁-C₃₂ substituted alkyl, C₅-C₃₂ or C₆-C₃₂        aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl or C₆-C₃₂ alkylaryl, or        C₆-C₃₂ substituted alkylaryl,        -   —(CHR₆—CHR₆—O—)_(w)—CHR₆—CHR₆-L and siloxyl residue wherein            each L is independently selected from —O—C(O)—R₇ or —O—R₇;

-   -   w is an integer from 0 to about 500, in one aspect w is an        integer from 0 to about 200, one aspect w is an integer from 0        to about 50;        -   each R₆ is independently selected from H or C₁-C₁₈ alkyl;            -   each R₇ is independently selected from the group                consisting of H; C₁-C₃₂ alkyl; C₁-C₃₂ substituted alkyl,                C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted                aryl, C₆-C₃₂ alkylaryl, and C₆-C₃₂ substituted aryl, and                a siloxyl residue;            -   each T is independently selected from H;

-   -   wherein each v in said organosilicone is an integer from 1 to        about 10, in one aspect, v is an integer from 1 to about 5 and        the sum of all v indices in each Z in the said organosilicone is        an integer from 1 to about 30 or from 1 to about 20 or even from        1 to about 10.

In one embodiment, the silicone is one comprising a relatively highmolecular weight. A suitable way to describe the molecular weight of asilicone includes describing its viscosity. A high molecular weightsilicone is one having a viscosity of from about 10 cSt to about3,000,000 cSt, or from about 100 cSt to about 1,000,000 cSt, or fromabout 1,000 cSt to about 600,000 cSt, or even from about 6,000 cSt toabout 300,000 cSt.

In one embodiment, the silicone comprises a blocky cationicorganopolysiloxane having the formula:

M_(w)D_(x)T_(y)Q_(z)

wherein:M=[SiR₁R₂R₃O_(1/2)], [SiR₁R₂G₁O_(1/2)], [SiR₁G₁G₂O_(1/2)],[SiG₁G₂G₃O_(1/2)], or combinations thereof;D=[SiR₁R₂O_(2/2)], [SiR₁G₁O_(2/2)], [SiG₁G₂O_(2/2)] or combinationsthereof;T=[SiR₁O_(3/2)], [SiG₁O_(3/2)] or combinations thereof;

Q=[SiO_(4/2)];

w=is an integer from 1 to (2+y+2z);x=is an integer from 5 to 15,000;y=is an integer from 0 to 98;z=is an integer from 0 to 98;R₁, R₂ and R₃ are each independently selected from the group consistingof H, OH, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl, C₅-C₃₂ or C₆-C₃₂ aryl,C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂ alkylaryl, C₆-C₃₂ substitutedalkylaryl, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted alkoxy, C₁-C₃₂ alkylamino,and C₁-C₃₂ substituted alkylamino;at least one of M, D, or T incorporates at least one moiety G₁, G₂ orG₃; and G₁, G₂, and G₃ are each independently selected from the formula:

wherein:X comprises a divalent radical selected from the group consisting ofC₁-C₃₂ alkylene, C₁-C₃₂ substituted alkylene, C₅-C₃₂ or C₆-C₃₂ arylene,C₅-C₃₂ or C₆-C₃₂ substituted arylene, C₆-C₃₂ arylalkylene, C₆-C₃₂substituted arylalkylene, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted alkoxy,C₁-C₃₂ alkyleneamino, C₁-C₃₂ substituted alkyleneamino, ring-openedepoxide, and ring-opened glycidyl, with the proviso that if X does notcomprise a repeating alkylene oxide moiety then X can further comprise aheteroatom selected from the group consisting of P, N and O;each R₄ comprises identical or different monovalent radicals selectedfrom the group consisting of H, C₁-C₃₂ alkyl, C₁-C₃₂ substituted alkyl,C₅-C₃₂ or C₆-C₃₂ aryl, C₅-C₃₂ or C₆-C₃₂ substituted aryl, C₆-C₃₂alkylaryl, and C₆-C₃₂ substituted alkylaryl;E comprises a divalent radical selected from the group consisting ofC₁-C₃₂ alkylene, C₁-C₃₂ substituted alkylene, C₅-C₃₂ or C₆-C₃₂ arylene,C₅-C₃₂ or C₆-C₃₂ substituted arylene, C₆-C₃₂ arylalkylene, C₆-C₃₂substituted arylalkylene, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted alkoxy,C₁-C₃₂ alkyleneamino, C₁-C₃₂ substituted alkyleneamino, ring-openedepoxide and ring-opened glycidyl, with the proviso that if E does notcomprise a repeating alkylene oxide moiety then E can further comprise aheteroatom selected from the group consisting of P, N, and O;E′ comprises a divalent radical selected from the group consisting ofC₁-C₃₂ alkylene, C₁-C₃₂ substituted alkylene, C₅-C₃₂ or C₆-C₃₂ arylene,C₅-C₃₂ or C₆-C₃₂ substituted arylene, C₆-C₃₂ arylalkylene, C₆-C₃₂substituted arylalkylene, C₁-C₃₂ alkoxy, C₁-C₃₂ substituted alkoxy,C₁-C₃₂ alkyleneamino, C₁-C₃₂ substituted alkyleneamino, ring-openedepoxide and ring-opened glycidyl, with the proviso that if E′ does notcomprise a repeating alkylene oxide moiety then E′ can further comprisea heteroatom selected from the group consisting of P, N, and O;p is an integer independently selected from 1 to 50;n is an integer independently selected from 1 or 2;when at least one of G₁, G₂, or G₃ is positively charged, A^(−t) is asuitable charge balancing anion or anions such that the total charge, k,of the charge-balancing anion or anions is equal to and opposite fromthe net charge on the moiety G₁, G₂ or G₃; wherein t is an integerindependently selected from 1, 2, or 3; and k≦(p*2/t)+1; such that thetotal number of cationic charges balances the total number of anioniccharges in the organopolysiloxane molecule;and wherein at least one E does not comprise an ethylene moiety.

Additional Components

The present invention can include other optional components (minorcomponents) conventionally used in textile treatment compositions, forexample, anti-oxidants, colorants, preservatives, optical brighteners,opacifiers, stabilizers such as guar gum and polyethylene glycol,anti-shrinkage agents, anti-wrinkle agents, soil release agents, fabriccrisping agents, reductive agents, spotting agents, germicides,fungicides, anti-corrosion agents, antifoam agents, Color Care Agentsincluding Chlorine Scavangers, Dye Transfer Inhibitors, Dye FixativesChelants and Anti-Abrasion Agents Perfume, PMC's, Cyclodextrin PerfumeComplexes, Free Cyclodextrin, Pro-Perfumes; Antioxidants and the like.

Substrate

One aspect of the present invention relates to fabric conditioningcompositions which are delivered to fabric via dryer-added substratethat effectively releases the composition in an automatic laundry(clothes) dryer. Such dispensing means can be designed for single usageor for multiple uses. The dispensing means can also be a “carriermaterial” that releases the fabric conditioning composition and then isdispersed and/or exhausted from the dryer. When the dispensing means isa flexible substrate, e.g., in sheet configuration, the fabricconditioning composition is releasably affixed on the substrate toprovide a weight ratio of conditioning composition to dry substrateranging from about 10:1 to about 0.5:1, preferably from about 5:1 toabout 1:1. To insure release, preferred flexible sheets withstand thedryer environment without decomposing or changing shape, e.g.combusting, creating off odors, or shrinking with heat or moisture.Substrates especially useful herein are rayon and/or polyester non-wovenfabrics.

Non-limiting examples of the substrates useful herein are cellulosicrayon and/or polyester non-woven fabrics having basis weights of fromabout 0.4 oz./yd2 to about 1 oz./yd2, preferably from about 0.5 oz./yd2to about 0.8 oz./yd2, more preferably from about 0.5 oz./yd2 to about0.6 oz./yd2. These substrates are typically prepared using, e.g., rayonand/or polyester fibers having deniers of from about 1 to about 8,preferably from about 3 to about 6, and more preferably about 4 to 6 ormixtures of different deniers. Typically, the fiber is a continuousfilament or a 3/16 inch to 2 inch fiber segment that is laid down, in apattern that results in a multiplicity of layers and intersectionsbetween overlayed portions of the filament or fiber, on a belt,preferably foraminous, and then the fiber intersections are glued and/orfused into fiber-to-fiber bonds by a combination of an adhesive binder,and/or heat and/or pressure. As non-limiting examples, the substrate maybe spun-bonded, melt-bonded, or point bonded or combinations of bondingprocesses may be chosen. The substrate breaking strength and elasticityin the machine and cross direction is sufficient to enable the substrateto be conveyed through a coating process. The porosity of the substratearticle is sufficient to enable air flow through the substrate topromote conditioning active release and prevent dryer vent blinding. Thesubstrate may also have a plurality of rectilinear slits extended alongone dimension of the substrate.

The dispensing means will normally carry an effective amount of fabricconditioning composition. Such effective amount typically providessufficient softness, antistatic effect and/or perfume deposition for atleast one treatment of a minimum load in an automatic laundry dryer.Amounts of the fabric conditioning composition irrespective of load sizefor a single article can vary from about 0.1 g to about 100 g,preferably from about 0.1 g to about 20 g, most preferably from about0.1 g to about 10 g. Amounts of fabric treatment composition formultiple uses, e.g., up to about 30, can be used.

Test Methods

Malodor reduction materials may be separated from mixtures, includingbut not limited to finished products such as consumer products andidentified, by analytical methods that include GC-MS and/or NMR.

Test Method for Determining Saturation Vapour Pressure (VP)

The saturation Vapour Pressure (VP) values are computed for each PRM inthe perfume mixture being tested. The VP of an individual PRM iscalculated using the VP Computational Model, version 14.02 (Linux)available from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto,Canada) to provide the VP value at 25° C. expressed in units of torr.The ACD/Labs' Vapor Pressure model is part of the ACD/Labs model suite.

Test Method for Determining the Logarithm of the Octanol/Water PartitionCoefficient (log P)

The value of the log of the Octanol/Water Partition Coefficient (log P)is computed for each PRM in the perfume mixture being tested. The log Pof an individual PRM is calculated using the Consensus log PComputational Model, version 14.02 (Linux) available from AdvancedChemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide theunitless log P value. The ACD/Labs' Consensus log P Computational Modelis part of the ACD/Labs model suite.

Test Method for the Generation of Molecular Descriptors

In order to conduct the calculations involved in the computed-value testmethods described herein, the starting information required includes theidentity, weight percent, and molar percent of each PRM in the perfumebeing tested, as a proportion of that perfume, wherein all PRMs in theperfume composition are included in the calculations. Additionally foreach of those PRMs, the molecular structure, and the values of variouscomputationally-derived molecular descriptors are also required, asdetermined in accordance with the Test Method for the Generation ofMolecular Descriptors described herein.

For each PRM in a perfume mixture or composition, its molecularstructure is used to compute various molecular descriptors. Themolecular structure is determined by the graphic molecular structurerepresentations provided by the Chemical Abstract Service (“CAS”), adivision of the American Chemical Society, Columbus, Ohio, U.S.A. Thesemolecular structures may be obtained from the CAS Chemical RegistrySystem database by looking up the index name or CAS number of each PRM.For PRMs, which at the time of their testing are not yet listed in theCAS Chemical Registry System database, other databases or informationsources may be used to determine their structures. For a PRM which haspotentially more than one isomer present, the molecular descriptorcomputations are conducted using the molecular structure of only one ofthe isomers, which is selected to represent that PRM. The selection ofisomer is determined by the relative amount of extension in themolecular structures of the isomers. Of all the isomers of a given PRM,it is the isomer whose molecular structure that is the most prevalentwhich is the one that is selected to represent that PRM. The structuresfor other potential isomers of that PRM are excluded from thecomputations. The molecular structure of the isomer that is the mostprevalent is paired with the concentration of that PRM, where theconcentration reflects the presence of all the isomers of that PRM thatare present.

A molecule editor or molecular sketching software program, such asChemDraw (CambridgeSoft/PerkinElmer Inc., Waltham, Mass., U.S.A.), isused to duplicate the 2-dimensional molecular structure representingeach PRM. Molecular structures should be represented as neutral species(quaternary nitrogen atoms are allowed) with no disconnected fragments(e.g., single structures with no counter ions). The winMolconn programdescribed below can convert any deprotonated functional groups to theneutral form by adding the appropriate number of hydrogen atoms and willdiscard the counter ion.

For each PRM, the molecular sketching software is used to generate afile which describes the molecular structure of the PRM. The file(s)describing the molecular structures of the PRMs is subsequentlysubmitted to the computer software program winMolconn, version 1.0.1.3(Hall Associates Consulting, Quincy, Mass., U.S.A., www.molconn.com), inorder to derive various molecular descriptors for each PRM. As such, itis the winMolconn software program which dictates the structurenotations and file formats that are acceptable options. These optionsinclude either a MACCS SDF formatted file (i.e., a Structure-Data File);or a Simplified Molecular Input Line Entry Specification (i.e., a SMILESstring structure line notation) which is commonly used within a simpletext file, often with a “.smi” or “.txt” file name extension. The SDFfile represents each molecular structure in the format of a multi-linerecord, while the syntax for a SMILES structure is a single line of textwith no white space. A structure name or identifier can be added to theSMILES string by including it on the same line following the SMILESstring and separated by a space, e.g.: C1=CC═CC═C1 benzene.

The winMolconn software program is used to generate numerous moleculardescriptors for each PRM, which are then output in a table format.Specific molecular descriptors derived by winMolconn are subsequentlyused as inputs (i.e., as variable terms in mathematical equations) for avariety of computer model test methods in order to calculate values suchas: saturation Vapour Pressure (VP); Boiling Point (BP); logarithm ofthe Octanol/Water Partition Coefficient (log P); Odour DetectionThreshold (ODT); Malodour Reduction Value (MORV); and/or UniversalMalodour Reduction Value (Universal MORV) for each PRM. The moleculardescriptor labels used in the models' test method computations are thesame labels reported by the winMolconn program, and their descriptionsand definitions can be found listed in the winMolconn documentation. Thefollowing is a generic description of how to execute the winMolconnsoftware program and generate the required molecular structuredescriptors for each PRM in a composition.

-   -   Computing Molecular Structure Descriptors using winMolconn:    -   1) Assemble the molecular structure for one or more perfume        ingredients in the form of a MACCS Structure-Data File, also        called an SDF file, or as a SMILES file.    -   2) Using version 1.0.1.3 of the winMolconn program, running on        an appropriate computer, compute the full complement of        molecular descriptors that are available from the program, using        the SDF or SMILES file described above as input.        -   a. The output of winMolconn is in the form of an ASCII text            file, typically space delimited, containing the structure            identifiers in the first column and respective molecular            descriptors in the remaining columns for each structure in            the input file.    -   3) Parse the text file into columns using a spreadsheet software        program or some other appropriate technique. The molecular        descriptor labels are found on the first row of the resulting        table.    -   4) Find and extract the descriptor columns, identified by the        molecular descriptor label, corresponding to the inputs required        for each model.        -   a. Note that the winMolconn molecular descriptor labels are            case-sensitive.

MORV and Universal MORV Calculation

-   1.) Input Molecular Descriptor values as determined via the method    above into the following four equations:

MORV=−8.5096+2.8597×(dxp9)+1.1253×(knotpv)−0.34484×(e1C2O2)−0.00046231×(idw)+3.3509×(idcbar)+0.11158×(n2pag22)  a)

MORV=−5.2917+2.1741×(dxvp5)−2.6595×(dxvp8)+0.45297×(e1C2C2d)−0.6202×(c1C2O2)+1.3542×(CdCH2)+0.68105×(CaasC)+1.7129×(idcbar)  b)

MORV=−0.0035+0.8028×(SHCsatu)+2.1673×(xvp7)−1.3507×(c1C1C3d)+0.61496×(c1C1O2)+0.00403×(idc)−0.23286×(nd2).  c)

MORV=−0.9926−0.03882×(SdO)+0.1869×(Ssp3OH)+2.1847×(xp7)+0.34344×(e1C3O2)−0.45767×(c1C2C3)+0.7684×(CKetone)  d)

Equation a) relates a material's effectiveness in reducing the malodortrans-3-methyl-2-hexenoic acid (carboxylic acid based malodors)Equation b) relates a material's effectiveness in reducing the malodortrimethylamine (amine based malodors)Equation c) relates a material's effectiveness in reducing the malodor3-mercapto-3-methylhexan-1-ol (thiol based malodors)Equation d) relates a material's effectiveness in reducing the malodorskatole (indole based malodors)

-   2.) For purpose of the present application, a material's MORV is the    highest MORV value from equations 1.)a) through 1.)d).-   3.) If all MORV values from equations 1.)a) through 1.)d) above are    greater than 0.5, the subject material has a Universal MORV.

Method for Assigning Fragrance Fidelity Index (FFI) and the BlockerIndex (BI) for a Malodor Reduction Compound

Blocker materials suitable for use in consumer products of the presentinvention are chosen for their ability to decrease malodor, while notinterfering with perception of a fragrance. Material selection is doneby assigning two indices to a test sample material from two referencescales in order to rank odor strengths. The two reference scales are theFragrance Fidelity Index (FFI) scale and the Blocker Index (BI) scale.The FFI ranks the ability of the test sample material to impart aperceivable odor which could cause interference when combined withanother fragrance and the BI ranks the ability of the test samplematerial to reduce malodor perception. The two methods for assigning theindices to a test sample on the FFI and the BI reference scales aregiven below.

Method for Assigning the FFI to Test Samples

The first step in the method for assigning an FFI to the test samples onthe FFI reference scale is to create the FFI reference swatches. Theswatches for the scale are created by treating clean fabrics swatcheswith a known amount of a known concentration of an ethyl vanillinsolution. Fabric swatches for this test are white knit polycotton (4inch×4 inch) swatches from EMC ordered as PC 50/50. The supplier isinstructed to strip the swatches first, stripping involves washing twicewith a fragrance-free detergent and rinsing three times.

Making the FFI Reference Swatches

Make three solutions of ethyl vanillin using a 50%/50% EtOH/water as thediluent at the following concentrations: 25 ppm, 120 ppm and 1000 ppm.Pipette 13 μL of each of the three solutions into the middle of a cleanswatch resulting in about a 1 cm diameter of the solution in the middleof the swatch. This will create a sensory scale of three swatches withthree different odor levels based on the concentration of the solutionpipetted onto the swatch. After drying for 30 minutes in a vented hood,the swatches are wrapped in aluminum foil to prevent odor contaminationto the treated swatch. A clean untreated swatch is also included as thelowest anchor point of reference for odor strength on the FFI scale. TheFFI reference scale swatches should be used within 0.5 to 12 hours anddiscarded after 12 hours. The swatches are used as scale anchor pointswhen graders evaluate a test sample(s) and are assigned a FragranceFidelity Index (FFI) as show in Table 7.

At least four perfumers/expert graders are used to rank the ethylvanillin swatches in the FFI scale. The perfumer/expert grader needs todemonstrate adequate discrimination on the scale. The perfumer/expertpanel is asked to rank order swatches according to a scale between 0 and3. The panel must demonstrate statistical differences between theswatches as seen in Table 7.

TABLE 7 Results FFI of reference swatches from six perfumers/expertgraders. Expert Grader Std FFI Swatch 1 2 3 4 5 6 Ave Dev. 0 Control:stripped 0 0 0.5 0 0 0 0.08 0.2 swatch NIL ethyl vanillin 1 Strippedswatch with 0.5 0.5 0.5 1.5 0.5 1.0 0.75 0.4 13 μL 25 ppm ethyl vanillin2 Stripped swatch with 2.0 1.5 1.5 2.0 2.0 2.0 1.8 0.2 13 μL 120 ppmethyl vanillin 3 Stripped swatch with 3.0 2.0 3.0 3.0 3.0 3.0 2.8 0.4 13μL 1000 ppm ethyl vanillin

The expert graders must demonstrate a full range of 2.5 over the 4swatches to be acceptably discriminating. Grader 2 in table 1 has arange of only 2 and is eliminated from the panel. The panel of expertgraders must also demonstrated the ability to statistically discriminatebetween swatches in the scale.

TABLE 8 This table demonstrates acceptable expert graders with anacceptable range and the panel meets the requirement for discriminatingstatistics. Expert Grader Std FFI Swatch 1 3 4 5 6 Ave Dev. 0 Control:stripped 0 0.5 0 0 0 0.08 0.2 swatch NIL ethyl vanillin 1 Strippedswatch with 0.5 0.5 1.5 0.5 1.0 0.80 0.4 13 μL 25 ppm ethyl vanillin 2Stripped swatch with 2.0 1.5 2.0 2.0 2.0 1.9 0.2 13 μL 120 ppm ethylvanillin 3 Stripped swatch with 3.0 3.0 3.0 3.0 3.0 3.0 0.0 13 μL 1000ppm ethyl vanillin

The reference swatches represent the 0, 1, 2, and 3 FFIs on the FFIreference scale, Table 9. The expert grader should familiarize them selfwith the strength of the odor on the FFI reference swatches by sniffingeach one starting at 0 (the lowest odor strength) and ending at 3 (thehighest odor strength). This should be done prior to evaluating the testsample material treated swatch.

TABLE 9 Swatch treatments comprising the Fragrance Fidelity Index (FFI)reference scale Swatch treatment Conc. of ethyl vanillin FFI Cleanfabric swatch w/13 μL ethyl vanillin 1000 ppm ethyl vanillin 3 Cleanfabric swatch w/13 μL ethyl vanillin  120 ppm ethyl vanillin 2 Cleanfabric swatch w/13 μL ethyl vanillin  25 ppm ethyl vanillin 1 Cleanfabric swatch NIL ethyl vanillin NIL ethyl vanillin 0Making Swatches Treated with the Test Material

A clean swatch is treated with 13 μL of a known concentration of a testsample material resulting in an about 1 cm of the solution on the cleanswatch. Just like the reference swatches, the test sample materialswatch is dried in a vented hood for 30 minutes and then wrapped inaluminum foil to prevent contamination. The test material swatches andthe FFI reference swatches should be made within 2 hours of each other.The test material swatch must be used within 0.5 to 12 hours anddiscarded after 12 hours.

Assigning the FFI to the Test Material

At least two perfumers/expert graders are used to assign an FFI grade toa test sample. The perfumer/expert grader smells the test sample swatchby holding that swatch 1 inch from their nose with their nose centeredover the area where the test sample was pipetted on to the fabric andthen assigns the test sample an FFI grade using the FFI reference scaleanchor swatches as references. The test sample swatch is assigned an FFIgrade at or between numbers on the FFI scale shown in Table 9. In caseswhere the test sample material is graded greater than 3, the testmaterial is not a blocker material or the concentration of the materialneeds to be lowered and reevaluated to determine if a lower level has amalodor blocker functionality.

Method for Assigning the BI to Test Sample

The first step in the method for assigning a BI to a test samplematerial on the BI reference scale is to create the BI referenceswatches. The swatches for the scale are created by treating cleanfabrics swatches with a known amount of a known volume of isovalericacid solution at a known concentration. Fabric swatches for this testare white knit polycotton (4 inch×4 inch) swatches from EMC ordered asPC 50/50. The supplier is instructed to strip the swatches first,stripping involves washing twice with a fragrance-free detergent andrinsing three times.

Making the BI Reference Swatches

Make one solution of 0.08% isovaleric acid using 50%/50% EtOH/water asthe diluent. The BI scale contains one clean swatch with no malodorapplied. Three other swatches each have a different volume of the 0.08%isovaleric acid applied. Pipette 2 μL of the 0.08% isovaleric acidsolution to one clean swatch, 5 μL of the 0.08% isovaleric acid solutionto the next swatch and 20 μL of isovaleric acid to the final cleanswatch. These solutions are pipetted to the middle of the swatches. Thiswill create a sensory scale of three swatches with three different odorlevels based on the volume of the 0.08% isovaleric acid solutionpipetted onto the swatch. After drying for 30 minutes in a vented hood,the swatches are wrapped in aluminum foil to prevent odor contaminationto the treated swatch. A clean untreated swatch is also included as thelowest anchor point of reference for malodor strength on the BI scale.The BI reference scale swatches should be used within 0.5 to 12 hoursand discarded after 12 hours. The swatches are used as scale anchorpoints when graders evaluate a test sample(s) and are assigned a BlockerIndex (BI) as show in Table 12.

At least four perfumers/expert graders are used to rank the isovalericacid swatches in the BI scale. The perfumer/expert grader needs todemonstrate adequate discrimination on the scale. The perfumer/expertgrader is asked to rank order swatches according to a scale between 0and 3. The panel of graders must demonstrate statistical differencesbetween the swatches as seen in Table 10.

TABLE 10 Results from six perfumers/expert graders to create the BIscale. Expert Grader Std BI Swatch 1 2 3 4 5 Ave Dev. 0 Control:stripped swatch 0 0 0 0 0 0 0 NIL isovaleric acid 1 Stripped swatch with2 μL 0.5 2.0 1.0 1.0 0.5 1.0 0.5 0.08% isovaleric acid 2 Stripped swatchwith 5 μL 2.0 2.5 2.0 2.0 2.0 2.1 0.2 0.08% isovaleric acid 3 Strippedswatch with 20 μL 3.0 3.0 3.0 3.0 2.5 2.8 0.2 0.08% isovaleric acid

The expert graders must demonstrate a full range of 2.5 over the 4swatches to be acceptably discriminating. The panel of expert gradersmust also demonstrated the ability to statistically discriminate betweenswatches in the scale. Expert grader #2 did not demonstrate the abilityto discriminate between the swatches and is eliminated from the panel,see Table 11.

TABLE 11 This table demonstrates acceptable expert graders with anacceptable range and the panel meets the requirement for discriminatingstatistics. Expert Grader Std BI Swatch 1 3 4 5 Ave Dev. 0 Control:stripped swatch 0 0 0 0 0 0 NIL isovaleric acid 1 Stripped swatch with 2μL 0.5 1.0 1.0 0.5 0.8 0.3 0.08% isovaleric acid 2 Stripped swatch with5 μL 2.0 2.0 2.0 2.0 2.0 0 0.08% isovaleric acid 3 Stripped swatch with20 μL 3.0 3.0 3.0 2.5 2.9 0.2 0.08% isovaleric acid

The reference swatches represent the 0, 1, 2, and 3 BIs on the BIreference scale, Table 12. The expert grader should familiarizeshim/herself with the strength of the odor on the BI reference swatchesby sniffing each one starting at 0 (the lowest odor strength) and endingat 3 (the highest odor strength). This should be done prior toevaluating the swatch treated with the test material.

TABLE 12 Swatch treatments comprising the Blocker Index (BI) referencescale. Swatch/treatment Wt of isovaleric acid BI Clean fabric swatchw/20 μL 0.08%  16 mg isovaleric acid 3 isovaleric acid Clean fabricswatch w/5 μL 0.08%   4 mg isovaleric acid 2 isovaleric acid Cleanfabric swatch w/2 μL 0.08% 1.6 mg isovaleric acid 1 isovaleric acidClean fabric swatch NIL isovaleric acid NIL isovaleric acid 0Making the Malodorous Swatch and Treating it with a Test Material

To evaluate the BI, the test material is applied to a malodorous swatchto determine how well the test material blocks the malodor. Themalodorous swatch is made by treating a clean swatch with 20 μL of a0.08% solution of isovaleric acid. Dry the malodorous swatch treatedwith isovaleric acid in a vented hood for 30 minutes. After drying themalodorous swatch a known concentration of test material solution,between 1 ppm and 100 ppm is pipetted onto the malodorous swatch. Applythe test material solution right on top of the spot where the isovalericacid solution was applied making an about 1 cm diameter spot. Just likethe BI reference swatches, the isovaleric acid+test material swatch isdried in a vented hood for 30 minutes and then wrapped in aluminum foilto prevent contamination. The isovaleric acid+test material swatches andthe BI reference swatches should be made within 2 hours of each other.The isovaleric acid+test material swatch must be used between 1-12 hoursjust like the reference swatches. It is sometimes necessary to evaluateseveral levels of the test material between about 1 and about 100 ppm todetermine the BI.

Assigning the BI to the Test Material

At least two perfumers/expert graders are used to assign the BI to thetest sample. The expert grader smells the isovaleric acid+test materialswatch by holding that swatch one inch from their nose with their nosecentered over the area where the test sample was pipetted on to thefabric and then assigns the isovaleric acid+test material swatch a BIbased on ranking its odor strength against the odor strength of theswatches in the BI reference scale. The test sample swatch is assigned aBI at or between numbers on the BI in table. In cases where theisovaleric acid+test material swatch odor is greater than 3 on the BIreference scale, this indicates the material is not a blocker or theconcentration of the test material needs to be lowered to achieve itsblocker functionality.

Malodor Reduction Compounds with FFI and BI Grades based on theaforementioned Table Ref # CAS# log P Name Conc FFI BI 281 54830-99-83.11 3a,4,5,6,7,7a-hexahydro-4,7- 10 ppm 0 2.0 methano-1H-indenylacetate 50 ppm 0.5 2.0 677 139504-68-0 3.75 1-((2-(tert- 10 ppm 0 2.3butyl)cyclohexyl)oxy)butan-2-ol 50 ppm 1.8 2.0 962 55066-48-3 3.173-methyl-5-phenylpentan-1-ol 10 ppm 0 2.3 50 ppm 0.5 1.7 261 173445-65-33.29 3-(3,3-dimethyl-2,3-dihydro-1H- 10 ppm 0 1.8 inden-5-yl)propanal 50ppm 1.3 1.3 1139 87731-18-8 2.11 (Z)-cyclooct-4-en-1-yl methyl 10 ppm 02.0 carbonate 50 ppm 1.0 2.7 4430-31-3 1.433,4,4a,5,6,7,8,8a-octahydrochromen- 10 ppm 0 2.0 2-one 50 ppm 0 2.0 20440379-24-6 3.89 7-methyloctyl acetate 10 ppm 0 2.0 50 ppm 0 2.7 100593981-50-1 5.59 ethyl (2,3,6-trimethylcyclohexyl) 50 ppm 0.5 2.6carbonate 391 106-33-2 5.73 Ethyl laurate 50 ppm 0.3 2.2 1148 1139-30-64.06 Caryophyllene Oxide 50 ppm 0.5 2.3 524 13877-91-3 4.313,7-Dimethyl-1,3,6-Octatriene(cis-β 50 ppm 0 2.8 3338-55-4 ocimene 70%)1149 23787-90-8 4 1,3,4,6,7,8alpha-hexahydro- 10 ppm 0 1.51,1,5,5-tetramethyl-2H-2,4alpha- 50 ppm 0.8 2.3 methanophtalen-8(5H)-one112-42-5 4.62 Undecanol 50 ppm 0.8 2.3 174 112-53-8 5.17 1-dodecanol 50ppm 0.5 2.3 98-52-2 2.78 4-tert-butyl cyclohexane 10 ppm 0 2.0 50 ppm0.3 2.0 109 112-39-0 6.41 Methyl palmitate 10 ppm 2.0Malodor Control Compounds with Improved Performance at Lower Levels.

Below are some non-limiting examples of preferred behavior by which themalodor control compound gives improved malodor control at lowerconcentration. These nonlimiting data provide additional compelling datathat malodor is being blocked, not masked.

Table Ref # CAS# Name Conc FFI BI N/A 68912-13-08,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7- 10 ppm 0 1.5methanoinden-6-yl propionate 50 ppm 0 2.2 N/A TBD4,8-dimethyl-1-(methylethyl)-7-oxybiciclo 10 ppm 2.0 [4.3.0]nonane 50ppm 0.3 2.2about 0.001 Fragrance Fidelity989898989898989898989898989898989898989898989898989898989898989898989898989898999999999999999999999999999999999999999999999999999999999999999999999999999999999999999999999999999999999999999999

Retesting Malodor Reduction Compounds at Lower Levels.

The example below demonstrates that while a malodor control compoundcould fail to demonstrate odor blocking (BI>2.5) at a higherconcentration it should be retested at a lower concentration todetermine if it passes.

Table Ref # CAS # Name Conc FFI BI N/A 173445-65-3 1H-Indene-5-propanal,10 ppm 0 1.5 2,3-dihydro-3,3-dimethyl- 50 ppm 0.5 2.7

Example 1 Compositions Comprising Malodor Reduction Compounds

In the present invention blends enable more potent malodor reductionbecause blends are useful at a higher % of the product compositionbefore becoming olfactively noticeable. Below are non-limiting examplesof malodor reduction compounds.

% wt Active Component CAS# A B C D E 2,2,8,8-tetramethyl-octahydro-1H-29461-14-1 35-45 15-25  5-20 10-30 15-25 2,4a-methanonapthalene-10-one1H-Indene-ar-propanal, 2,3- 300371-33-9 10-20  1-30 NIL  5-10 1-5dihydro-1,1-dimethyl- Hexadecanoic acid, (2E)-3,7- 3681-73-0 35-45 10-25NIL 30-40 35-50 dimethyl-2,6-octadien-1-yl ester1-Pentanol-3-methyl-5-phenyl 55066-48-3 10-20 10-25  2-10  5-17 104,7-Methano-1H-inden-5-ol, 171102-41-3 0-5 10-25 NIL 1-6 1-53a,4,5,6,7,7a-hexahydro-, 5-acetate 4,8-dimethyl-1-(methylethyl)-7- N/A0-5 NIL NIL NIL 1-5 oxybiciclo [4.3.0]nonane(3Z)-3,7-dimethylocta-1,3,6-triene 3338-55-4 NIL NIL 10-20 2-5 NIL1H-Indene-5-propanal, 2,3- 173445-65-3 NIL NIL NIL 7.5-16   1-15dihydro-3,3-dimethyl- 3,4,4a,5,6,7,8,8a- 4430-31-3 NIL NIL NIL 3-7  1-15octahydrochromen-2-one 1-(2-tert- 139504-68-0 NIL NIL NIL 0.25-1.5  NILbutylcyclohexyl)oxybutan-2-ol ethyl (2,3,6-trimethylcyclohexyl)93981-50-1 NIL NIL 15-30 NIL  2 carbonate benzyl 2-hydroxypropanoate2051-96-9 NIL NIL 2-5 NIL NIL (3,5-dimethylcyclohex-3-en-1- 67634-16-6NIL NIL  5-30 NIL NIL yl)methanol 2-Dodecanol 10203-28-8 NIL 0.25-1  NIL 0.5-3  NIL

Example 2 Compositions Comprising Malodor Reduction Compounds

% wt Active Ingredient CAS# A B C B D E (E)-1-(2,6,6-trimethyl-1-127-42-4  4 8 2 8  3 2 cyclohex-2-enyl)pent-1-en-3- one ethyldodecanoate 106-33-2 NIL 1 NIL 3 NIL NIL 3a,4,5,6,7,7a-hexahydro-1H-68912-13-0  8 30 1 4  1 3.5 4,7-methanoinden-1-yl propanoate[1R-(1R*,4R*,6R*,10S*)]- 1139-30-6 NIL 0.3 2 0.5 NIL 0.54,12,12-trimethyl-9- methylene-5- oxatricyclo[8.2.0.04,6]dodecane(8E)-cyclohexadec-8-en-1-one 3100-36-5 NIL 5 NIL 7 NIL NIL3,5,5-trimethylhexyl acetate 58430-94-7 25 15 50  35 60 56 ethyl (2,3,6-93981-50-1 NIL 1 NIL 5 NIL NIL trimethylcyclohexyl) carbonate2,4-dimethyl-4,4a,5,9b- 27606-09-3 25 10 15  15 16 15tetrahydroindeno[1,2- d][1,3]dioxine 2,2,7,7- 23787-90-8  8 9 5 7  5 5tetramethyltricyclo[6.2.1.01,6] undecan-5-one(3,5-dimethylcyclohex-3-en- 67634-16-6 NIL 0.7 NIL 0.5 NIL NIL1-yl)methanol 3-(7,7-dimethyl-4- 33885-52-8 30 20 25  15 15 18bicyclo[3.1.1]hept-3-enyl)- 2,2-dimethylpropanal Total 100  100 100  100100  100

Example 3 Malodor Reduction Composition

% wt Active Ingredient CAS # A B C 5-Cyclohexadecen-1-One 37609-25-915.0 2.00 2.00 decahydro-2,2,7,7,8,9,9- 476332-65-7 0.005 0.01 0.01heptamethylindeno(4,3a-b)furan 2,3-Dihydro-5,6-dimethoxy-2-(4-33704-61-9 0.3 0.5 0.5 piperidinylmethylene)-1H-inden-1-one CedrylMethyl Ether 19870-74-7 6.0 10.0 4.0 Trans-4-Decenal 65405-70-1 0.0050.002 0.002 Decyl Aldehyde 112-31-2 3.74 2.0 2.0 3-methylcyclopentadecenone 63314-79-4 0.4 1.0 1.0 Diphenyl Oxide 101-84-8 0.51.0 1.0 3a,4,5,6,7,7a-hexahydro-4,7-methano- 54830-99-8 5.0 8.0 8.01H-indenyl acetate 3a,4,5,6,7,7a-hexahydro-1H-4,7- 68912-13-0 6.0 8.08.0 methanoinden-1-yl propanoate 2-(5-methyl-2-propan-2-yl-8- 68901-32-610.0 15.0 15.0 bicyclo[2.2.2]oct-5-enyl)-1,3-dioxolane(E)-3,7-dimethyl-2,6- 3681-73-0 10.0 10.0 16.0 octadienylhexadecanoateIso Nonyl Acetate 58430-94-7 6.65 8.0 3.0 2,2,7,7- 23787-90-8 10.0 8.08.0 tetramethyltricyclo[6.2.1.01,6]undecan-5- one (1-Methyl-2-(1,2,2-198404-98-7 0.1 0.3 0.3 trimethylbicyclo[3.1.0]-hex-3-ylmethyl)cyclopropyl)methanol Lauric Aldehyde 112-54-9 0.625 1.0 0.7Methyl Iso Eugenol 93-16-3 18.000 10.0 13.0 Methyl hexadecanoate112-39-0 3.000 10.0 12.0 2,3-dihydro-1,1-1H-dimethyl-indene-ar-300371-33-9 0.400 0.0 0.3 propanal 4-tert-butylcyclohexanol 98-52-20.400 0.1 0.1 2-isobutyl-4-hydroxy-4- 63500-71-0 1.600 2.0 2.0methyltetrahydropyran Undecyl Aldehyde 112-44-7 1.725 2.888 1.888Undecylenic Aldehyde 112-45-8 0.550 0.2 1.2 Total 100 100.0 100.0

Example 4 Dryer Added Fabric Softener Sheet Composition

An example of a dryer added fabric softener sheet composition preparedwith malodor reduction composition, according to the compositions shownin Example 1.

Example 10.1 Example 10.2 Example 10.3 Example 10.4 Ingredient Wt %Active Wt % Active Wt % Active Wt % Active DEQA¹ 0-50 50 — — DEQA² 0-50— — 30 DTDMAMS³ 0-50 — 50 — 7018FA⁴ 0-50 — 50 — TS-20⁵ 0-15 — — 15 SMS⁶0-15 — — 15 SDASA⁷ 0-19 25 — 19 TPED⁸ —  3 — — Complex⁹ 0-16.5 16.5 — 8.0 Clay¹⁰ Balance Balance Balance Balance Free (Neat) Perfume 0-40-1.5 0-3 0-1.5 Free (Neat) malodor reducing 0 to 0.5 0 to 0.5 0-0.50-0.5 composition Encapsulated Perfume/malodor 0-2 0-2 0-2 0-2 reducingcomposition¹¹ Encapsulated Perfume¹¹ 0-4 0-4 0-2 0-2 Encap. malodorreducing 0-4 0-2 0-2 0-2 composition¹¹ Active Weight 2.4  2.4  1.9  2.4(g/sheet) ¹DEQA¹: Di(soft tallowoyloxyethyl)dimethylammonium methylsulfate with 25% > 7018 FA, as described below, as solvent ²DEQA²:Di(soft tallowoyloxyethyl)hydroxyethylmethylammoniun methyl sulfate with18% >> partially hydrogenated tallow fatty acid solvent ³DTDMAMS:Di(hydrogenated tallowalkyl)dimethylammonium methyl sulfate ⁴7018FA:70:30 Stearic Acid:Palmitic Acid (IV = 0) Industrene 7018 sold by Witco⁵TS-20: Polyoxyethylene-20 Sorbitan Tristearate (Glycosperse TS-20, soldby Lonza ⁶SMS: Sorbitan Mono Stearate ⁷SDASA: 1:2 ratio of stearyldimethyl amine:triple pressed stearic acid ⁸TPED:N,N,N′,N′-Tetrakis(2-hydroxypropyl)ethylenediamine (Quadrol, sold byBASF) ⁹Complex: Beta-Cyclodextrin/Perfume Complex ¹⁰Clay: CalciumBentonite Clay (Bentonite L sold by Southern Clay Products Free (Neat)Perfume ¹¹PMC is a friable shell. About 50% water by weight of the PMC(including encapsulated perfume and/or blocker) is assumed. The microcapsule encapsulates perfume, malodor reduction composition, orcombinations thereof with the total internal phase at about 32% active

The compositions of Example 6 are mixed homogeneously and impregnatedonto a non-woven polyester sheet having dimensions of about 6% in ×12″(about 17.1 cm×30.5 cm) and weighing about 1 gram.

The resulting dryer added fabric softener sheet product when added to anautomatic dryer is effective at reducing malodor on the clothing.

The dimensions and values disclosed herein are not to be understood asbeing strictly limited to the exact numerical values recited. Instead,unless otherwise specified, each such dimension is intended to mean boththe recited value and a functionally equivalent range surrounding thatvalue. For example, a dimension disclosed as “40 mm” is intended to mean“about 40 mm.”

Every document cited herein, including any cross referenced or relatedpatent or application, is hereby incorporated herein by reference in itsentirety unless expressly excluded or otherwise limited. The citation ofany document is not an admission that it is prior art with respect toany invention disclosed or claimed herein or that it alone, or in anycombination with any other reference or references, teaches, suggests,or discloses any such invention. Further, to the extent that any meaningor definition of a term in this document conflicts with any meaning ordefinition of the same term in a document incorporated by reference, themeaning or definition assigned to that term in this document shallgovern.

While particular embodiments of the present invention have beenillustrated and described, it would be obvious to those skilled in theart that various other changes and modifications can be made withoutdeparting from the spirit and scope of the invention. It is, therefore,intended to cover in the appended claims all such changes andmodifications that are within the scope of this invention.

What is claimed:
 1. An article comprising a) a substrate, preferably aflexible substrate, more preferably a flexible substrate that is asheet; preferably said substrate comprises a fabric softening active,preferably said fabric softening active coats all or a portion of saidsubstrate; b) a sum total from about 0.00025% to about 1%, preferablyfrom about 0.0025% to about 0.1%, more preferably from about 0.005% toabout 0.075%, most preferably from about 0.01% to about 0.05% of 1 ormore malodor reduction materials, preferably 1 to about 20 malodorreduction materials, more preferably 1 to about 15 malodor reductionmaterials, most preferably 1 to about 10 malodor reduction materials,each of said malodor reduction materials having a MORV of at least 0.5,preferably from 0.5 to 10, more preferably from 1 to 10, most preferablyfrom 1 to 5, and preferably each of said malodor reduction materialshaving a Universal MORV, said sum total of malodor reduction materialshaving a Blocker Index of less than 3, more preferable less than about2.5 even more preferably less than about 2 and still more preferablyless than about 1 and most preferably 0 and/or a Blocker Index averageof 3 to about 0.001.
 2. An article according to claim 1, wherein saidmalodor reduction materials have a Fragrance Fidelity Index of fromabout less than 3, more preferable less than about 2.5 even morepreferably less than about 2 and still more preferably less than about 1and most preferably 0 or a Fragrance Fidelity Index average of 3 toabout 0.001.
 3. An article according to any preceding claim, saidarticle comprising a perfume and having a weight ratio of parts ofmalodor reduction composition to parts of perfume of from about 1:20,000to about 3000:1, preferably from about 1:10,000 to about 1,000:1, morepreferably 5,000:1 to about 500:1 and most preferably from about 1:15 toabout 1:1.
 4. An article according to any preceding claim, comprisingone or more malodor reduction materials having a log P greater than 3,preferably greater than 3 but less than 8, preferably said one or moremalodor reduction materials are selected from the group consisting of2-ethylhexyl (Z)-3-(4-methoxyphenyl)acrylate;2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-1,3-dioxolane;1,1-dimethoxynon-2-yne;3-methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decane;methoxycyclododecane; 1,1-dimethoxycyclododecane;(Z)-tridec-2-enenitrile; (2-hydroxy-4-methoxyphenyl)(phenyl)methanone;2,4a,5,8a-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ylformate; 1,8-dioxacycloheptadecan-9-one;4-(tert-pentyl)cyclohexan-1-one; 2-methoxy-1,1′-biphenyl;3a,5,6,7,8,8b-hexahydro-2,2,6,6,7,8,8-heptamethyl-4H-indeno(4,5-d)-1,3-dioxole;7-isopropyl-8,8-dimethyl-6,10-dioxaspiro[4.5]decane; octylfuran-2-carboxylate; octyl acetate; 2-heptyl-4-methyl-1,3-dioxolane;octanal; 1,1-dimethoxyoctane; 7-methyl-3-methyleneocta-1,6-diene;2-methyl-6-methyleneoct-7-en-2-yl acetate; tetradecanal;tetradecanenitrile;2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-octahydronaphthalen-1-ol;2-((1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethyl acetate;(4R,4aS,6R)-4,4a-dimethyl-6-(prop-1-en-2-yl)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one;nonan-1-ol; nonanal; 12-methyl-14-tetradec-9-enolide;N-ethyl-2-isopropyl-5-methylcyclohexane-1-carboxamide;2-methoxynaphthalene; (E)-3,7,11-trimethyldodeca-1,6,10-trien-3-ol;(Z)-3,7-dimethylocta-2,6-dien-1-ol; methyl (E)-non-2-enoate;10-isopropyl-2,7-dimethyl-1-oxaspiro[4.5]deca-3,6-diene;2-(2-(4-methylcyclohex-3-en-1-yl)propyl)cyclopentan-1-one;(E)-4-(2,2,3,6-tetramethylcyclohexyl)but-3-en-2-one;(4-(4-methylpent-3-en-1-yl)cyclohex-3-en-1-yl)methyl acetate;2-(tert-butyl)-4,5,6-trimethyl-1,3-phenylene dinitrite;1,7-dioxacycloheptadecan-8-one;1-(4-(tert-butyl)-2,6-dimethyl-3,5-dinitrophenyl)ethan-1-one;1-(tert-butyl)-2-methoxy-4-methyl-3,5-dinitrobenzene;3-methylcyclopentadecan-1-one; (E)-3-methylcyclopentadec-4-en-1-one;1-(4-isopropylcyclohexyl)ethan-1-ol; (E)-dec-5-enoic acid; methylnon-2-ynoate; 2-methyldecanal; 6,6-dimethoxy-2,5,5-trimethylhex-2-ene;methyl stearate; 1,1-dimethoxy-2-methylundecane; undecan-2-one;2-methylundecanal; methyl tetradecanoate; methyl(9Z,12Z)-octadeca-9,12-dienoate; methyl palmitate;1-methyl-2-phenoxybenzene; 1-allyl-4-methoxybenzene;1-(naphthalen-2-yl)ethan-1-one; methyl oct-2-ynoate; methyl2,6,6-trimethylcyclohex-2-ene-1-carboxylate;7-isopropyl-10-methyl-1,5-dioxaspiro[5.5]undecan-3-ol;3-(3-(tert-butyl)phenyl)-2-methylpropanal;(E)-4-(4,8-dimethylnona-3,7-dien-1-yl)pyridine;(E)-trideca-3,12-dienenitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol;8-isopropyl-6-methylbicyclo[2.2.2]oct-5-ene-2-carbaldehyde;(S)-1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene;3,7-dimethylocta-1,6-dien-3-yl octanoate; 3,7-dimethylocta-1,6-dien-3-ylisobutyrate; 3,7-dimethylocta-1,6-dien-3-yl benzoate;3,7-dimethylocta-1,6-dien-3-yl 2-aminobenzoate;(2Z,6E)-3,7-dimethylnona-2,6-dienenitrile;3-(4-methylcyclohex-3-en-1-yl)butanal;(2,5-dimethyl-1,3-dihydroinden-2-yl)methanol;3-(4-(tert-butyl)phenyl)-2-methylpropanal; dodecan-1-ol; dodecylacetate; dodecanoic acid; 5-hexyl-5-methyldihydrofuran-2(3H)-one;dodecanal; 4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexan-1-one;((3S,3aR,6R,8aS)-7,7-dimethyl-8-methyleneoctahydro-1H-3a,6-methanoazulen-3-yl)methanol;5-(sec-butyl)-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane;(1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)cyclopropyl)methanol;2-propylheptanenitrile; 2-hexylcyclopentan-1-one;2,6,9,10-tetramethyl-1-oxaspiro(4.5)deca-3,6-diene; isopropyl palmitate;isopropyl tetradecanoate; isopropyl dodecanoate;(E)-cyclohexadec-8-en-1-one;(2S,5S)-2-isopropyl-5-methylcyclohexan-1-one;2-hexylcyclopent-2-en-1-one;(2S,5S)-2-isopropyl-5-methylcyclohexan-1-one;4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde;(Z)-1-(benzyloxy)-2-methoxy-4-(prop-1-en-1-yl)benzene;1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one;6-(sec-butyl)quinoline;2-(cyclohexyloxy)-1,7,7-trimethylbicyclo[2.2.1]heptane;(1R,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl propionate;(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate;4-((2R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexan-1-ol;(1R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate;2-(4-isopropylcyclohexa-1,4-dien-1-yl)ethyl formate; isopentyl(E)-undec-6-enoate; isopentyl dodecanoate;(E)-oxacycloheptadec-10-en-2-one; (E)-non-2-enenitrile;(E)-8-(1H-indol-1-yl)-2,6-dimethyloct-7-en-2-ol;8,8-di(1H-indol-1-yl)-2,6-dimethyloctan-2-ol; 2-cyclododecylpropan-1-ol;3-methyl-5-phenylpentanenitrile;2,3-dihydro-3,3-dimethyl-1H-indene-5-propanal;3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal; hexyl octanoate;hexyl hexanoate; (Z)-2-benzylideneoctanal; hexyl benzoate;(Z)-hex-1-en-1-yl (Z)-2-methylbut-2-enoate;(E)-3,7-dimethylocta-2,6-dien-1-yl palmitate; oxacycloheptadecan-2-one;ethyl (1R,2R,3R,4R)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate;2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl propionate;(E)-oxacyclohexadec-13-en-2-one;6-butyl-2,4-dimethyl-3,6-dihydro-2H-pyran;2-((3S,5R,8S)-3,8-dimethyl-1,2,3,4,5,6,7,8-octahydroazulen-5-yl)propan-2-ol;1-(2,6,6-trimethylcyclohex-2-en-1-yl)pentan-3-one; ethyl2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate;(1Z,5Z)-1,5-dimethyl-8-(propan-2-ylidene)cyclodeca-1,5-diene;(1E,6E)-8-isopropyl-1-methyl-5-methylenecyclodeca-1,6-diene;(E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate;(E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate;(6E,10E)-3,7,11,15-tetramethylhexadeca-1,6,10,14-tetraen-3-ol;(E)-2-(3,7-dimethylocta-2,6-dien-1-yl)cyclopentan-1-one;5-heptyldihydrofuran-2(3H)-one; 1-methyl-4-(propan-2-ylidene)cyclohexylacetate; 1-methyl-4-(propan-2-ylidene)cyclohexan-1-ol;(1R,4aR,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene;(Z)-4-(2,2-dimethyl-6-methylenecyclohexyl)but-3-en-2-one;(4aS,9aR)-3,5,5,9-tetramethyl-2,4a,5,6,7,9a-hexahydro-1H-benzo[7]annulene;(1R,3aR,4R,7R)-1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene;2-((2R,4aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol;5-octyldihydrofuran-2(3H)-one;(Z)-1-(2,2-dimethyl-6-methylenecyclohexyl)but-2-en-1-one;(1R,4aS,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene;1-(3,3-dimethylcyclohexyl)pent-4-en-1-one;4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene;furan-2-ylmethyl octanoate; furan-2-ylmethyl hexanoate; furan-2-ylmethylheptanoate; 2-methyldecanenitrile;8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-ylpropionate;ethyl(3aR,4S,7R,7aR)-octahydro-3aH-4,7-methanoindene-3a-carboxylate;(6-isopropyl-9-methyl-1,4-dioxaspiro[4.5]decan-2-yl)methanol;undec-10-enenitrile; 3-(2-ethylphenyl)-2,2-dimethylpropanal;(E)-4,8-dimethyldeca-4,9-dienal;(E)-4-((3aR,4R,7R,7aR)-1,3a,4,6,7,7a-hexahydro-5H-4,7-methanoinden-5-ylidene)-3-methylbutan-2-ol;8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate;3-(4-ethylphenyl)-2,2-dimethylpropanenitrile; 2-heptylcyclopentan-1-one;1-ethoxyethoxy Cyclododecane; 3-cyclohexene-1-carboxylic acid,2,6,6-trimethyl-, methyl ester;(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-yl acetate;(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol;oxacyclohexadecan-2-one; (E)-cyclopentadec-4-en-1-one;1-cyclopentadec-4-en-1-one; 1,4-dioxacycloheptadecane-5,17-dione; ethylundec-10-enoate; ethyl palmitate; ethyl nonanoate; ethyl tetradecanoate;(E)-3,7-dimethylnona-1,6-dien-3-ol; ethyl dodecanoate; ethyl decanoate;ethyl 6,6-dimethyl-2-methylenecyclohex-3-ene-1-carboxylate;6-ethyl-2,10,10-trimethyl-1-oxaspiro[4.5]deca-3,6-diene;2-((1R,3S,4S)-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohexyl)propan-2-ol;(E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol;(E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal;1,1-dimethoxydodecane; (R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene;7,9-dimethylspiro[5.5]undecan-3-one; oxydibenzene; diphenylmethane;2-methyl-1-phenylpropan-2-yl butyrate;octahydro-1H-4,7-methanoinden-5-yl acetate;2-methyl-5-(prop-1-en-2-yl)cyclohexyl acetate;3,7-dimethyloct-6-en-3-ol; dibutylsulfane; 1,2-diphenylethane;6-hexyltetrahydro-2H-pyran-2-one;(3R,4R)-1-isopropyl-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohex-1-ene;(3S,3aS,5R)-3,8-dimethyl-5-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene;6-heptyltetrahydro-2H-pyran-2-one;(1S,8aR)-4,7-dimethyl-1-(propan-2-yl)-1,2,3,5,6,8a-hexahydronaphthalene;(Z)-1-((1R,2S)-2,6,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;(1S,8aS)-1-isopropyl-4,7-dimethyl-1,2,3,5,6,8a-hexahydronaphthalene;3,7,7-trimethylbicyclo[4.1.0]hept-3-ene; dec-9-en-1-ol; decylpropionate; 1,1-diethoxydecane; 1-cyclohexylethyl (E)-but-2-enoate;3-(4-isopropylphenyl)-2-methylpropanal; cyclotetradecane;cyclopentadecanone; cyclohexyl 2-hydroxybenzoate;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl butyrate;8,8-dimethyl-1,2,3,4,5,6,7,8-octahydronaphthalene-2-carbaldehyde;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-5-yl isobutyrate;(5R,6R)-3,6-dimethyl-5-(prop-1-en-2-yl)-6-vinyl-4,5,6,7-tetrahydrobenzofuran;2-(3-phenylpropyl)pyridine; dodecanenitrile;(E)-cycloheptadec-9-en-1-one;3-(4-methylcyclohex-3-en-1-yl)but-3-en-1-yl acetate;3-(4-methylcyclohex-3-en-1-yl)butan-1-ol;(E)-3-methyl-5-phenylpent-2-enenitrile;(E)-2-(2,6-dimethylhepta-1,5-dien-1-yl)-4-methyl-1,3-dioxolane;(E)-1,1-dimethoxy-3,7-dimethylocta-2,6-diene;(E)-1,1-diethoxy-3,7-dimethylocta-2,6-diene;(E)-3,7-dimethylocta-1,3,6-triene; (E)-oxacycloheptadec-11-en-2-one;(Z)-dec-4-enal; (E)-hex-3-en-1-yl (E)-hex-3-enoate; (Z)-hex-3-en-1-yl2-hydroxybenzoate; (Z)-hex-3-en-1-yl benzoate; (Z)-hex-3-en-1-yl2-methylbutanoate; cinnamyl propionate; cinnamyl isobutyrate; cinnamylcinnamate; hexadecan-1-ol;(E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)hepta-1,6-dien-3-one;2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)butanal;(3aR,5aR,9aR,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan;1,6-dioxacycloheptadecan-7-one;1-(6-(tert-butyl)-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl)ethan-1-one;(3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene;(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-3-ylformate;(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-ylacetate; (4Z,8Z)-1,5,9-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene;(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-ol;5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane;5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane;1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro-4H-inden-4-one;(Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-3-en-5-yl acetate;(1S,2S,5R,8S)-4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-ol;2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-yl acetate; octanenitrile;decanoic acid; decanal; 2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane;ethyl 2-methyl-4-oxo-6-pentylcyclohex-2-ene-1-carboxylate;2,6-di-tert-butyl-4-methylphenol; butyl stearate; butyl undec-10-enoate;2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)butan-1-ol;3-(4-(tert-butyl)phenyl)propanal;(1S,2S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate;1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate;2-ethoxy-2,6,6-trimethyl-9-methylenebicyclo[3.3.1]nonane;(ethoxymethoxy)cyclododecane;(E)-1-methyl-4-(6-methylhept-5-en-2-ylidene)cyclohex-1-ene;3,3,6,7-tetramethyloctahydro-2H-chromene;(5R,10R)-6,10-dimethyl-2-(propan-2-ylidene)spiro[4.5]dec-6-en-8-one;1-methyl-4-(prop-1-en-2-yl)cyclohexyl acetate;(2Z,6E)-2,6-dimethyl-10-methylenedodeca-2,6,11-trienal;(R)-3-methylene-6-((S)-6-methylhept-5-en-2-yl)cyclohex-1-ene;(4aR,7R,8aS)-4a-methyl-1-methylene-7-(prop-1-en-2-yl)decahydronaphthalene;(Z)-2-methyl-5-((1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]heptan-2-yl)pent-2-en-1-ol;6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane; 2-ethoxynaphthalene;(1S,4R,7R)-1,4,9,9-tetramethyl-1,2,3,4,5,6,7,8-octahydro-4,7-methanoazulene;(1aS,5aR,9aR)-1a,5,5,7-tetramethyl-1a,2,3,4,5,5a,8,9-octahydrobenzo[1,7]cyclohepta[1,2-b]oxirene;(R)-3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzo[7]annulene;(1S,4S)-1,4-dimethyl-7-(propan-2-ylidene)-1,2,3,4,5,6,7,8-octahydroazulene;(E)-7,11-dimethyl-3-methylenedodeca-1,6,10-triene;(1R,2S,6S,7S,8S)-8-isopropyl-1-methyl-3-methylenetricyclo[4.4.0.02,7]decane;(3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro-1H-3a,7-methanoazulene;(1R,9S,Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene;(S)-4-methyl-1-((S)-6-methylhept-5-en-2-yl)cyclohex-3-en-1-ol; benzyldodecanoate; benzyl cinnamate; benzyl benzoate;2′-isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4′-[1,3]dioxane];4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbonitrile; methyl(E)-2-((7-hydroxy-3,7-dimethyloctylidene)amino)benzoate; 4-methoxybenzyl2-phenylacetate; pentyl (Z)-3-phenylacrylate;(3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan;(4aR,5R,7aS,9R)-2,2,5,8,8,9a-hexamethyloctahydro-4H-4a,9-methanoazuleno[5,6-d][1,3]dioxole;2,5,5-trimethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-ol;2,5,5-trimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-ol;1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol;(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-tetramethyldodecahydro-5H-3,5a-epoxynaphtho[2,1-c]oxepine;2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-b]furan;2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan;2-(sec-butyl)-1-vinylcyclohexyl acetate;(4R,4aS)-4,4a-dimethyl-6-(propan-2-ylidene)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one;2-(4-methylcyclohex-3-en-1-yl)propan-2-yl propionate;(2Z,6E,9E)-2,6,10-trimethyldodeca-2,6,9,11-tetraenal;(2R,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene;1,7-dimethyl-7-(4-methylpent-3-en-1-yl)tricyclo[2.2.1.02,6]heptane;(E)-5-(2,3-dimethyltricyclo[2.2.1.02,6]heptan-3-yl)-2-methylpent-2-en-1-ol;(1R,3aS,7S,8aR)-1,4,9,9-tetramethyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methanoazulene;1-(5,5-dimethylcyclohex-1-en-1-yl)pent-4-en-1-one;(1S,4aS,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene;(R,Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)pent-1-en-3-one;1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene;(Z)-4-(2,5,6,6-tetramethylcyclohex-2-en-1-yl)but-3-en-2-one;(1Z,4E,8Z)-2,6,6,9-tetramethylcycloundeca-1,4,8-triene;(4aR,8S,9aS)-3,5,5,8-tetramethyl-9-methylene-2,4a,5,6,7,8,9,9a-octahydro-1H-benzo[7]annulene;(1aR,4R,4aR,7bS)-1,1,4,7-tetramethyl-1a,2,3,4,4a,5,6,7b-octahydro-1H-cyclopropa[e]azulene;1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,4,5,6,7,8-octahydroazulene;(3E,6E)-3,7,11-trimethyldodeca-1,3,6,10-tetraene;7,7-dimethyl-2-methylenebicyclo[2.2.1]heptane;2-((2R,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol;(R)-1-methyl-4-(6-methylhept-5-en-2-yl)benzene;(3aR,3bR,4S,7R,7aS)-4-isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-1H-cyclopenta[1,3]cyclopropa[1,2]benzene;(1aS,2aR,3R,5aS,7R,7aR)-3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene;(1R,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol;(1S,4aR,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene;(R)-2-((R)-4-methylcyclohex-3-en-1-yl)hex-5-en-2-ol;(Z)-1-methyl-4-(6-methylhepta-2,5-dien-2-yl)cyclohex-1-ene;2,6-dimethyl-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]hept-2-ene;(E)-2-benzylideneheptan-1-ol; (E)-2-benzylideneheptyl acetate;(Z)-(2-(diethoxymethyl)hept-1-en-1-yl)benzene;(E)-2-benzylideneheptanal;(1S,4aR,8aS)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene;(3R,5aS,9aR)-2,2,5a,9-tetramethyl-3,4,5,5a,6,7-hexahydro-2H-3,9a-methanobenzo[b]oxepine;1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde;3-methyl-1-phenylpentan-3-ol; 2,6,10-trimethylundecanal; allyl3-cyclohexylpropanoate;(1aR,4aS,7R,7aR,7bS)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulene;(E)-undec-9-enal; methyl(E)-2-(((3,5-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate;2,6,10-trimethylundec-9-enal;(7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methylacetate; nonyl acetate; (2-(1-propoxyethoxy)ethyl)benzene;(Z)-2-(4-methylbenzylidene)heptanal; dec-9-enal;(Z)-oxacycloheptadec-8-en-2-one;(2S,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene;2-((2S,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol;1-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethan-1-one;6-isopropylquinoline;3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;6,10,14-trimethylpentadecan-2-one; (E)-cyclohexadec-5-en-1-one;1-isopropyl-4-methylcyclohex-3-en-1-ol;1-isopropyl-4-methylcyclohex-3-en-1-ol;3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran;(1aR,2S,4aS)-2,4a,8,8-tetramethyloctahydrocyclopropa[d]naphthalen-3(1H)-one;(Z)-dodec-2-enal; (E)-hex-3-en-1-yl 3-methylbutanoate;3,6-dimethyloctan-3-yl acetate; 3-(4-isopropylphenyl)propanal;(Z)-undec-2-enenitrile; (E)-undec-2-enal; phenethyl butyrate;(Z)-non-2-enal; nonan-2-ol; nonan-2-one; 2-isobutylquinoline;(E)-2-hexylidenecyclopentan-1-one; 2-heptyltetrahydrofuran;(E)-dec-2-enal; 2,6-dimethyloctanal; decan-1-ol; (E)-hept-1-en-1-ylacetate; undec-10-en-1-ol; undec-10-enal;2-((2R,4aS)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol;1-isopropyl-4-methyl-7-thiabicyclo[2.2.1]heptane;(3E,5Z)-undeca-1,3,5-triene; 3,7-dimethyloct-6-en-3-ol;1,3,3-trimethylbicyclo[2.2.1]heptan-2-yl acetate;1,1,2,3,3-pentamethyl-2,3-dihydro-1H-indene;(Z)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-dodec-3-enal;(S)-5-heptyldihydrofuran-2(3H)-one; (R)-5-heptyldihydrofuran-2(3H)-one;(E)-6,10-dimethylundeca-5,9-dien-2-yl acetate;(Z)-3-methyl-5-phenylpent-2-enenitrile;(2S,5S,6S)-2,6,10,10-tetramethyl-1-oxaspiro[4.5]decan-6-ol;(2E)-3-methyl-5-phenyl-2-pentenenitrile;(2S,5R)-2-isopropyl-5-methylcyclohexan-1-one;(R,E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en-2-yl)-1,3-dioxolane;(E)-4-(2,2-dimethyl-6-methylenecyclohexyl)-3-methylbut-3-en-2-one;3-(3-isopropylphenyl)butanal;3-(1-ethoxyethoxy)-3,7-dimethylocta-1,6-diene;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate;2-((3S,3aS,5R)-3,8-dimethyl-1,2,3,3a,4,5,6,7-octahydroazulen-5-yl)propan-2-ol;benzyl 2-phenylacetate;3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2,2-dimethylpropanal;2-methyl-5-(6-methylhept-5-en-2-yl)bicyclo[3.1.0]hex-2-ene;1-(1,1,2,3,3,6-hexamethyl-2,3-dihydro-1H-inden-5-yl)ethan-1-one;(E)-tridec-2-enal;(1R,4S,4aS,6R,8aS)-4,8a,9,9-tetramethyloctahydro-1,6-methanonaphthalen-1(2H)-ol;p-tolyl hexanoate; 5-hexyl-4-methyldihydrofuran-2(3H)-one; ethyl(2Z,4E)-deca-2,4-dienoate; 2,4-dimethyl-6-phenyl-3,6-dihydro-2H-pyran;2-cyclohexylidene-2-phenylacetonitrile;(4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methyl acetate;(4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol;(2-isopropoxyethyl)benzene; 2-cyclohexylhepta-1,6-dien-3-one;(2-(cyclohexyloxy)ethyl)benzene; phenethyl 2-methylbutanoate; phenethyl2-phenylacetate; phenyl benzoate; phenethyl benzoate;2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acetaldehyde;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-ylpivalate;(E)-3,3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol;1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde;p-tolyl 2-phenylacetate; Ethyl 2,4,7-decatrienoate;2-benzyl-4,4,6-trimethyl-1,3-dioxane;2,4-dimethyl-4-phenyltetrahydrofuran;(2R,4a′R,8a′R)-3,7′-dimethyl-3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-spiro[oxirane-2,2′-[1,4]methanonaphthalene];(Z)-6-ethylideneoctahydro-2H-5,8-methanochromene;2-((S)-1-((S)-3,3-dimethylcyclohexyl)ethoxy)-2-oxoethyl propionate;methyl 2,2-dimethyl-6-methylenecyclohexane-1-carboxylate;4-methyl-2-phenyl-3,6-dihydro-2H-pyran;2,2,7,9-tetramethylspiro(5.5)undec-8-en-1-one;3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol;(Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;(E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;1-(3-hydroxy-3-methylpent-4-en-1-yl)-2,5,5,8a-tetramethyldecahydronaphthalen-2-ol;(4aR,6aS,10aS,10bR)-3,4a,7,7,10a-pentamethyl-4a,5,6,6a,7,8,9,10,10a,10b-decahydro-1H-benzo[f]chromene;(4aR,8aR)-4a,8-dimethyl-2-(propan-2-ylidene)-1,2,3,4,4a,5,6,8a-octahydronaphthalene;2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropylcyclopropanecarboxylate; 3-(4-isobutylphenyl)-2-methylpropanal;(1aR,4aR,7S,7aR,7bR)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulen-7-ol;1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one; (Z)-dodec-4-enal;(1S,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol;(1S,4S,4aR,8aS)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol;3-methyl-2-pentylcyclopentan-1-one;2,6,10,10-tetramethyl-1-oxaspiro[4.5]dec-6-ene;(1aR,4aS)-2,4a,8,8-tetramethyl-1,1a,4,4a,5,6,7,8-octahydrocyclopropa[d]naphthalene;1-isopropyl-2-methoxy-4-methylbenzene;1-(2,2,6-trimethylcyclohexyl)hexan-3-ol;(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol; (Z)-dec-2-enal;(E)-non-2-enal; (E)-dec-4-enal; (Z)-oxacycloheptadec-8-en-2-one;(Z)-3,7-dimethylocta-1,3,6-triene; (Z)-3,7-dimethylocta-1,3,6-triene;(E)-3,7-dimethylocta-2,6-dien-1-ol;(1R-(1alpha,3alpha,4alpha))-2,3,4,4a,5,6-hexahydro-2,2-dimethyl-1,3-methanonaphthalen-7(1H)-one; tridecan-1-ol; methyl2-((1-hydroxy-3-phenylbutyl)amino)benzoate;1-((2E,5Z,9Z)-2,6,10-trimethylcyclododeca-2,5,9-trien-1-yl)ethan-1-one;decahydro-2,6,6,7,8,8-hexamethyl-2h-indeno(4,5-b)furan; pentamethyloctahydroindenodioxane; undecanal; (E)-4-methyldec-3-en-5-ol;(3R,4aS,5R)-4a,5-dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene;2-((2R,8R,8aS)-8,8a-dimethyl-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl)propan-2-ol;(Z)-2-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enal;1-methoxy-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoindene; methyl(Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate;2,4,6-trimethyl-4-phenyl-1,3-dioxane;1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one;methyl (Z)-2-(((2,4-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate;4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-ol;4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-ylacetate; decahydro-3H-spiro[furan-2,5′-[4,7]methanoindene];(2Z,6E)-nona-2,6-dienenitrile; (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azulen-4-ol;3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbonitrile;(1S,2S,3S,5R)-2,6,6-trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexan]-2′-en-4′-one;1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene];(2′S,4a′S,8a′S)-1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene];(1R,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,7,8,8a-hexahydronaphthalene;(7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methanol;1-ethoxy-4-(tert-pentyl)cyclohexane; (3Z)-1-(2-buten-1-yloxy)-3-hexene;4-(2-methoxypropan-2-yl)-1-methylcyclohex-1-ene;3-methoxy-3,7-dimethylocta-1,6-diene; 3,7-dimethyloctanal; hexyl2-hydroxybenzoate; hexyl (Z)-but-2-enoate;(Z)-3,7-dimethylocta-2,6-dien-1-yl formate;(Z)-1-(2,6,6-trimethylcyclohex-1-en-1-yl)pent-1-en-3-one;(E)-3,7-dimethylocta-4,6-dien-3-ol; methyl(Z)-3,7-dimethylocta-2,6-dienoate;((1s,4s)-4-isopropylcyclohexyl)methanol; 3,7-dimethylocta-1,6-dien-3-ylpropionate; 3,7-dimethylocta-1,6-dien-3-yl formate;3,7-dimethylocta-1,6-dien-3-yl butyrate; 3,7-dimethylocta-1,6-dien-3-ylacetate; 3,7-dimethylocta-1,6-dien-3-ol;2,2-dimethyl-5-phenylhexanenitrile;(Z)-4-(6,6-dimethylcyclohex-2-en-1-yl)-3-methylbut-3-en-2-one;7-methyloctyl acetate; isopentyl octanoate; hexyl propionate; hexylbutyrate; hexyl 2-methylbutanoate; hexyl furan-2-carboxylate; heptylacetate; (Z)-3,7-dimethylocta-2,6-dienenitrile;(E)-3,7-dimethylocta-2,6-dien-1-yl formate;(E)-3,7-dimethylocta-2,6-dien-1-yl octanoate;(E)-3,7-dimethylocta-2,6-dien-1-yl benzoate;(E)-3,7-dimethylocta-2,6-dienal;1-isopropyl-4-methylcyclohexa-1,4-diene; 2-(sec-butyl)cyclohexan-1-one;3-(2-ethylphenyl)-2,2-dimethylpropanal; 2-(tert-butyl)cyclohexyl ethylcarbonate; ethyl octanoate; ethyl 2-cyclohexylpropanoate;4-methyl-2-phenyltetrahydro-2H-pyran; 2,6-dimethyloct-7-en-2-ol;3-methyl-2-pentylcyclopent-2-en-1-one; 2-(4-methylcyclohexyl)propan-2-ylacetate; 4-(2,6,6-trimethylcyclohex-2-en-1-yl)butan-2-one;(oxybis(methylene))dibenzene; dibutyl phthalate; decyl 2-aminobenzoate;methyl (1s,4s)-1,4-dimethylcyclohexane-1-carboxylate; 2-cyclohexylethylacetate; (3Z,5Z)-2,6-dimethylocta-1,3,5,7-tetraene;4-cyclohexyl-2-methylbutan-2-ol; 2-benzyl-2-methylbut-3-enenitrile;3,7-dimethyloct-6-enenitrile; 3,7-dimethyloct-6-en-1-yl 2-phenylacetate;3,7-dimethyloct-6-en-1-yl formate; 3,7-dimethyloct-6-en-1-yl benzoate;3,7-dimethyloct-6-en-1-ol; 3,7-dimethyloct-6-enal;(E)-3,7-dimethylocta-2,6-dienal;(1R,2S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptane; (Z)-hex-3-en-1-ylpentanoate; (E)-hex-3-en-1-yl (E)-2-methylbut-2-enoate;(Z)-hex-3-en-1-yl butyrate; 4-chloro-3,5-dimethylphenol;5-isopropyl-2-methylphenol;(E)-2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-2-enal;3-isopropyl-6-methylenecyclohex-1-ene; benzyl 2-hydroxybenzoate; benzyl3-methylbutanoate; 1-(3,3-dimethylcyclohexyl)ethyl formate;(Z)-1-methoxy-4-(prop-1-en-1-yl)benzene; pentyl benzoate;2-(4-methylcyclohex-3-en-1-yl)propan-2-yl acetate;(Z)-3-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one;(2-(allyloxy)ethyl)benzene; allyl heptanoate; 6,8-dimethylnonan-2-ol;5-methyl-5-phenylhexan-3-one; 3,7-dimethyl-2-methyleneoct-6-enal;3,7-dimethyloctan-1-ol; 2-pentylcyclopentan-1-ol;(2S,4S)-2-heptyl-2,4-dimethyl-1,3-dioxolane;(E)-2-isopropyl-5-methylhex-2-enal;1-isopropyl-4-methyl-7-oxabicyclo[2.2.1]heptane;(Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one;(R)-3,7-dimethylocta-1,6-dien-3-ol; 3,7-dimethyloct-6-enal;(R)-3,7-dimethyloct-6-enal; 3,7-dimethyloct-6-en-1-ol;3,7-dimethyloct-6-en-1-ol;(1R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene;(1S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; hexyl(Z)-2-methylbut-2-enoate; p-cymene; phenethyl isobutyrate; phenethyl(Z)-2-methylbut-2-enoate; phenethyl methacrylate;(2Z,5Z)-5,6,7-trimethylocta-2,5-dien-4-one; 1-methoxy-4-propylbenzene;2-(4-(tert-butyl)phenyl)acetaldehyde; 4-(tert-pentyl)cyclohexan-1-ol;2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; ethyl(2,3,6-trimethylcyclohexyl) carbonate; 1-(3,3-dimethylcyclohexyl)ethylacetate; (S)-3,7-dimethylocta-1,6-dien-3-ol;1-isopropyl-4-methylenebicyclo[3.1.0]hexane; 3,7-dimethyloctanal;4-(2,2,6-trimethylcyclohexyl)butan-2-ol; 3,7-dimethyloctan-3-ol;3,7-dimethyloctan-3-yl acetate; ethyl(1R,6S)-2,2,6-trimethylcyclohexane-1-carboxylate;2-isopropyl-5-methylphenol;(Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one;(Z)-1-methoxy-4-(prop-1-en-1-yl)benzene; 2,2,2-trichloro-1-phenylethylacetate; 2,2,5-trimethyl-5-pentylcyclopentan-1-one;(4-tert-butylcyclohexyl)acetate; 4-(tert-butyl)cyclohexyl acetate;4-methyl-4-phenylpentan-2-yl acetate;(Z)-1-((2-methylallyl)oxy)hex-3-ene;4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane;1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-one,more preferably said one or more malodor reduction materials areselected from the group consisting of 2-ethylhexyl(Z)-3-(4-methoxyphenyl)acrylate;2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-1,3-dioxolane;1,1-dimethoxynon-2-yne;3-methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decane;methoxycyclododecane; 1,1-dimethoxycyclododecane;(Z)-tridec-2-enenitrile; (2-hydroxy-4-methoxyphenyl)(phenyl)methanone;2,4a,5,8a-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ylformate; 1,8-dioxacycloheptadecan-9-one;4-(tert-pentyl)cyclohexan-1-one; 2-methoxy-1,1′-biphenyl;3a,5,6,7,8,8b-hexahydro-2,2,6,6,7,8,8-heptamethyl-4H-indeno(4,5-d)-1,3-dioxole;7-isopropyl-8,8-dimethyl-6,10-dioxaspiro[4.5]decane; octylfuran-2-carboxylate; octyl acetate; 2-heptyl-4-methyl-1,3-dioxolane;octanal; 1,1-dimethoxyoctane; 7-methyl-3-methyleneocta-1,6-diene;2-methyl-6-methyleneoct-7-en-2-yl acetate; tetradecanal;tetradecanenitrile;2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-octahydronaphthalen-1-ol;2-((1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethyl acetate;(4R,4aS,6R)-4,4a-dimethyl-6-(prop-1-en-2-yl)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one;nonan-1-ol; nonanal; 12-methyl-14-tetradec-9-enolide;N-ethyl-2-isopropyl-5-methylcyclohexane-1-carboxamide;2-methoxynaphthalene; (E)-3,7,11-trimethyldodeca-1,6,10-trien-3-ol;(Z)-3,7-dimethylocta-2,6-dien-1-ol; methyl (E)-non-2-enoate;10-isopropyl-2,7-dimethyl-1-oxaspiro[4.5]deca-3,6-diene;2-(2-(4-methylcyclohex-3-en-1-yl)propyl)cyclopentan-1-one;(E)-4-(2,2,3,6-tetramethylcyclohexyl)but-3-en-2-one;(4-(4-methylpent-3-en-1-yl)cyclohex-3-en-1-yl)methyl acetate;2-(tert-butyl)-4,5,6-trimethyl-1,3-phenylene dinitrite;1,7-dioxacycloheptadecan-8-one;1-(4-(tert-butyl)-2,6-dimethyl-3,5-dinitrophenyl)ethan-1-one;1-(tert-butyl)-2-methoxy-4-methyl-3,5-dinitrobenzene;3-methylcyclopentadecan-1-one; (E)-3-methylcyclopentadec-4-en-1-one;1-(4-isopropylcyclohexyl)ethan-1-ol; (E)-dec-5-enoic acid; methylnon-2-ynoate; 2-methyldecanal; 6,6-dimethoxy-2,5,5-trimethylhex-2-ene;methyl stearate; 1,1-dimethoxy-2-methylundecane; undecan-2-one;2-methylundecanal; methyl tetradecanoate; methyl(9Z,12Z)-octadeca-9,12-dienoate; methyl palmitate;1-methyl-2-phenoxybenzene; 1-allyl-4-methoxybenzene;1-(naphthalen-2-yl)ethan-1-one; methyl oct-2-ynoate; methyl2,6,6-trimethylcyclohex-2-ene-1-carboxylate;7-isopropyl-10-methyl-1,5-dioxaspiro[5.5]undecan-3-ol;3-(3-(tert-butyl)phenyl)-2-methylpropanal;(E)-4-(4,8-dimethylnona-3,7-dien-1-yl)pyridine;(E)-trideca-3,12-dienenitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol;8-isopropyl-6-methylbicyclo[2.2.2]oct-5-ene-2-carbaldehyde;(S)-1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene;3,7-dimethylocta-1,6-dien-3-yl octanoate;3,7-dimethylocta-1,6-dien-3-ylisobutyrate;3,7-dimethylocta-1,6-dien-3-yl benzoate; 3,7-dimethylocta-1,6-dien-3-yl2-aminobenzoate; (2Z,6E)-3,7-dimethylnona-2,6-dienenitrile;3-(4-methylcyclohex-3-en-1-yl)butanal;(2,5-dimethyl-1,3-dihydroinden-2-yl)methanol;3-(4-(tert-butyl)phenyl)-2-methylpropanal; dodecan-1-ol; dodecylacetate; dodecanoic acid; 5-hexyl-5-methyldihydrofuran-2(3H)-one;dodecanal; 4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexan-1-one;((3S,3aR,6R,8aS)-7,7-dimethyl-8-methyleneoctahydro-1H-3a,6-methanoazulen-3-yl)methanol;5-(sec-butyl)-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane;(1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)cyclopropyl)methanol;2-propylheptanenitrile; 2-hexylcyclopentan-1-one;2,6,9,10-tetramethyl-1-oxaspiro(4.5)deca-3,6-diene; isopropyl palmitate;isopropyl tetradecanoate; isopropyl dodecanoate;(E)-cyclohexadec-8-en-1-one;(2S,5S)-2-isopropyl-5-methylcyclohexan-1-one;2-hexylcyclopent-2-en-1-one;(2S,5S)-2-isopropyl-5-methylcyclohexan-1-one;4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde;(Z)-1-(benzyloxy)-2-methoxy-4-(prop-1-en-1-yl)benzene;1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one;6-(sec-butyl)quinoline;2-(cyclohexyloxy)-1,7,7-trimethylbicyclo[2.2.1]heptane;(1R,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl propionate;(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate;4-((2R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexan-1-ol;(1R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate;2-(4-isopropylcyclohexa-1,4-dien-1-yl)ethyl formate; isopentyl(E)-undec-6-enoate; isopentyl dodecanoate;(E)-oxacycloheptadec-10-en-2-one; (E)-non-2-enenitrile;(E)-8-(1H-indol-1-yl)-2,6-dimethyloct-7-en-2-ol;8,8-di(1H-indol-1-yl)-2,6-dimethyloctan-2-ol; 2-cyclododecylpropan-1-ol;3-methyl-5-phenylpentanenitrile;2,3-dihydro-3,3-dimethyl-1H-indene-5-propanal;3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal; hexyl octanoate;hexyl hexanoate; (Z)-2-benzylideneoctanal; hexyl benzoate;(Z)-hex-1-en-1-yl (Z)-2-methylbut-2-enoate;(E)-3,7-dimethylocta-2,6-dien-1-yl palmitate; oxacycloheptadecan-2-one;ethyl (1R,2R,3R,4R)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate;2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl propionate;(E)-oxacyclohexadec-13-en-2-one;6-butyl-2,4-dimethyl-3,6-dihydro-2H-pyran;2-((3S,5R,8S)-3,8-dimethyl-1,2,3,4,5,6,7,8-octahydroazulen-5-yl)propan-2-ol;1-(2,6,6-trimethylcyclohex-2-en-1-yl)pentan-3-one; ethyl2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate;(1Z,5Z)-1,5-dimethyl-8-(propan-2-ylidene)cyclodeca-1,5-diene;(1E,6E)-8-isopropyl-1-methyl-5-methylenecyclodeca-1,6-diene;(E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate;(E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate;(6E,10E)-3,7,11,15-tetramethylhexadeca-1,6,10,14-tetraen-3-ol;(E)-2-(3,7-dimethylocta-2,6-dien-1-yl)cyclopentan-1-one;5-heptyldihydrofuran-2(3H)-one; 1-methyl-4-(propan-2-ylidene)cyclohexylacetate; 1-methyl-4-(propan-2-ylidene)cyclohexan-1-ol;(1R,4aR,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene;(Z)-4-(2,2-dimethyl-6-methylenecyclohexyl)but-3-en-2-one;(4aS,9aR)-3,5,5,9-tetramethyl-2,4a,5,6,7,9a-hexahydro-1H-benzo[7]annulene;(1R,3aR,4R,7R)-1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene;2-((2R,4aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol;5-octyldihydrofuran-2(3H)-one;(Z)-1-(2,2-dimethyl-6-methylenecyclohexyl)but-2-en-1-one;(1R,4aS,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene;1-(3,3-dimethylcyclohexyl)pent-4-en-1-one;4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene;furan-2-ylmethyl octanoate; furan-2-ylmethyl hexanoate; furan-2-ylmethylheptanoate; 2-methyldecanenitrile;8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-ylpropionate; ethyl(3aR,4S,7R,7aR)-octahydro-3aH-4,7-methanoindene-3a-carboxylate;(6-isopropyl-9-methyl-1,4-dioxaspiro[4.5]decan-2-yl)methanol;undec-10-enenitrile; 3-(2-ethylphenyl)-2,2-dimethylpropanal;(E)-4,8-dimethyldeca-4,9-dienal;(E)-4-((3aR,4R,7R,7aR)-1,3a,4,6,7,7a-hexahydro-5H-4,7-methanoinden-5-ylidene)-3-methylbutan-2-ol;8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate;3-(4-ethylphenyl)-2,2-dimethylpropanenitrile; 2-heptylcyclopentan-1-one;1-ethoxyethoxy Cyclododecane; 3-cyclohexene-1-carboxylic acid,2,6,6-trimethyl-, methyl ester;(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-yl acetate;(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol;oxacyclohexadecan-2-one; (E)-cyclopentadec-4-en-1-one;1-cyclopentadec-4-en-1-one; 1,4-dioxacycloheptadecane-5,17-dione; ethylundec-10-enoate; ethyl palmitate; ethyl nonanoate; ethyl tetradecanoate;(E)-3,7-dimethylnona-1,6-dien-3-ol; ethyl dodecanoate; ethyl decanoate;ethyl 6,6-dimethyl-2-methylenecyclohex-3-ene-1-carboxylate;6-ethyl-2,10,10-trimethyl-1-oxaspiro[4.5]deca-3,6-diene;2-((1R,3S,4S)-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohexyl)propan-2-ol;(E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol;(E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal;1,1-dimethoxydodecane; (R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene;7,9-dimethylspiro[5.5]undecan-3-one; oxydibenzene; diphenylmethane;2-methyl-1-phenylpropan-2-yl butyrate;octahydro-1H-4,7-methanoinden-5-yl acetate;2-methyl-5-(prop-1-en-2-yl)cyclohexyl acetate;3,7-dimethyloct-6-en-3-ol; dibutylsulfane; 1,2-diphenylethane;6-hexyltetrahydro-2H-pyran-2-one;(3R,4R)-1-isopropyl-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohex-1-ene;(3S,3aS,5R)-3,8-dimethyl-5-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene;6-heptyltetrahydro-2H-pyran-2-one;(1S,8aR)-4,7-dimethyl-1-(propan-2-yl)-1,2,3,5,6,8a-hexahydronaphthalene;(Z)-1-((1R,2S)-2,6,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;(1S,8aS)-1-isopropyl-4,7-dimethyl-1,2,3,5,6,8a-hexahydronaphthalene;3,7,7-trimethylbicyclo[4.1.0]hept-3-ene; dec-9-en-1-ol; decylpropionate; 1,1-diethoxydecane; 1-cyclohexylethyl (E)-but-2-enoate;3-(4-isopropylphenyl)-2-methylpropanal; cyclotetradecane;cyclopentadecanone; cyclohexyl 2-hydroxybenzoate;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl butyrate;8,8-dimethyl-1,2,3,4,5,6,7,8-octahydronaphthalene-2-carbaldehyde;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-5-yl isobutyrate;(5R,6R)-3,6-dimethyl-5-(prop-1-en-2-yl)-6-vinyl-4,5,6,7-tetrahydrobenzofuran;2-(3-phenylpropyl)pyridine; dodecanenitrile;(E)-cycloheptadec-9-en-1-one;3-(4-methylcyclohex-3-en-1-yl)but-3-en-1-yl acetate;3-(4-methylcyclohex-3-en-1-yl)butan-1-ol;(E)-3-methyl-5-phenylpent-2-enenitrile;(E)-2-(2,6-dimethylhepta-1,5-dien-1-yl)-4-methyl-1,3-dioxolane;(E)-1,1-dimethoxy-3,7-dimethylocta-2,6-diene;(E)-1,1-diethoxy-3,7-dimethylocta-2,6-diene;(E)-3,7-dimethylocta-1,3,6-triene; (E)-oxacycloheptadec-11-en-2-one;(Z)-dec-4-enal; (E)-hex-3-en-1-yl (E)-hex-3-enoate; (Z)-hex-3-en-1-yl2-hydroxybenzoate; (Z)-hex-3-en-1-yl benzoate; (Z)-hex-3-en-1-yl2-methylbutanoate; cinnamyl propionate; cinnamyl isobutyrate; cinnamylcinnamate; hexadecan-1-ol;(E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)hepta-1,6-dien-3-one;2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)butanal;(3aR,5aR,9aR,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan;1,6-dioxacycloheptadecan-7-one;1-(6-(tert-butyl)-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl)ethan-1-one;(3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene;(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-3-ylformate;(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-ylacetate; (4Z,8Z)-1,5,9-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene;(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-ol;5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane;5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane;1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro-4H-inden-4-one;(Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-3-en-5-yl acetate;(1S,2S,5R,8S)-4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-ol;2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-yl acetate; octanenitrile;decanoic acid; decanal; 2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane;ethyl 2-methyl-4-oxo-6-pentylcyclohex-2-ene-1-carboxylate;2,6-di-tert-butyl-4-methylphenol; butyl stearate; butyl undec-10-enoate;2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)butan-1-ol;3-(4-(tert-butyl)phenyl)propanal;(1S,2S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate;1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate;2-ethoxy-2,6,6-trimethyl-9-methylenebicyclo[3.3.1]nonane;(ethoxymethoxy)cyclododecane;(E)-1-methyl-4-(6-methylhept-5-en-2-ylidene)cyclohex-1-ene;3,3,6,7-tetramethyloctahydro-2H-chromene;(5R,10R)-6,10-dimethyl-2-(propan-2-ylidene)spiro[4.5]dec-6-en-8-one;1-methyl-4-(prop-1-en-2-yl)cyclohexyl acetate;(2Z,6E)-2,6-dimethyl-10-methylenedodeca-2,6,11-trienal;(R)-3-methylene-6-((S)-6-methylhept-5-en-2-yl)cyclohex-1-ene;(4aR,7R,8aS)-4a-methyl-1-methylene-7-(prop-1-en-2-yl)decahydronaphthalene;(Z)-2-methyl-5-((1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]heptan-2-yl)pent-2-en-1-ol;6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane; 2-ethoxynaphthalene;(1S,4R,7R)-1,4,9,9-tetramethyl-1,2,3,4,5,6,7,8-octahydro-4,7-methanoazulene;(1aS,5aR,9aR)-1a,5,5,7-tetramethyl-1a,2,3,4,5,5a,8,9-octahydrobenzo[1,7]cyclohepta[1,2-b]oxirene;(R)-3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzo[7]annulene;(1S,4S)-1,4-dimethyl-7-(propan-2-ylidene)-1,2,3,4,5,6,7,8-octahydroazulene;(E)-7,11-dimethyl-3-methylenedodeca-1,6,10-triene;(1R,2S,6S,7S,8S)-8-isopropyl-1-methyl-3-methylenetricyclo[4.4.0.02,7]decane;(3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro-1H-3a,7-methanoazulene;(1R,9S,Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene;(S)-4-methyl-1-((S)-6-methylhept-5-en-2-yl)cyclohex-3-en-1-ol; benzyldodecanoate; benzyl cinnamate; benzyl benzoate;2′-isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4′-[1,3]dioxane];4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbonitrile; methyl(E)-2-((7-hydroxy-3,7-dimethyloctylidene)amino)benzoate; 4-methoxybenzyl2-phenylacetate; pentyl (Z)-3-phenylacrylate;(3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan;(4aR,5R,7aS,9R)-2,2,5,8,8,9a-hexamethyloctahydro-4H-4a,9-methanoazuleno[5,6-d][1,3]dioxole;2,5,5-trimethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-ol;2,5,5-trimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-ol;1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol;(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-tetramethyldodecahydro-5H-3,5a-epoxynaphtho[2,1-c]oxepine;2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-b]furan;2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan;2-(sec-butyl)-1-vinylcyclohexyl acetate;(4R,4aS)-4,4a-dimethyl-6-(propan-2-ylidene)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one;2-(4-methylcyclohex-3-en-1-yl)propan-2-yl propionate;(2Z,6E,9E)-2,6,10-trimethyldodeca-2,6,9,11-tetraenal;(2R,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene;1,7-dimethyl-7-(4-methylpent-3-en-1-yl)tricyclo[2.2.1.02,6]heptane;(E)-5-(2,3-dimethyltricyclo[2.2.1.02,6]heptan-3-yl)-2-methylpent-2-en-1-ol;(1R,3aS,7S,8aR)-1,4,9,9-tetramethyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methanoazulene;1-(5,5-dimethylcyclohex-1-en-1-yl)pent-4-en-1-one;(1S,4aS,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene;(R,Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)pent-1-en-3-one;1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene;(Z)-4-(2,5,6,6-tetramethylcyclohex-2-en-1-yl)but-3-en-2-one;(1Z,4E,8Z)-2,6,6,9-tetramethylcycloundeca-1,4,8-triene;(4aR,8S,9aS)-3,5,5,8-tetramethyl-9-methylene-2,4a,5,6,7,8,9,9a-octahydro-1H-benzo[7]annulene;(1aR,4R,4aR,7bS)-1,1,4,7-tetramethyl-1a,2,3,4,4a,5,6,7b-octahydro-1H-cyclopropa[e]azulene;1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,4,5,6,7,8-octahydroazulene;(3E,6E)-3,7,11-trimethyldodeca-1,3,6,10-tetraene;7,7-dimethyl-2-methylenebicyclo[2.2.1]heptane;2-((2R,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol;(R)-1-methyl-4-(6-methylhept-5-en-2-yl)benzene;(3aR,3bR,4S,7R,7aS)-4-isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-1H-cyclopenta[1,3]cyclopropa[1,2]benzene;(1aS,2aR,3R,5aS,7R,7aR)-3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene;(1R,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol;(1S,4aR,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene;(R)-2-((R)-4-methylcyclohex-3-en-1-yl)hex-5-en-2-ol;(Z)-1-methyl-4-(6-methylhepta-2,5-dien-2-yl)cyclohex-1-ene;2,6-dimethyl-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]hept-2-ene;(E)-2-benzylideneheptan-1-ol; (E)-2-benzylideneheptyl acetate;(Z)-(2-(diethoxymethyl)hept-1-en-1-yl)benzene;(E)-2-benzylideneheptanal;(1S,4aR,8aS)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene;(3R,5aS,9aR)-2,2,5a,9-tetramethyl-3,4,5,5a,6,7-hexahydro-2H-3,9a-methanobenzo[b]oxepine;1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde;3-methyl-1-phenylpentan-3-ol; 2,6,10-trimethylundecanal; allyl3-cyclohexylpropanoate;(1aR,4aS,7R,7aR,7bS)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulene;(E)-undec-9-enal; methyl(E)-2-(((3,5-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate;2,6,10-trimethylundec-9-enal;(7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methylacetate; nonyl acetate; (2-(1-propoxyethoxy)ethyl)benzene;(Z)-2-(4-methylbenzylidene)heptanal; dec-9-enal;(Z)-oxacycloheptadec-8-en-2-one;(2S,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene;2-((2S,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol;1-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethan-1-one;6-isopropylquinoline;3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;6,10,14-trimethylpentadecan-2-one; (E)-cyclohexadec-5-en-1-one;1-isopropyl-4-methylcyclohex-3-en-1-ol;1-isopropyl-4-methylcyclohex-3-en-1-ol;3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran;(1aR,2S,4aS)-2,4a,8,8-tetramethyloctahydrocyclopropa[d]naphthalen-3(1H)-one;(Z)-dodec-2-enal; (E)-hex-3-en-1-yl 3-methylbutanoate;3,6-dimethyloctan-3-yl acetate; 3-(4-isopropylphenyl)propanal;(Z)-undec-2-enenitrile; (E)-undec-2-enal; phenethyl butyrate;(Z)-non-2-enal; nonan-2-ol; nonan-2-one; 2-isobutylquinoline;(E)-2-hexylidenecyclopentan-1-one; 2-heptyltetrahydrofuran;(E)-dec-2-enal; 2,6-dimethyloctanal; decan-1-ol; (E)-hept-1-en-1-ylacetate; undec-10-en-1-ol; undec-10-enal;2-((2R,4aS)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol;1-isopropyl-4-methyl-7-thiabicyclo[2.2.1]heptane;(3E,5Z)-undeca-1,3,5-triene; 3,7-dimethyloct-6-en-3-ol;1,3,3-trimethylbicyclo[2.2.1]heptan-2-yl acetate;1,1,2,3,3-pentamethyl-2,3-dihydro-1H-indene;(Z)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-dodec-3-enal;(S)-5-heptyldihydrofuran-2(3H)-one; (R)-5-heptyldihydrofuran-2(3H)-one;(E)-6,10-dimethylundeca-5,9-dien-2-yl acetate;(Z)-3-methyl-5-phenylpent-2-enenitrile;(2S,5S,6S)-2,6,10,10-tetramethyl-1-oxaspiro[4.5]decan-6-ol;(2E)-3-methyl-5-phenyl-2-pentenenitrile;(2S,5R)-2-isopropyl-5-methylcyclohexan-1-one;(R,E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en-2-yl)-1,3-dioxolane;(E)-4-(2,2-dimethyl-6-methylenecyclohexyl)-3-methylbut-3-en-2-one;3-(3-isopropylphenyl)butanal;3-(1-ethoxyethoxy)-3,7-dimethylocta-1,6-diene;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate;2-((3S,3aS,5R)-3,8-dimethyl-1,2,3,3a,4,5,6,7-octahydroazulen-5-yl)propan-2-ol;benzyl 2-phenylacetate;3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2,2-dimethylpropanal;2-methyl-5-(6-methylhept-5-en-2-yl)bicyclo[3.1.0]hex-2-ene;1-(1,1,2,3,3,6-hexamethyl-2,3-dihydro-1H-inden-5-yl)ethan-1-one;(E)-tridec-2-enal;(1R,4S,4aS,6R,8aS)-4,8a,9,9-tetramethyloctahydro-1,6-methanonaphthalen-1(2H)-ol;p-tolyl hexanoate; 5-hexyl-4-methyldihydrofuran-2(3H)-one; ethyl(2Z,4E)-deca-2,4-dienoate; 2,4-dimethyl-6-phenyl-3,6-dihydro-2H-pyran;2-cyclohexylidene-2-phenylacetonitrile;(4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methyl acetate;(4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol;(2-isopropoxyethyl)benzene; 2-cyclohexylhepta-1,6-dien-3-one;(2-(cyclohexyloxy)ethyl)benzene; phenethyl 2-methylbutanoate; phenethyl2-phenylacetate; phenyl benzoate; phenethyl benzoate;2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acetaldehyde;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl pivalate;(E)-3,3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol;1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde;p-tolyl 2-phenylacetate; Ethyl 2,4,7-decatrienoate;2-benzyl-4,4,6-trimethyl-1,3-dioxane;2,4-dimethyl-4-phenyltetrahydrofuran;(2R,4a′R,8a′R)-3,7′-dimethyl-3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-spiro[oxirane-2,2′-[1,4]methanonaphthalene];(Z)-6-ethylideneoctahydro-2H-5,8-methanochromene;2-((S)-1-((S)-3,3-dimethylcyclohexyl)ethoxy)-2-oxoethyl propionate;methyl 2,2-dimethyl-6-methylenecyclohexane-1-carboxylate;4-methyl-2-phenyl-3,6-dihydro-2H-pyran;2,2,7,9-tetramethylspiro(5.5)undec-8-en-1-one;3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol;(Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;(E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;1-(3-hydroxy-3-methylpent-4-en-1-yl)-2,5,5,8a-tetramethyldecahydronaphthalen-2-ol;(4aR,6aS,10aS,10bR)-3,4a,7,7,10a-pentamethyl-4a,5,6,6a,7,8,9,10,10a,10b-decahydro-1H-benzo[f]chromene;(4aR,8aR)-4a,8-dimethyl-2-(propan-2-ylidene)-1,2,3,4,4a,5,6,8a-octahydronaphthalene;2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropylcyclopropanecarboxylate; 3-(4-isobutylphenyl)-2-methylpropanal;(1aR,4aR,7S,7aR,7bR)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulen-7-ol;1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one; (Z)-dodec-4-enal;(1S,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol;(1S,4S,4aR,8aS)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol;3-methyl-2-pentylcyclopentan-1-one;2,6,10,10-tetramethyl-1-oxaspiro[4.5]dec-6-ene;(1aR,4aS)-2,4a,8,8-tetramethyl-1,1a,4,4a,5,6,7,8-octahydrocyclopropa[d]naphthalene;1-isopropyl-2-methoxy-4-methylbenzene;1-(2,2,6-trimethylcyclohexyl)hexan-3-ol;(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol; (Z)-dec-2-enal;(E)-non-2-enal; (E)-dec-4-enal; (Z)-oxacycloheptadec-8-en-2-one;(Z)-3,7-dimethylocta-1,3,6-triene; (Z)-3,7-dimethylocta-1,3,6-triene;(E)-3,7-dimethylocta-2,6-dien-1-ol;(1R-(1alpha,3alpha,4alpha))-2,3,4,4a,5,6-hexahydro-2,2-dimethyl-1,3-methanonaphthalen-7(1H)-one; tridecan-1-ol; methyl2-((1-hydroxy-3-phenylbutyl)amino)benzoate;1-((2E,5Z,9Z)-2,6,10-trimethylcyclododeca-2,5,9-trien-1-yl)ethan-1-one;decahydro-2,6,6,7,8,8-hexamethyl-2h-indeno(4,5-b)furan; pentamethyloctahydroindenodioxane; undecanal; (E)-4-methyldec-3-en-5-ol;(3R,4aS,5R)-4a,5-dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene;2-((2R,8R,8aS)-8,8a-dimethyl-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl)propan-2-ol;(Z)-2-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enal;1-methoxy-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoindene; methyl(Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate;2,4,6-trimethyl-4-phenyl-1,3-dioxane;1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one;methyl (Z)-2-(((2,4-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate;4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-ol;4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-ylacetate; decahydro-3H-spiro[furan-2,5′-[4,7]methanoindene];(2Z,6E)-nona-2,6-dienenitrile;(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azulen-4-ol;3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbonitrile;(1S,2S,3S,5R)-2,6,6-trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexan]-2′-en-4′-one;1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene];(2'S,4a'S,8a'S)-1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene];(1R,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,7,8,8a-hexahydronaphthalene;(7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methanol;4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane;1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-one,more preferably said one or more malodor reduction materials areselected from the group consisting of3-methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decane;2,4a,5,8a-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ylformate; 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-octahydronaphthalen-1-ol;(4R,4aS,6R)-4,4a-dimethyl-6-(prop-1-en-2-yl)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one;((3S,3aR,6R,8aS)-7,7-dimethyl-8-methyleneoctahydro-1H-3a,6-methanoazulen-3-yl)methanol;(E)-cyclohexadec-8-en-1-one;(Z)-1-(benzyloxy)-2-methoxy-4-(prop-1-en-1-yl)benzene;1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one;(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ylisobutyrate;2,3-dihydro-3,3-dimethyl-1H-indene-5-propanal;3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal;2-((2R,4aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol;4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene;8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate;octahydro-1H-4,7-methanoinden-5-yl acetate;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl butyrate;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-5-yl isobutyrate;(5R,6R)-3,6-dimethyl-5-(prop-1-en-2-yl)-6-vinyl-4,5,6,7-tetrahydrobenzofuran;(E)-cycloheptadec-9-en-1-one;(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-3-ylformate;(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-ylacetate;(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-ol;5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane;(Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-3-en-5-yl acetate;(1S,2S,5R,8S)-4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-ol;(1S,2S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate;(Z)-2-methyl-5-((1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]heptan-2-yl)pent-2-en-1-ol;(1S,4R,7R)-1,4,9,9-tetramethyl-1,2,3,4,5,6,7,8-octahydro-4,7-methanoazulene;(1aS,5aR,9aR)-1a,5,5,7-tetramethyl-1a,2,3,4,5,5a,8,9-octahydrobenzo[1,7]cyclohepta[1,2-b]oxirene;(3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro-1H-3a,7-methanoazulene;4-methoxybenzyl 2-phenylacetate;2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan;(4R,4aS)-4,4a-dimethyl-6-(propan-2-ylidene)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one;(E)-5-(2,3-dimethyltricyclo[2.2.1.02,6]heptan-3-yl)-2-methylpent-2-en-1-ol;(1R,3aS,7S,8aR)-1,4,9,9-tetramethyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methanoazulene;(1aR,4R,4aR,7bS)-1,1,4,7-tetramethyl-1a,2,3,4,4a,5,6,7b-octahydro-1H-cyclopropa[e]azulene;2-((2R,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol;(3aR,3bR,4S,7R,7aS)-4-isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-1H-cyclopenta[1,3]cyclopropa[1,2]benzene;(3R,5aS,9aR)-2,2,5a,9-tetramethyl-3,4,5,5a,6,7-hexahydro-2H-3,9a-methanobenzo[b]oxepine;(1aR,4aS,7R,7aR,7bS)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulene;2-((2S,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol;1-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethan-1-one;(E)-cyclohexadec-5-en-1-one;(1aR,2S,4aS)-2,4a,8,8-tetramethyloctahydrocyclopropa[d]naphthalen-3(1H)-one;2-((2R,4aS)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate;1-(1,1,2,3,3,6-hexamethyl-2,3-dihydro-1H-inden-5-yl)ethan-1-one;(1R,4S,4aS,6R,8aS)-4,8a,9,9-tetramethyloctahydro-1,6-methanonaphthalen-1(2H)-ol;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl pivalate;(2R,4a′R,8a′R)-3,7′-dimethyl-3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-spiro[oxirane-2,2′-[1,4]methanonaphthalene];2,2,7,9-tetramethylspiro(5.5)undec-8-en-1-one;(Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;(4aR,6aS,10aS,10bR)-3,4a,7,7,10a-pentamethyl-4a,5,6,6a,7,8,9,10,10a,10b-decahydro-1H-benzo[f]chromene;(1aR,4aR,7S,7aR,7bR)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulen-7-ol;1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one;(1aR,4aS)-2,4a,8,8-tetramethyl-1,1a,4,4a,5,6,7,8-octahydrocyclopropa[d]naphthalene;(1R-(1alpha,3alpha,4aalpha))-2,3,4,4a,5,6-hexahydro-2,2-dimethyl-1,3-methanonaphthalen-7(1H)-one;2-((2R,8R,8aS)-8,8a-dimethyl-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl)propan-2-ol;1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one;methyl (Z)-2-(((2,4-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate;4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-ylacetate; decahydro-3H-spiro[furan-2,5′-[4,7]methanoindene];(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azulen-4-ol;3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbonitrile;(1S,2S,3S,5R)-2,6,6-trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexan]-2′-en-4′-one;1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene];(2'S,4a'S,8a'S)-1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene];tetrahydronaphthalen-2-yl)-1,3-dioxolane;2-(cyclohexyloxy)-1,7,7-trimethylbicyclo[2.2.1]heptane;4-((2R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexan-1-ol;8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-ylpropionate;(1aS,2aR,3R,5aS,7R,7aR)-3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene;4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane;1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-one,and most preferably said one or more malodor reduction materials areselected from the group consisting of3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal;8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate;2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan;(E)-cyclohexadec-5-en-1-one;4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane;1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-oneand mixtures thereof.
 5. An article according to any preceding claim,wherein said malodor reduction materials are not selected from the groupconsisting of geranyl nitrile; helional; nonanal; linalool;(S)-(+)-linalool; (R)-(−)-linalool; nerol; tetrahydrolinalool;2-phenylethyl acetate; eugenol; ethyl linalool; allyl heptoate; agrumennitrile; citronitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol;2-methyl-5-phenylpentan-1-ol; dodecanenitrile;2-heptylcyclopentan-1-one; methyl nonyl acetaldehyde;3-(2-ethylphenyl)-2,2-dimethylpropanal;(Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one;(R,E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;4-(tert-butyl)cyclohexyl acetate; 1-cyclohexylethyl (E)-but-2-enoate;allyl 2-(cyclohexyloxy)acetate; alpha terpinyl acetate; beta terpinylacetate; gamma terpinyl acetate; methyl dodecyl ether;2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; cinnamylisobutyrate;(E)-2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-2-enal; gammamethyl ionone; ethyl 2,3,6-trimethyl cyclohexyl carbonate ethyl2,3,6-trimethyl cyclohexyl carbonate; Citral diethyl acetal;Dimethoxycyclododecane;1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one;oxacyclohexadecan-2-one;4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene;Ethylene brassylate; Methyl(Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate;4,7-Methano-1H-inden-5-ol, 3a,4,5,6,7,7a-hexahydro-, 5-acetate; cedrylmethyl ether; vetivert acetate;1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one;Benzophenone; Farnesol; trans,trans-farnesol;3-(3-isopropylphenyl)butanal; 2,6,10-trimethylundec-9-enal;3-(4-(tert-butyl)phenyl)propanal;3-(4-isopropylphenyl)-2-methylpropanal; Citronellal (1); Citronellal(d); (E)-4,8-dimethyldeca-4,9-dienal; Pino Acetaldehyde;3-(4-(tert-butyl)phenyl)-2-methylpropanal; Cinnamic aldehyde; Citral;Geranial; MethoxyMelonal; o-methoxycinnamaldehyde;(E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal; MethylOctyl Acetaldehyde; 3-(4-methoxyphenyl)-2-methylpropanal;5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde; Iso Cyclocitral;Octanal; 2-Undecenal; 10-Undecenal; Trans-trans-2,6-Nonadienal;Trans-2,cis-6-nondienal; Heliotropin; Hexyl Cinnamic aldehyde;p-methyl-alpha-pentylcinnamaldehyde; Alpha-methyl cinnamaldehyde;3,4-dimethoxybenzaldehyde; Myrtenal; Perillaldehyde; Maceal; Methylpalmitate; Methyl iso eugenol and mixtures thereof.
 6. An articleaccording to any preceding claim, having a weight ratio of fabricsoftener active to dry substrate ranging from about 10:1 to about 0.5:1,preferably from about 5:1 to about 1:1, preferably said a fabricsoftener active is selected from the group consisting of a quaternaryammonium compound, a silicone polymer, a polysaccharide, a clay, anamine, a fatty ester, a dispersible polyolefin, a polymer latex andmixtures thereof.
 7. An article according to any preceding claimcomprising a quaternary ammonium compound selected from the groupconsisting of bis-(2-hydroxypropyl)-dimethylammonium methylsulphatefatty acid ester, 1,2-di(acyloxy)-3-trimethylammoniopropane chloride, N,N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride,N,N-bis(tallowoyl-oxy-ethyl) N,N-dimethyl ammonium chloride,N,N-bis(stearoyl-oxy-ethyl)N-(2 hydroxyethyl)N-methyl ammoniummethylsulfate, 1,2 di(stearoyl-oxy) 3 trimethyl ammoniumpropanechloride, dicanoladimethylammonium chloride,di(hard)tallowdimethylammonium chloride dicanoladimethylammoniummethylsulfate, 1-methyl-1-stearoylamidoethyl-2-stearoylimidazoliniummethylsulfate, 1-tallowylamidoethyl-2-tallowylimidazoline, DipalmethylHydroxyethylammoinum Methosulfate and mixtures thereof.
 8. An articleaccording to any preceding claim comprising a fabric softening activehaving an Iodine Value of between 0-140, preferably 5-100, morepreferably 10-80, even more preferably, 15-70, most preferably 18-25. 9.A article according to any preceding claim, said article comprising anadjunct ingredient selected from the group consisting of surfactants,builders, chelating agents, dye transfer inhibiting agents, dispersants,enzymes, and enzyme stabilizers, catalytic materials, bleach activators,hydrogen peroxide, sources of hydrogen peroxide, preformed peracids,polymeric dispersing agents, clay soil removal/anti-redeposition agents,brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfumedelivery systems, structure elasticizing agents, carriers, structurants,hydrotropes, processing aids, solvents, pigments and mixtures thereof.10. A method of controlling malodors comprising: contacting a situscomprising a malodor or that will develop a malodor with an articleselected from the group consisting of the articles of claims 1 to
 9. 11.The method of claim 10 wherein, said situs comprises a fabric and saidcontacting step comprises contacting said fabric with a sufficientamount of Applicants' article containing Malodor reducing composition toprovide said fabric with a level of malodor reduction material at least0.0025 mg of malodor reduction material/kg of fabric, preferably fromabout 0.00025 mg of malodor reduction material/kg of fabric to about 25mg of malodor reduction material/kg of fabric, more preferably fromabout 0.025 mg of malodor reduction material/kg of fabric to about 20 mgof malodor reduction material/kg of fabric, most preferably from about0.25 of malodor reduction material/kg of fabric to about 10 mg ofmalodor reduction material/kg of fabric of said sum of malodor reductionmaterials.